Kinetic modeling of secondary organic aerosol formation: Effects of particle- and gas-phase reactions of semivolatile products

Atmospheric Chemistry and Physics

Volumn 7, Issue 15, 2007, Pages 4135-4147

  Chan, A W H ^a   Kroll, J H ^a,b   Ng, N L ^a   Seinfeld, J H ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b AERODYNE RESEARCH INC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL FORMATION; ATMOSPHERIC MODELING; GAS PHASE REACTION; HYDROCARBON; LABORATORY METHOD; OXIDATION; VOLATILE SUBSTANCE;

EID: 34547727770     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-7-4135-2007     Document Type: Article

References (36)

1. Bowman, F. M., Odum, J. R., Seinfeld, J. H., and Pandis, S. N.: Mathematical model for gas-particle partitioning of secondary organic aerosols, Atmos. Environ., 31, 3921-3931, 1997.
2. Calvert, J. G., Atkinson, R., Becker, K. H., Kamens, R. M., Seinfeld, J. H., Wallington, T. J., and Yarwoord, G.: The mechanisms of atmospheric oxidation of aromatic hydrocarbons, Oxford University Press, New York, 2002.
3. Czoschke, N. M., Jang, M., and Kamens, R. M.: Effect of acidic seed on biogenic secondary organic aerosol growth, Atmos. Environ., 37, 4287-4299, 2003.
4. Donahue, N. M., Robinson, A. L., Stanier, C. O., and Pandis, S. N.: Coupled partitioning, dilution, and chemical aging of semivolatile organics, Environ. Sci. Technol., 40, 2635-2643, 2006.
5. Gao, S., Ng, N. L., Keywood, M., Varutbangkul, V., Bahreini, R., Nenes, A., He, J., Yoo, K. Y., Beauchamp, J. L., Hodyss, R. P., Flagan, R. C., and Seinfeld, J. H.: Particle phase acidity and oligomer formation in secondary organic aerosol, Environ. Sci. Technol., 38, 6582-6589, 2004a.
6. Gao, S., Keywood, M., Ng, N. L., Surratt, J., Varutbangkul, V., Bahreini, R., Flagan, R. C., and Seinfeld, J. H.: Low-molecular weight and oligomeric components in secondary organic aerosol from the ozonolysis of cycloalkenes and ©-pinene, J. Phys. Chem. A, 108, 10147-10 164, 2004b.
7. Grieshop, A. P., Donahue, N. M., and Robinson, A. L.: Is the gas-particle partitioning in alpha-pinene secondary organic aerosol reversible?, Geophys. Res. Lett., 34, L14810, doi:10.1029/2007GL029987, 2007.
8. Griffin, R. J., Dabdub, D., and Seinfeld, J. H.: Secondary organic aerosol - 1. Atmospheric chemical mechanism for production of molecular constituents, J. Geophys. Res., 107, 4332, doi: 10.1029/2001JD000541, 2002a.
9. Griffin, R. J., Dabdub, D., Kleeman, M. J., Fraser, M. P., Cass, G. R., and Seinfeld, J. H.: Secondary organic aerosol - 3. Urban/regional scale model of size- and composition-resolved aerosols, J. Geophys. Res., 107, 4334, doi: 10.1029/2001JD000544, 2002b.
10. Iinuma, Y., Böge, O., Gnauk, T., and Herrmann, H.: Aerosolchamber study of the α-pinene/03 reaction: influence of particle acidity on aerosol yields and products, Atmos. Environ. 38, 761-773, 2004.
11. Jang, M., Czoschke, N. M., Lee, S., and Kamens, R. M.: Heterogeneous atmospheric aerosol production by acid-catalyzed particlephase reactions, Science, 298, 814-817, 2002.
12. Johnson, D., Utembe, S. R., Jenkin, M. E., Derwent, R. G., Hayman, G. D., Alfarra, M. R., Coe, H., and McFiggans, G.: Simulating regional scale secondary organic aerosol formation during the TORCH 2003 campaign in the southern UK, Atmos. Chem. Phys., 6, 403-418, 2006, http://www.atmos-chem-phys.net/6/403/2006/ .
13. Kalberer, M., Paulsen, D., Sax, M., Steinbacher, M., Dommen, J., Prevot, A. S. H., Fisseha, R., Weingartner, E., Frankevich, V., Zenobi, R., and Baltensperger, U.: Identification of polymers as major components of atmospheric organic aerosols, Science, 303, 1659-1662, 2004.
14. Kroll, J. H. and Seinfeld, J. H.: Representation of secondary organic aerosol (SOA) laboratory chamber data or the interpretation of mechanisms of particle growth, Environ. Sci. Technol., 39, 4159-4165, 2005.
15. x conditions, Geophys. Res. Lett., 32, L18808, doi:10.1029/2005GL023637, 2005.
16. Kroll, J. H., Ng, N. L., Murphy, S. M., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol formation from isoprene photooxidation, Environ. Sci. Technol., 40, 1869-1877, 2006.
17. Kroll, J. H., Chan, A. W. H., Ng, N. L., Flagan, R. C., and Seinfeld, J. H.: Reactions of semivolatile organics and their effects on secondary organic aerosol formation, Environ. Sci. Technol., 41, 3545-3550, 2007.
18. Liggio, J., Li, S. M., and McLaren, R.: Heterogeneous reactions of glyoxal on particulate matter: Identification of acetals and sulfate esters, Environ. Sci. Technol., 39, 1532-1541, 2005.
19. Liggio, J. and Li, S. M.: Organosulfate formation during the uptake of pinonaldehyde on acidic sulfate aerosols, Geophys. Res. Lett. 33, L13808, doi:10.1029/2006GL026079, 2006.
20. x, Environ. Sci. Technol., 39, 9229-9236, 2005.
21. Miyoshi, A., Hatakeyama, S., and Washida, N.: OH radicalinitiated photooxidation of isoprene - An estimate of global CO production, J. Geophys. Res., 99, 18779-18787, 1994.
22. Ng, N. L., Kroll, J. H., Keywood, M. D., Bahreini, R., Varut-bangkul, V., Flagan, R. C., Seinfeld, J. H., Lee, A., and Goldstein, A. H.: Contribution of first- versus second-generation products to secondary organic aerosols formed in the oxidation of biogenic hydrocarbons, Environ. Sci. Technol., 40, 2283-2297, 2006.
23. Ng, N. L., Kroll, J. H., Chan, A. W. H., Chhabra, P. S., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol formation from, m-xylene, toluene, and benzene, Atmos. Chem. Phys., 7, 3902-3922, 2007
24. Odum, J. R., Hoffmann, T., Bowman, F., Collins, D., Flagan, R. C., and Seinfeld, J. H.: Gas/particle partitioning and secondary organic aerosol yields, Environ. Sci. Technol., 30, 2580-2585, 1996.
25. Odum, J. R., Jungkamp, T P. W., Griffin, R. J., Flagan, R. C., and Seinfeld, J. H.: The atmospheric aerosol-forming potential of whole gasoline vapor, Science, 276, 96-99, 1997.
26. Pankow, J. F.: An absorption model of gas/particle partitioning of organic compounds in the atmosphere, Atmos. Environ, 28A, 185-188, 1994a.
27. Pankow, J. F.: An absorption model of the gas/aerosol partitioning involved in the formation of secondary organic aerosol, Atmos. Environ., 28A, 189-193, 1994b.
28. Paulsen, D., Weingartner, E., Alfarra, M. R., and Baltensperger, U.: Volatility measurements of photochemically and nebulizer-generated organic aerosol particles, J. Aerosol Sci., 37, 1025-1051, 2006.
29. Pun, B. K., Griffin, R. J., Seigneur, C., and Seinfeld, J. H.: Secondary organic aerosol - 2. Thermodynamic model for gas/particle partitioning of molecular constituents, J. Geophys. Res., 107, 4333, doi:10.1029/2001JD000542, 2002.
30. Sato, K., Klotz, B., Hateketama, S., Imamura, T., Washizu, Y., Matsumi, Y., and Washida, N.: Secondary organic aerosol formation during the photo-oxidation of toluene: dependence on initial hydrocarbon concentration, Bull. Chem. Soc. Jpn., 77, 667-671, 2004.
31. Seinfeld, J. H. and Pankow, J. F.: Organic atmospheric particulate material, Annu. Rev. Phys. Chem., 54, 121-140, 2003.
32. Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics, John Wiley, New York, 2006.
33. Surratt, J. D., Murphy, S. M., Kroll, J. H., Ng, N. L., Hildebrandt, L., Sorooshian, A., Szmigielski, R., Vermeylen, R., Maenhaut, W., Claeys, M., Flagan, R. C., and Seinfeld, J. H.: Chemical composition of secondary organic aerosol formed in the photooxidation of isoprene, J. Phys. Chem. A, 110, 9665-9690, 2006.
34. Surratt, J. D., Kroll, J. H., Kleindienst, T E., Edney, E. O., Claeys, M., Sorooshian, A., Ng, N. L., Offenberg, J. H., Lewandowski, M., Jaoui, M., Flagan, R. C., and Seinfeld, J. H.: Evidence for organosulfates in secondary organic aerosol, Environ. Sci. Technol., 41, 517-527, 2007.
35. 3 in the presence of alcohols and carboxylic acids, Environ. Sci. Technol., 34, 2105-2115, 2000.
36. Tolocka, M. P., Jang, M., Ginter, J. M., Cox, F J., Kamens, R. M., and Johnston, M. V: Formation of oligomers in secondary organic aerosol, Environ. Sci. Technol., 38, 1428-1434, 2004.