Probing substrate-product relationships by natural abundance deuterium 2D NMR spectroscopy in liquid-crystalline solvents: Epoxidation of linoleate to vernoleate by two different plant enzymes

Analytical and Bioanalytical Chemistry

Volumn 402, Issue 9, 2012, Pages 2985-2998

  Billault, Isabelle ^a,b   Le Du, Alicia ^a   Ouethrani, Minale ^a   Serhan, Zeinab ^b   Lesot, Philippe ^b   Robins, Richard J ^a  

^a UNIVERSITÉ DE NANTES   (France)

^b UNIVERSITÉ PARIS SUD   (France)

Author keywords

Epoxide formation; Isotope ratio profile determination; Linoleic acid; Liquid crystalline solvents; Natural abundance deuterium 2D NMR spectroscopy; Vernoleic acid

Indexed keywords

EPOXIDE FORMATION; ISOTOPE RATIO PROFILE DETERMINATION; LINOLEIC; LIQUID-CRYSTALLINE; NATURAL ABUNDANCE;

CRYSTALLINE MATERIALS; DEUTERIUM; ENZYMES; LIQUIDS; NANOCAPSULES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SITE SELECTION;

LINOLEIC ACID;

CYTOCHROME P450; DEUTERIUM; DIOXYGENASE; EPOXIDE; LINOLEIC ACID; OLEIC ACID; SOLVENT; VEGETABLE OIL; VEGETABLE PROTEIN; VERNOLIC ACID;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ENZYME SPECIFICITY; ENZYMOLOGY; EUPHORBIA; EVALUATION; LIQUID CRYSTAL; METABOLISM; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; VERNONIA;

CYTOCHROME P-450 ENZYME SYSTEM; DEUTERIUM; DIOXYGENASES; EPOXY COMPOUNDS; EUPHORBIA; LINOLEIC ACID; LIQUID CRYSTALS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; OLEIC ACIDS; OXIDATION-REDUCTION; PLANT OILS; PLANT PROTEINS; SOLVENTS; SUBSTRATE SPECIFICITY; VERNONIA;

EUPHORBIA; EUPHORBIA LAGASCAE; VERNONIA; VERNONIA GALAMENSIS;

EID: 84858705428     PISSN: 16182642     EISSN: 16182650     Source Type: Journal    
DOI: 10.1007/s00216-012-5748-6     Document Type: Article

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