Selective electrocatalytic reduction of CO 2 to formate by water-stable iridium dihydride pincer complexes

Journal of the American Chemical Society

Volumn 134, Issue 12, 2012, Pages 5500-5503

  Kang, Peng ^a   Cheng, Chen ^a   Chen, Zuofeng ^a   Schauer, Cynthia K ^a   Meyer, Thomas J ^a   Brookhart, Maurice ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROCATALYTIC REDUCTION; IRIDIUM DIHYDRIDE; PINCER COMPLEXES; PINCER LIGANDS; SELECTIVE CATALYSTS; SPECTROSCOPIC STUDIES;

IRIDIUM; IRIDIUM COMPOUNDS; REDUCTION; SPECTROSCOPIC ANALYSIS;

CARBON DIOXIDE;

ACETONITRILE; CARBON DIOXIDE; FORMIC ACID; IRIDIUM COMPLEX; IRIDIUM DIHYDRIDE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; ELECTROCATALYSIS; ELECTROCHEMICAL ANALYSIS; LOW TEMPERATURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; THERMODYNAMICS;

EID: 84859151808     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja300543s     Document Type: Article

References (36)

1. Meyer, T. J. Acc. Chem. Res. 1989, 22, 163-170
2. Leitner, W. Angew. Chem., Int. Ed. Engl. 1995, 34, 2207-2221
3. Benson, E. E.; Kubiak, C. P.; Sathrum, A. J.; Smieja, J. M. Chem. Soc. Rev. 2009, 38, 89-99
4. Mikkelsen, M.; Jorgensen, M.; Krebs, F. C. Energy Environ. Sci. 2010, 3, 43-81
5. Beley, M.; Collin, J. P.; Ruppert, R.; Sauvage, J. P. J. Chem. Soc., Chem. Commun 1984, 1315-1316
6. Dubois, D. L.; Miedaner, A.; Haltiwanger, R. C. J. Am. Chem. Soc. 1991, 113, 8753-8764
7. Hammouche, M.; Lexa, D.; Momenteau, M.; Saveant, J. M. J. Am. Chem. Soc. 1991, 113, 8455-8466
8. Bruce, M. R. M.; Megehee, E.; Sullivan, B. P.; Thorp, H. H.; Otoole, T. R.; Downard, A.; Pugh, J. R.; Meyer, T. J. Inorg. Chem. 1992, 31, 4864-4873
9. Smieja, J. M.; Kubiak, C. P. Inorg. Chem. 2010, 49, 9283-9289
10. Bourrez, M.; Molton, F.; Chardon-Noblat, S.; Deronzier, A. Angew. Chem., Int. Ed. 2011, 50, 9903-9906
11. Chen, Z. F.; Chen, C. C.; Weinberg, D. R.; Kang, P.; Concepcion, J. J.; Harrison, D. P.; Brookhart, M. S.; Meyer, T. J. Chem. Commun. 2011, 47, 12607-12609
12. Slater, S.; Wagenknecht, J. H. J. Am. Chem. Soc. 1984, 106, 5367-5368
13. Ishida, H.; Tanaka, H.; Tanaka, K.; Tanaka, T. J. Chem. Soc., Chem. Commun 1987, 131-132
14. Bolinger, C. M.; Story, N.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1988, 27, 4582-4587
15. Arana, C.; Yan, S.; Keshavarzk, M.; Potts, K. T.; Abruna, H. D. Inorg. Chem. 1992, 31, 3680-3682
16. Caix, C.; Chardon-Noblat, S.; Deronzier, A. J. Electroanal. Chem. 1997, 434, 163-170
17. Rail, M. D.; Berben, L. A. J. Am. Chem. Soc. 2011, 133, 18577-18579
18. Reda, T.; Plugge, C. M.; Abram, N. J.; Hirst, J. Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 10654-10658
19. Johnson, T. C.; Morris, D. J.; Wills, M. Chem. Soc. Rev. 2010, 39, 81-88
20. Rice, C.; Ha, R. I.; Masel, R. I.; Waszczuk, P.; Wieckowski, A.; Barnard, T. J. Power Sources 2002, 111, 83-89
21. Jessop, P. G.; Ikariya, T.; Noyori, R. Nature 1994, 368, 231-233
22. Jessop, P. G.; Joo, F.; Tai, C. C. Coord. Chem. Rev. 2004, 248, 2425-2442
23. Tanaka, R.; Yamashita, M.; Nozaki, K. J. Am. Chem. Soc. 2009, 131, 14168-14169
24. Schmeier, T. J.; Dobereiner, G. E.; Crabtree, R. H.; Hazari, N. J. Am. Chem. Soc. 2011, 133, 9274-9277
25. Tanaka, R.; Yamashita, M.; Chung, L. W.; Morokuma, K.; Nozaki, K. Organometallics 2011, 30, 6742-6750
26. Langer, R.; Diskin-Posner, Y.; Leitus, G.; Shimon, L. J. W.; Ben-David, Y.; Milstein, D. Angew. Chem., Int. Ed. 2011, 50, 9948-9952
27. Creutz, C.; Chou, M. H. J. Am. Chem. Soc. 2007, 129, 10108-10109
28. Chakraborty, S.; Zhang, J.; Krause, J. A.; Guan, H. J. Am. Chem. Soc. 2010, 132, 8872-8873
29. Federsel, C.; Boddien, A.; Jackstell, R.; Jennerjahn, R.; Dyson, P. J.; Scopelliti, R.; Laurenczy, G.; Beller, M. Angew. Chem., Int. Ed. 2010, 49, 9777-9780
30. Rankin, M. A.; Cummins, C. C. J. Am. Chem. Soc. 2010, 132, 10021-10023
31. Kaska, W. C.; Nemeh, S.; Shirazi, A.; Potuznik, S. Organometallics 1988, 7, 13-15
32. Vigalok, A.; Ben-David, Y.; Milstein, D. Organometallics 1996, 15, 1839-1844
33. Huang, K. W.; Han, J. H.; Musgrave, C. B.; Fujita, E. Organometallics 2007, 26, 508-513
34. Lee, D. W.; Jensen, C. M.; Morales-Morales, D. Organometallics 2003, 22, 4744-4749
35. Fujita, E.; Szalda, D. J.; Creutz, C.; Sutin, N. J. Am. Chem. Soc. 1988, 110, 4870-4871
36. Zanello, P. Inorganic Electrochemistry: Theory, Practice and Applications; Royal Society of Chemistry: Cambridge, U.K., 2003.