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Volumn 120, Issue 5, 1998, Pages 871-876

Deciphering the cryptoregiochemistry of oleate Δ12 desaturase: A kinetic isotope effect study

Author keywords

[No Author keywords available]

Indexed keywords

ACYL COENZYME A DESATURASE; CASTOR OIL; ISOTOPE; LINOLEIC ACID; OLEIC ACID;

EID: 0032506948     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971362i     Document Type: Article
Times cited : (55)

References (53)
  • 1
    • 0008794286 scopus 로고
    • Vance, D. E., Vance, J. E., Eds.; The Benjamin Cummings Publishing Co. Ltd.: Menlo Park, CA
    • Cook, H. In Biochemistry of Lipids and Membranes; Vance, D. E., Vance, J. E., Eds.; The Benjamin Cummings Publishing Co. Ltd.: Menlo Park, CA, 1985; pp 189-203.
    • (1985) Biochemistry of Lipids and Membranes , pp. 189-203
    • Cook, H.1
  • 2
    • 0002747562 scopus 로고
    • Vance D. E., Vance, J. E., Eds.; The Benjamin Cummings Publishing Co. Ltd.: Menlo Park, CA
    • Cullis, P. R.; Hope, M. J. In Biochemistry of Lipids and Membranes; Vance, D. E., Vance, J. E., Eds.; The Benjamin Cummings Publishing Co. Ltd.: Menlo Park, CA, 1985; pp 25-72.
    • (1985) Biochemistry of Lipids and Membranes , pp. 25-72
    • Cullis, P.R.1    Hope, M.J.2
  • 19
    • 0029197421 scopus 로고
    • Additional support for such a mechanism as it applies to sMMO has recently been obtained using chiral methyl group experiments.18
    • (c) Newcomb has suggested that this species is not a true intermediate but behaves as "a component of a reacting ensemble" with a very short lifetime; accordingly it has been postulated that this type of hydrocarbon activation proceeds by "a nonsynchronous, concerted oxygen insertion" mechanism: cf., Newcomb, M.; Le Tadic-Biadetti, F. H.; Chestney, D. L.; Roberts, E. S.; Hollenberg, P. F. J. Am. Chem. Soc. 1995, 117, 12085. Additional support for such a mechanism as it applies to sMMO has recently been obtained using chiral methyl group experiments.18
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 12085
    • Newcomb, M.1    Le Tadic-Biadetti, F.H.2    Chestney, D.L.3    Roberts, E.S.4    Hollenberg, P.F.5
  • 41


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.