Substrate range of the titanium TADDOLate catalyzed asymmetric fluorination of activated carbonyl compounds

Helvetica Chimica Acta

Volumn 95, Issue 3, 2012, Pages 353-403

  Bertogg, Andreas ^a   Hintermann, Lukas ^a,b   Huber, Dominique P ^a   Perseghini, Mauro ^a   Sanna, Maria ^a   Togni, Antonio ^a  

^a LABORATORY OF INORGANIC CHEMISTRY   (Switzerland)

^b TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

, , , Tetraaryl 1,3 dioxolane 4,5 diyl dimethanol; Asymmetric catalysis; Catalysis; Fluorination; Fluoroorganic compounds; TADDOL; Titanium complexes

Indexed keywords

ASYMMETRIC CATALYSIS; ASYMMETRIC FLUORINATION; BENZYL ESTERS; CHIRAL ESTERS; CHLOROMETHYL; DIASTEREOMERIC RATIOS; FLUORO-ORGANIC COMPOUNDS; FUNCTIONALIZATIONS; KETO ESTER; MODEL SUBSTRATES; OPTIMAL CONDITIONS; PHENYL ESTERS; ROOM TEMPERATURE; STEREOCHEMICAL DIFFERENTIATION; SUBSTRATE RANGE; TADDOL; TETRAFLUOROBORATES; TITANIUM COMPLEXES;

AMIDES; ESTERIFICATION; ESTERS; FLUORINATION; FLUORINE; HALOGENATION; KETONES; SUBSTRATES; TITANIUM; TITANIUM COMPOUNDS;

CATALYSIS;

AMIDE; BENZENE DERIVATIVE; BENZYL DERIVATIVE; BICYCLO COMPOUND; BORIC ACID; BUTYRIC ACID DERIVATIVE; CARBONYL DERIVATIVE; DIKETONE; ESTER DERIVATIVE; FLUORINE DERIVATIVE; LACTONE DERIVATIVE; METHANOL DERIVATIVE; NAPHTHALENE DERIVATIVE; OCTANE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; THIOESTER; TITANIUM;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYST; CHIRALITY; DIASTEREOISOMER; FLUORINATION; PRIORITY JOURNAL; REACTION ANALYSIS; ROOM TEMPERATURE; STEREOCHEMISTRY;

EID: 84859071594     PISSN: 0018019X     EISSN: 15222675     Source Type: Journal    
DOI: 10.1002/hlca.201100375     Document Type: Article

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