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Volumn 129, Issue 33, 2007, Pages 10108-10109

Rapid transfer of hydride ion from a ruthenium complex to C1 species in water

Author keywords

[No Author keywords available]

Indexed keywords

2,2' BIPYRIDINE; CARBON; HYDRIDE ION; RUTHENIUM; RUTHENIUM (2,2',6',2'' TERPYRIDINE)(2,2' BIPYRIDINE); SOLVENT; UNCLASSIFIED DRUG; WATER;

EID: 34548173428     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja074158w     Document Type: Article
Times cited : (73)

References (23)
  • 9
    • 34548161531 scopus 로고    scopus 로고
    • The hydride complex [1][PF6] was prepared as described5: 1H NMR (DMSO-d6 δ, 14.7; IR (KBr pellet) νH 1827 cm-1, νD 1292 cm-1; UV-vis 500 nm (8.5 × 103 M-1 cm-1, ESI MS in acetonitrile m/z 492.2 [Ru(terpy)(bpy)H, 102Ru, relative intensity 100% in m/z range 200-1000, The hydride complex undergoes very rapid exchange with the deuterons of D2O, CD3OD, and C2D5OD, probably via a dihydrogen complex, and reacts with acid (k < 103 M-1 s-1) to yield dihydrogen yield ≥ 60, the kinetics and mechanism of these reactions are currently under study. Manipulations were carried out under dim light. As noted by Konno et al, 5 the hydride complex is not oxygen sensitive, but must be rigorously protected from th
    • 2 in methanol for an hour, followed by evaporation to dryness. The digitized absorbance-time data from kinetics runs were least-squares-fit to an exponential function using Origin.
  • 17
    • 0003975936 scopus 로고
    • 3rd ed, R. E. Krieger: Huntington, NY
    • Walker, J. F. Formaldehyde, 3rd ed.; R. E. Krieger: Huntington, NY, 1964.
    • (1964) Formaldehyde
    • Walker, J.F.1
  • 20
    • 34548155614 scopus 로고    scopus 로고
    • Creutz, C.; Chou, M. H. unpublished work.
    • Creutz, C.; Chou, M. H. unpublished work.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.