Investigation of α-pinene + ozone secondary organic aerosol formation at low total aerosol mass

Environmental Science and Technology

Volumn 40, Issue 11, 2006, Pages 3536-3543

  Presto, Albert A ^a,b   Donahue, Neil M ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b NATIONAL ENERGY TECHNOLOGY LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL PRODUCTION; PARTITIONING MODELS; PROTON-TRANSFER REACTION MASS SPECTROMETRY (PTR-MS); SECONDARY ORGANIC AEROSOL (SOA);

CONCENTRATION (PROCESS); EXTRAPOLATION; LIGHTING; MASS SPECTROMETRY; MATHEMATICAL MODELS; OZONE; REAL TIME SYSTEMS;

AEROSOLS;

FLUOROCARBON; OZONE; PINENE; POLITEF; TERPENE; VOLATILE ORGANIC COMPOUND;

AEROSOLS; CONCENTRATION (PROCESS); EXTRAPOLATION; LIGHTING; MASS SPECTROMETRY; MATHEMATICAL MODELS; OZONE; REAL TIME SYSTEMS;

AEROSOL; OZONE;

AEROSOL; ARTICLE; GAS; GAS CHROMATOGRAPHY; IONIZATION; MASS SPECTROMETRY; MATHEMATICAL MODEL; OXIDATION; OZONOLYSIS; PARTITION COEFFICIENT; PHOTOCHEMISTRY; PHOTOLYSIS; SECONDARY ORGANIC AEROSOL; SIGNAL NOISE RATIO; ULTRAVIOLET RADIATION; VAPOR PRESSURE;

AEROSOLS; AIR POLLUTANTS; MASS SPECTROMETRY; MONOTERPENES; OZONE;

EID: 33646036285     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es052203z     Document Type: Article

References (45)

1. Pandis, S.; Paulson, S.; Seinfeld, J.; Flagan, R. Aerosol formation in the photooxidation of isoprene and β-pinene. Atmos. Environ., Part A 1991, 25, 997.
2. Zhang, S.; Shaw, M.; Seinfeld, J.; Flagan, R. Photochemical aerosol formation from α-pinene and β-pinene. J. Geophys. Res. 1992, 97, 20717.
3. Hoffmann, T.; Odum, J.; Bowman, F.; Collins, D.; Kluckow, D.; Flagan, R.; Seinfeld, J. Formation of organic aerosols from the oxidation of biogenic hydrocarbons. J. Atmos. Chem. 1997, 26, 189.
4. Griffin, R.; Cocker, D.; Flagan, R.; Seinfeld, J. Organic aerosol formation from the oxidation of biogenic hydrocarbons. J. Geophys. Res., [Atmos.] 1999, 104, 3555.
5. Jang, M.; Kamens, R.; Leach, K.; Strommen, M. A thermodynamic approach using group contribution methods to model the partitioning of semivolatile organic compounds on atmospheric particulate matter. Environ. Sci. Technol. 1997, 31, 2805.
6. 3 radical-initiated oxidation of selected monoterpenes. Environ. Sci. Technol. 1999, 33, 553.
7. Glausius, M.; Lahaniati, M.; Calogirou, A.; DiBella, D.; Jensen, N.; Hjorth, J.; Kotzias, D.; Larsen, B. Carboxylic acids in secondary aerosols from oxidation of cyclic monoterpenes by ozone. Environ. Sci. Technol. 2000, 34, 1001.
8. Koch, S.; Winterhalter, R.; Uherek, E.; Kolloff, A.; Neeb, P.; Moortgat, G. Formation of new particles in the gas-phase ozonolysis of monoterpenes. Atmos. Environ. 2000, 34, 4031.
9. x/air in the presence of natural sunlight. J. Geophys. Res., [Atmos.] 2001, 106, 12541.
10. 3 reaction: Influence of particle acidity on aerosol yields and products. Atmos. Environ. 2004, 38, 761.
11. Presto, A. A.; Huff Hartz, K. E.; Donahue, N. M. Secondary organic aerosol production from terpene ozonolysis. 1. Effect of UV radiation. Environ. Sci. Technol. 2005, 39, 7036-7045.
12. x concentration. Environ. Sci. Technol. 2005, 39, 7046-7054.
13. 3-carene/, and cyclohexene/ ozone systems. Environ. Sci. Technol. 2001, 35, 1164.
14. Wittig, A.; Anderson, N.; Khlystov, A.; Pandis, S.; Davidson, C.; Robinson, A. Pittsburgh air quality study overview. Atmos. Environ. 2004, 38, 3107.
15. Cabada, J.; Rees, S.; Takahama, S.; Khlystov, A.; Pandis, S.; Davidson, C.; Robinson, A. Mass size distributions and size resolved chemical composition of fine particulate matter at the Pittsburgh supersite. Atmos. Environ. 2004, 38, 3127.
16. Seinfeld, J.; Pandis, S. Atmospheric Chemistry and Physics; Wiley & Sons: New York, 1998.
17. Calvert, J.; Atkinson, R.; Kerr, J.; Madronich, S.; Moortgat, G.; Wallington, T.; Yarwood, G. The Mechanisms of Atmospheric Oxidation of the Alkenes; Oxford University Press: New York, 2000.
18. Ng, N. L.; Kroll, J. H.; Keywood, M. D.; Bahreini, R.; Varutbangkul, V.; Flagan, R. C.; Seinfeld, J. H.; Lee, A.; Goldstein, A. H. Contribution of first- versus second-generation products to secondary organic aerosols formed in the oxidation of biogenic hydrocarbons. Environ. Sci. Technol. 2006, 40, 2283.
19. Lindinger, A.; Hansel, A.; Jordan, A. On-line monitoring of volatile organic compounds at pptv levels by means of proton-transfer-reaction mass spectrometry (PTR-MS) medical applications, food control and environmental research. Int. J. Mass Spectrom. Ion Processes 1998, 173, 191.
20. Hayward, S.; Hewitt, C.; Sartin, J.; Owen, S. Performance characteristics and applications of a proton transfer reaction-mass spectrometer for measuring volatile organic compounds in ambient air. Environ. Sci. Technol. 2002, 36, 1554.
21. Hewitt, C.; Hayward, S.; Tani, A. The application of proton transfer reaction-mass spectrometry (PTR-MS) to the monitoring and analysis of volatile organic compounds in the atmosphere. J. Environ. Monit. 2003, 5, 1.
22. de Gouw, J.; Warneke, C.; Karl, T.; Eerdekens, G.; van der Veen, C.; Fall, R. Sensitivity and specificity of atmospheric trace gas detection by proton-transfer-reaction mass spectrometry. Int. J. Mass Spectrom. 2003, 223-224, 365.
23. Warneke, C.; de Gouw, J.; Kuster, W.; Goldan, P.; Fall, R. Validation of atmospheric VOC measurements by proton-transfer-reaction mass spectrometry using a gas-chromatographic preseparation method. Environ. Sci. Technol. 2003, 37, 2494.
24. Tani, A.; Hayward, S.; Hewitt, C. Measurement of monoterpenes and related compounds by proton transfer reaction-mass spectrometry (PTR-MS). Int. J. Mass Spectrom. 2003, 223-224, 561.
25. Tani, A.; Hayward, S.; Hansel, A.; Hewitt, C. Effect of water vapour pressure on monoterpene measurements using proton transfer reaction-mass spectrometry (PTR-MS). Int. J. Mass Spectrom. 2004, 239, 161.
26. Whisthaler, A.; Tamas, G.; Wyon, D.; Strom-Tejsen, P.; Space, D.; Beauchamp, J.; Mark, T.; Weschler, C. Products of ozone-initiated chemistry in a simulated aircraft environment. Environ. Sci. Technol. 2005, 39, 4823.
27. Atkinson, R. J. Phys. Chem. Ref. Data 1997, 26.
28. Odum, J.; Hoffmann, T.; Bowman, F.; Collins, D.; Flagan, R.; Seinfeld, J. Gas/particle partitioning and secondary organic aerosol yields. Environ. Sci. Technol. 1996, 30, 2580.
29. Odum, J.; Jungkamp, T.; Griffin, R.; Forstner, H.; Flagan, R.; Seinfeld, J. Aromatics, reformulated gasoline, and atmospheric organic aerosol formation. Environ Sci. Technol. 1997, 31, 1890.
30. Kalberer, M.; Yu, J.; Cocker, D.; Flagan, R.; Seinfeld, J. Aerosol formation in the cyclohexene-ozone system. Environ. Sci. Technol. 2000, 34, 4894.
31. Takekawa, H.; Minoura, H.; Yamazaki, S. Temperature dependence of secondary organic aerosol formation by photooxidation of hydrocarbons. Atmos. Environ. 2003, 37, 3413.
32. Keywood, M.; Varutbangkul, V.; Bahreini, R.; Flagan, R.; Seinfeld, J. Secondary organic aerosol formation from the ozonolysis of cycloalkenes and related compounds. Environ. Sci. Technol. 2004, 38, 4157.
33. Pankow, J. An absorption model of gas/particle partitioning of organic compounds in the atmosphere. Atmos. Environ. 1994, 28, 185.
34. Pankow, J. An absorption model of the gas/aerosol partitioning involved in the formation of secondary organic aerosol. Atmos. Environ. 1994, 28, 189.
35. Cocker, D.; Clegg, S.; Flagan, R.; Seinfeld, J. The effect of water on gas-particle partitioning of secondary organic aerosol. Part I: α-Pinene/ozone system. Atmos. Environ. 2001, 35, 6049.
36. Stanier, C. O.; Donahue, N. M.; Pandis, S. N. Environ. Sci. Technol., submitted for publication.
37. Donahue, N.; Robinson, A. L.; Stanier, C. O.; Pandis, S. N. The coupled partitioning, dilution, and chemical aging of semivolatile organics. Environ. Sci. Technol. 2006, 40, 2635.
38. Pathak, R. K.; Stanier, C. O.; Presto, A. A.; Donahue, N. M.; Pandis, S. N. Environ. Sci. Technol., submitted for publication.
39. Shrivastava, M.; Lipsky, E. M.; Stanier, C. O.; Robinson, A. L. Modeling semivolatile organic aerosol mass emissions from combustion systems. Environ. Sci. Technol. 2006, 40, 2671.
40. x production rates in the Nashville urban plume. J. Geophys. Res., [Atmos.] 2002, 107, 4146.
41. Hoppel, W.; Fitzgerald, J.; Frick, G.; Caffrey, P.; Pasternack, L.; Hegg, D.; Gao, S.; Leaitch, R.; Shantz, N.; Cantrell, C.; Albrechcinski, T.; Ambrusko, J.; Sullivan, W. Particle formation and growth from ozonolysis of α-pinene. J. Geophys. Res., [Atmos.] 2001, 106, 27603.
42. Donahue, N. M.; Huff Hartz, K. E.; Chuong, B.; Presto, A. A.; Stanier, C. O.; Rosenhorn, T.; Robinson, A. L.; Pandis, S. N. Critical factors determining the variation in SOA yields from terpene ozonolysis: A combined experimental and computational study. Faraday Discuss. 2005, 130, 295-309.
43. Tolocka, M.; Jang, M.; Ginter, J.; Cox, F.; Kamens, R.; Johnston, M. Formation of oligomers in secondary organic aerosol. Environ. Sci. Technol. 2004, 33, 1428.
44. Gao, S.; Keywood, M.; Ng, L.; Surratt, J.; Varutbangkul, V.; Bahreini, R.; Flagan, R.; Seinfeld, J. Low-molecular-weight and oligomeric components in secondary organic aerosol from the ozonolysis of cycloalkenes and α-pinene J. Phys. Chem. A 2004, 108, 10147.
45. x conditions. Geophys. Res. Lett. 2005, 32, L18808.