Particle mass yield from β-caryophyllene ozonolysis

Atmospheric Chemistry and Physics

Volumn 12, Issue 7, 2012, Pages 3165-3179

  Chen, Q ^a   Li, Y L ^a,b   McKinney, K A ^c   Kuwata, M ^a   Martin, S T ^a,d  

^a HARVARD UNIVERSITY   (United States)

^b HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^c AMHERST COLLEGE   (United States)

^d HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AIR QUALITY; BIOGENIC MATERIAL; CONCENTRATION (COMPOSITION); OZONE; PARAMETERIZATION; STOICHIOMETRY;

EID: 84859305191     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-12-3165-2012     Document Type: Article

References (68)

1. Aiken, A. C., DeCarlo, P. F., and Jimenez, J. L.: Elemental analysis of organic species with electron ionization high-resolution mass spectrometry, Anal. Chem., 79, 8350-8358, doi:10.1021/ac071150w, 2007. (Pubitemid 350060037)
2. Aiken, A. C., Decarlo, P. F., Kroll, J. H., Worsnop, D. R., Huffman, J. A., Docherty, K. S., Ulbrich, I. M., Mohr, C., Kimmel, J. R., Sueper, D., Sun, Y., Zhang, Q., Trimborn, A., Northway, M., Ziemann, P. J., Canagaratna, M. R., Onasch, T. B., Alfarra, M. R., Prevot, A. S. H., Dommen, J., Duplissy, J., Metzger, A., Baltensperger, U., and Jimenez, J. L.: O/C and OM/OC ratios of primary, secondary, and ambient organic aerosols with high-resolution time-of-flight aerosol mass spectrometry, Environ. Sci. Technol., 42, 4478-4485, doi:10.1021/es703009q, 2008. (Pubitemid 351842394)
3. Alfarra, M. R., Coe, H., Allan, J. D., Bower, K. N., Boudries, H., Canagaratna, M. R., Jimenez, J. L., Jayne, J. T., Garforth, A. A., Li, S. M., and Worsnop, D. R.: Characterization of urban and rural organic particulate in the lower Fraser valley using two aerodyne aerosol mass spectrometers, Atmos. Environ., 38, 5745-5758, doi:10.1016/j.atmosenv.2004.01.054, 2004. (Pubitemid 39277943)
4. Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of bio-genic volatile organic compounds: a review, Atmos. Environ., 37, S197-S219, doi:10.1016/s1352-2310(03)00391-1, 2003. (Pubitemid 37103155)
5. Bahreini, R., Keywood, M. D., Ng, N. L., Varutbangkul, V., Gao, S., Flagan, R. C., Seinfeld, J. H., Worsnop, D. R., and Jimenez, J. L.: Measurements of secondary organic aerosol from oxidation of cycloalkenes, terpenes, and m-xylene using an Aerodyne aerosol mass spectrometer, Environ. Sci. Technol., 39, 5674-5688, doi:10.1021/es048061a, 2005.
6. Carlton, A. G., Bhave, P. V., Napelenok, S. L., Edney, E. D., Sar-war, G., Pinder, R. W., Pouliot, G. A., and Houyoux, M.: Model Representation of Secondary Organic Aerosol in CMAQv4.7, Environ. Sci. Technol., 44, 8553-8560, doi:10.1021/es100636q, 2010.
7. Chan, A. W. H., Kroll, J. H., Ng, N. L., and Seinfeld, J. H.: Kinetic modeling of secondary organic aerosol formation: effects of particle-and gas-phase reactions of semivolatile products, At-mos. Chem. Phys., 7, 4135-4147, doi:10.5194/acp-7-4135-2007, 2007. (Pubitemid 47230496)
8. Chan, M. N., Surratt, J. D., Chan, A. W. H., Schilling, K., Offen-berg, J. H., Lewandowski, M., Edney, E. O., Kleindienst, T. E., Jaoui, M., Edgerton, E. S., Tanner, R. L., Shaw, S. L., Zheng, M., Knipping, E. M., and Seinfeld, J. H.: Influence of aerosol acidity on the chemical composition of secondary organic aerosol from beta-caryophyllene, Atmos. Chem. Phys., 11, 1735-1751, doi:10.5194/acp-11-1735-2011, 2011.
9. Chen, Q., Farmer, D. K., Schneider, J., Zorn, S. R., Heald, C. L., Karl, T. G., Guenther, A., Allan, J. D., Robinson, N., Coe, H., Kimmel, J. R., Pauliquevis, T., Borrmann, S., Poschl, U., An-dreae, M. O., Artaxo, P., Jimenez, J. L., and Martin, S. T.: Mass spectral characterization of submicron biogenic organic particles in the Amazon Basin, Geophys. Res. Lett., 36, L20806, doi:10.1029/2009gl039880, 2009.
10. Chen, Q., Liu, Y., Donahue, N. M., Shilling, J. E., and Martin, S. T.: Particle-phase chemistry of secondary organic material: Modeled compared to measured O:C and H:C elemental ratios provide constraints, Environ. Sci. Technol., 45, 4763-4770, doi:10.1021/es104398s, 2011.
11. Chung, S. H. and Seinfeld, J. H.: Global distribution and climate forcing of carbonaceous aerosols, J. Geophys. Res., 107, 4407, doi:10.1029/ 2001jd001397, 2002. (Pubitemid 43206212)
12. DeCarlo, P. F., Slowik, J. G., Worsnop, D. R., Davidovits, P., and Jimenez, J. L.: Particle morphology and density characterization by combined mobility and aerodynamic diameter measurements, Part 1: Theory, Aerosol Sci. Technol., 38, 1185-1205, doi:10.1080/027868290903907, 2004. (Pubitemid 40075872)
13. DeCarlo, P. F., Kimmel, J. R., Trimborn, A., Northway, M. J., Jayne, J. T., Aiken, A. C., Gonin, M., Fuhrer, K., Horvath, T., Docherty, K. S., Worsnop, D. R., and Jimenez, J. L.: Field-deployable, high-resolution, time-of-flight aerosol mass spectrometer, Anal. Chem., 78, 8281-8289, doi:10.1021/ac061249n, 2006. (Pubitemid 44927604)
14. Donahue, N. M., Robinson, A. L., Stanier, C. O., and Pandis, S. N.: Coupled partitioning, dilution, and chemical aging of semivolatile organics, Environ. Sci. Technol., 40, 02635-02643, doi:10.1021/es052297c, 2006.
15. Ehara, K., Hagwood, C., and Coakley, K. J.: Novel method to classify aerosol particles according to their mass-to-charge ratio-Aerosol particle mass analyser, J. Aerosol Sci., 27, 217-234, 1996. (Pubitemid 26109302)
16. Fiore, A., Jacob, D. J., Liu, H., Yantosca, R. M., Fairlie, T. D., and Li, Q.: Variability in surface ozone background over the United States: Implications for air quality policy, J. Geophys. Res., 108, 4787, doi:10.1029/2003jd003855, 2003.
17. Fu, P. Q., Kawamura, K., Chen, J., and Barrie, L. A.: Isoprene, monoterpene, and sesquiterpene oxidation products in the high arctic aerosols during late winter to early summer, Environ. Sci. Technol., 43, 4022-4028, doi:10.1021/es803669a, 2009.
18. Griffin, R. J., Cocker, D. R., Flagan, R. C., and Seinfeld, J. H.: Organic aerosol formation from the oxidation of biogenic hydrocarbons, J. Geophys. Res., 104, 3555-3567, 1999. (Pubitemid 29298432)
19. Grosjean, D., Williams, E. L., Grosjean, E., Andino, J. M., and Seinfeld, J. H.: Atmospheric oxidation of biogenic hydrocarbons: Reaction of ozone with β-pinene, d-limonene, and trans-caryophyllene, Environ. Sci. Technol., 27, 2754-2758, 1993.
20. Helmig, D., Balsley, B., Davis, K., Kuck, L. R., Jensen, M., Bognar, J., Smith, T., Arrieta, R. V., Rodriguez, R., and Birks, J. W.: Vertical profiling and determination of landscape fluxes of biogenic nonmethane hydrocarbons within the planetary boundary layer in the Peruvian Amazon, J. Geophys. Res., 103, 25519-25532, doi:10.1029/98JD01023, 1998. (Pubitemid 128700099)
21. Helmig, D., Ortega, J., Duhl, T., Tanner, D., Guenther, A., Harley, P., Wiedinmyer, C., Milford, J., and Sakulyanontvittaya, T.: Sesquiterpene emissions from pine trees-Identifications, emission rates and flux estimates for the contiguous United States, Environ. Sci. Technol., 41, 1545-1553, doi:10.1021/es0618907, 2007. (Pubitemid 46362451)
22. Hoffmann, T., Odum, J. R., Bowman, F., Collins, D., Klockow, D., Flagan, R. C., and Seinfeld, J. H.: Formation of organic aerosols from the oxidation of biogenic hydrocarbons, J. Atmos. Chem., 26, 189-222, 1997.
23. Hu, D., Bian, Q., Li, T. W. Y., Lau, A. K. H., and Yu, J. Z.: Contributions of isoprene, monoterpenes, β-caryophyllene, and toluene to secondary organic aerosols in Hong Kong during the summer of 2006, J. Geophys. Res., 113, D22206, doi:10.1029/2008jd010437, 2008.
24. Jaoui, M. and Kamens, R. M.: Gas and particulate products distribution from the photooxidation of α-humulene in the presence of NOx, natural atmospheric air and sunlight, J. Atmos. Chem., 46, 29-54, 2003. (Pubitemid 37009790)
25. Jaoui, M., Leungsakul, S., and Kamens, R. M.: Gas and particle products distribution from the reaction of β-caryophyllene with ozone, J. Atmos. Chem., 45, 261-287, 2003. (Pubitemid 36874550)
26. Jaoui, M., Lewandowski, M., Kleindienst, T. E., Offenberg, J. H., and Edney, E. O.: β-caryophyllinic acid: An atmospheric tracer for β-caryophyllene secondary organic aerosol, Geophys. Res. Lett., 34, L05816, doi:10.1029/2006gl028827, 2007. (Pubitemid 46876236)
27. Kanawati, B., Herrmann, F., Joniec, S., Winterhalter, R., and Moortgat, G. K.: Mass spectrometric characterization of β-caryophyllene ozonolysis products in the aerosol studied using an electrospray triple quadrupole and time-of-flight analyzer hybrid system and density functional theory, Rapid Commun. Mass Spectrom., 22, 165-186, 2008. (Pubitemid 351156129)
28. Katrib, Y., Martin, S. T., Rudich, Y., Davidovits, P., Jayne, J. T., and Worsnop, D. R.: Density changes of aerosol particles as a result of chemical reaction, Atmos. Chem. Phys., 5, 275-291, doi:10.5194/acp-5-275-2005, 2005. (Pubitemid 40335308)
29. King, S. M., Rosenoern, T., Shilling, J. E., Chen, Q., and Martin, S. T.: Cloud condensation nucleus activity of secondary organic aerosol particles mixed with sulfate, Geophys. Res. Lett., 34, L24806, doi:10.1029/2007gl030390, 2007. (Pubitemid 351279332)
30. King, S. M., Rosenoern, T., Shilling, J. E., Chen, Q., and Martin, S. T.: Increased cloud activation potential of secondary organic aerosol for atmospheric mass loadings, Atmos. Chem. Phys., 9, 2959-2971, doi:10.5194/acp-9-2959-2009, 2009.
31. Kleindienst, T. E., Smith, D. F., Li, W., Edney, E. O., Driscoll, D. J., Speer, R. E., and Weathers, W. S.: Secondary organic aerosol formation from the oxidation of aromatic hydrocarbons in the presence of dry submicron ammonium sulfate aerosol, Atmos. Environ., 33, 3669-3681, 1999. (Pubitemid 29324724)
32. Kleindienst, T. E., Jaoui, M., Lewandowski, M., Offenberg, J. H., Lewis, C. W., Bhave, P. V., and Edney, E. O.: Estimates of the contributions of biogenic and anthropogenic hydrocarbons to secondary organic aerosol at a southeastern US location, Atmos. Environ., 41, 8288-8300, doi:10.1016/j. atmosenv.2007.06.045, 2007. (Pubitemid 350101314)
33. Knutson, E. O. and Whitby, K. T.: Aerosol classification by electric mobility: Apparatus, theory, and applications, J. Aerosol Sci., 6, 443-451, 1975.
34. Kroll, J. H., Donahue, N. M., Jimenez, J. L., Kessler, S. H., Cana-garatna, M. R., Wilson, K. R., Altieri, K. E., R.Mazzoleni, L., Wozniak, A. S., Bluhm, H., Mysak, E. R., Smith, J. D., Kolb, C. E., and Worsnop, D. R.: Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol, Nature Chem., 3, 133-139, doi:10.1038/nchem.948, 2011.
35. Kuwata, M., Zorn, S. R., and Martin, S. T.: Using elemental ratios to predict the density of organic material composed of carbon, hydrogen, and oxygen, Environ. Sci. Technol., 46, 787-794, doi:10.1021/es202525q, 2012.
36. Lee, A., Goldstein, A. H., Keywood, M. D., Gao, S., Varut-bangkul, V., Bahreini, R., Ng, N. L., Flagan, R. C., and Seinfeld, J. H.: Gas-phase products and secondary aerosol yields from the ozonolysis of ten different terpenes, J. Geophys. Res., 111, D07302, doi:10.1029/2005jd006437, 2006a.
37. Lee, A., Goldstein, A. H., Kroll, J. H., Ng, N. L., Varut-bangkul, V., Flagan, R. C., and Seinfeld, J. H.: Gas-phase products and secondary aerosol yields from the photooxida-tion of 16 different terpenes, J. Geophys. Res., 111, D17305, doi:10.1029/2006jd007050, 2006b.
38. Li, Y. J., Chen, Q., Guzman, M. I., Chan, C. K., and Martin, S. T.: Second-generation products contribute substantially to the particle-phase organic material produced by β-caryophyllene ozonolysis, Atmos. Chem. Phys., 11, 121-132, doi:10.5194/acp-10-1-2010, 2011.
39. Liu, B. Y. H. and Lee, K. W.: An aerosol generator of high stability, Am. Ind. Hyg. Assoc. J., 36, 861-865, doi:10.1080/0002889758507357, 1975.
40. Matsunaga, A. and Ziemann, P. J.: Gas-wall partitioning of organic compounds in a Teflon film chamber and potential effects on reaction product and aerosol yield measurements, Aerosol Sci. Technol., 44, 881-892, doi:10.1080/02786826.2010.501044, 2010.
41. Matthew, B. M., Middlebrook, A. M., and Onasch, T. B.: Collection efficiencies in an Aerodyne Aerosol Mass Spectrometer as a function of particle phase for laboratory generated aerosols, Aerosol Sci. Technol., 42, 884-898, doi:10.1080/02786820802356797, 2008.
42. McMurry, P. H. and Grosjean, D.: Gas and aerosol wall losses in Teflon film smog chambers, Environ. Sci. Technol., 19, 1176-1182, 1985. (Pubitemid 16197737)
43. McMurry, P. H. and Rader, D. J.: Aerosol wall losses in electrically charged chambers, Aerosol Sci. Technol., 4, 249-268, 1985. (Pubitemid 15561853)
44. Mensah, A. A., Buchholz, A., Mentel, T. F., Tillmann, R., and Kiendler-Scharr, A.: Aerosol mass spectrometric measurements of stable crystal hydrates of oxalates and inferred relative ionization efficiency of water, J. Aerosol Sci., 42, 11-19, doi:10.1016/j.jaerosci.2010.10.003, 2011.
45. Neue, U. D., Kele, M., Bunner, B., Kromidas, A., Dourdeville, T., Mazzeo, J. R., Grumbach, E. S., Serpa, S., Wheat, T. E., Hong, P., and Gilar, M.: Ultra-Performance Liquid Chromatography Technology and Applications, in: Adv. Chromatogr. (Boca Raton, FL, U. S.), edited by: Grushka, E., and Grinberg, N., Advances in Chromatography, 99-143, 2010.
46. Ng, N. L., Kroll, J. H., Keywood, M. D., Bahreini, R., Varut-bangkul, V., Flagan, R. C., Seinfeld, J. H., Lee, A., and Goldstein, A. H.: Contribution of first-versus second-generation products to secondary organic aerosols formed in the oxidation of biogenic hydrocarbons, Environ. Sci. Technol., 40, 2283-2297, doi:10.1021/es052269u, 2006.
47. Ng, N. L., Chhabra, P. S., Chan, A. W. H., Surratt, J. D., Kroll, J. H., Kwan, A. J., McCabe, D. C., Wennberg, P. O., Sorooshian, A., Murphy, S. M., Dalleska, N. F., Flagan, R. C., and Seinfeld, J. H.: Effect of NOx level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes, Atmos. Chem. Phys., 7, 5159-5174, doi:10.5194/acp-7-5159-2007, 2007. (Pubitemid 47554256)
48. Nguyen, T. L., Winterhalter, R., Moortgat, G., Kanawati, B., Peeters, J., and Vereecken, L.: The gas-phase ozonolysis of β-caryophyllene (C15H24). Part II: A theoretical study, Phys. Chem. Chem. Phys., 11, 4173-4183, 2009.
49. Odum, J. R., Hoffmann, T., Bowman, F., Collins, D., Flagan, R. C., and Seinfeld, J. H.: Gas/particle partitioning and secondary organic aerosol yields, Environ. Sci. Technol., 30, 2580-2585, 1996.
50. Offenberg, J. H., Kleindienst, T. E., Jaoui, M., Lewandowski, M., and Edney, E. O.: Thermal properties of secondary organic aerosols, Geophys. Res. Lett., 33, L03816, doi:10.1029/2005gl024623, 2006.
51. Offenberg, J. H., Lewandowski, M., Edney, E. O., Kleindi-enst, T. E., and Jaoui, M.: Influence of aerosol acidity on the formation of secondary organic aerosol from biogenic precursor hydrocarbons, Environ. Sci. Technol., 43, 7742-7747, doi:10.1021/es901538e, 2009.
52. Pankow, J. F.: An absorption-model of gas-particle partitioning of organic compounds in the atmosphere, Atmos. Environ., 28, 185-188, 1994a.
53. Pankow, J. F.: An absorption-model of the gas aerosol partitioning involved in the formation of secondary organic aerosol, Atmos. Environ., 28, 189-193, 1994b.
54. Pankow, J. F. and Asher, W. E.: SIMPOL.1: a simple group contribution method for predicting vapor pressures and enthalpies of vaporization of multifunctional organic compounds, Atmos. Chem. Phys., 8, 2773-2796, doi:10.5194/acp-8-2773-2008, 2008.
55. Pierce, J. R., Engelhart, G. J., Hildebrandt, L., Weitkamp, E. A., Pathak, R. K., Donahue, N. M., Robinson, A. L., Adams, P. J., and Pandis, S. N.: Constraining particle evolution from wall losses, coagulation, and condensation-evaporation in smog-chamber experiments: Optimal estimation based on size distribution measurements, Aerosol Sci. Technol., 42, 1001-1015, doi:10.1080/02786820802389251, 2008.
56. Presto, A. A. and Donahue, N. M.: Investigation of α-pinene plus ozone secondary organic aerosol formation at low total aerosol mass, Environ. Sci. Technol., 40, 3536-3543, doi:10.1021/es052203z, 2006. (Pubitemid 43830962)
57. Sakulyanontvittaya, T., Duhl, T., Wiedinmyer, C., Helmig, D., Matsunaga, S., Potosnak, M., Milford, J., and Guenther, A.: Monoterpene and sesquiterpene emission estimates for the United States, Environ. Sci. Technol., 42, 1623-1629, doi:10.1021/es702274e, 2008a. (Pubitemid 351416172)
58. Sakulyanontvittaya, T., Guenther, A., Helmig, D., Milford, J., and Wiedinmyer, C.: Secondary organic aerosol from sesquiterpene and monoterpene emissions in the United States, Environ. Sci. Technol., 42, 8784-8790, doi:10.1021/es800817r, 2008b.
59. Seinfeld, J. H. and Pankow, J. F.: Organic atmospheric par-ticulate material, Annu. Rev. Phys. Chem., 54, 121-140, doi:10.1146/annurev.physchem.54. 011002.103756, 2003.
60. Seinfeld, J. H., Kleindienst, T. E., Edney, E. O., and Cohen, J. B.: Aerosol growth in a steady-state, continuous flow chamber: Application to studies of secondary aerosol formation, Aerosol Sci. Technol., 37, 728-734, doi:10.1080/02786820390214954, 2003. (Pubitemid 40164072)
61. Shilling, J. E., Chen, Q., King, S. M., Rosenoern, T., Kroll, J. H., Worsnop, D. R., McKinney, K. A., and Martin, S. T.: Particle mass yield in secondary organic aerosol formed by the dark ozonolysis of α-pinene, Atmos. Chem. Phys., 8, 2073-2088, doi:10.5194/acp-8-2073-2008, 2008.
62. Shilling, J. E., Chen, Q., King, S. M., Rosenoern, T., Kroll, J. H., Worsnop, D. R., DeCarlo, P. F., Aiken, A. C, Sueper, D., Jimenez, J. L., and Martin, S. T.: Loading-dependent elemental composition of a-pinene SOA particles, Atmos. Chem. Phys., 9, 771-782, doi:10.5194/acp-9-771-2009,2009.
63. Shu, Y. H. and Atkinson, R.: Atmospheric lifetimes and fates of a series of sesquiterpenes, J. Geophys. Res., 100, 7275-7281, doi:10.1029/95JD00368, 1995.
64. Slowik, J. G., Stroud, C, Bottenheim, J. W., Brickell, P. C, Chang, R. Y.-W., Liggio, J., Makar, P. A., Martin, R. V., Moran, M. D., Shantz, N. C, Sjostedt, S. J., van Donkelaar, A., Vlasenko, A., Wiebe, H. A., Xia, A. G., Zhang, J., Leaitch, W. R., and Ab-batt, J. P. D.: Characterization of a large biogenic secondary organic aerosol event from eastern Canadian forests, Atmos. Chem. Phys., 10,2825-2845, doi:10.5194/acp-10-2825-2010, 2010.
65. Solomon, P., Cowling, E., Hidy, G., and Furiness, C: Comparison of scientific findings from major ozone field studies in North America and Europe, Atmos. Environ., 34, 1885-1920, 2000. (Pubitemid 30151060)
66. Wang, S. C. and Flagan, R. C: Scanning electrical mobility spectrometer, J. Aerosol Sci., 20, 1485-1488, doi:10.1016/0021-8502(89)90868-9, 1989. (Pubitemid 20675780)
67. Winterhalter, R., Herrmann, F., Kanawati, B., Nguyen, T. L., Peeters, J., Vereecken, L., and Moortgat, G. K.: The gas-phase ozonolysis of/3-caryophyllene (C15H24). Part I: an experimental study, Phys. Chem. Chem. Phys., 11, 4152-4172, doi:10.1039/b817824k, 2009.
68. Zhang, H. L. and Ying, Q.: Secondary organic aerosol formation and source apportionment in Southeast Texas, Atmos. Environ., 45, 3217-3227, doi:10.1016/j.atmosenv.2011.03.046,2011.