Hydrogenolysis of aqueous glycerol over raney nickel catalyst: Comparison of pure and biodiesel by-product

Industrial and Engineering Chemistry Research

Volumn 51, Issue 10, 2012, Pages 3863-3869

  Hoşgün, Halit L ^a   Yildiz, Mehmet ^a   Gerçel, H Ferdi ^b  

^a ESKISEHIR OSMANGAZI UNIVERSITY   (Turkey)

^b ANADOLU UNIVERSITY   (Turkey)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,2-PROPANEDIOL; AQUEOUS GLYCEROLS; BIODIESEL PRODUCTION; CRUDE GLYCEROL; HYDROGEN PRESSURES; LIQUID PRODUCTS; RANEY NICKEL CATALYSTS; REACTION CONDITIONS; STIRRING SPEED;

BIODIESEL; BYPRODUCTS; GLYCEROL; HYDROGENOLYSIS; HYDROLYSIS; LIQUIDS;

CATALYST SELECTIVITY;

EID: 84858311385     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie201781q     Document Type: Article

References (57)

1. Omer, A. M. Energy, environment and sustainable development Renewable Sustainable Energy Rev. 2008, 12, 2265
2. Shafiee, S.; Topal, E. When will fossil fuel reserves be dimished? Energy Policy 2009, 37, 181
3. Gerpen, J. V. Biodiesel processing and production Fuel Process. Technol. 2005, 86, 1097
4. Zabeti, M.; Daud, W. M. A. W.; Aroua, M. K. Biodiesel production using alumina-supported calcium oxide: An optimization study Fuel Process. Technol. 2010, 91, 243
5. http://www.ebb-eu.org/stats.php (accessed May 2011).
6. Zheng, Y.; Xiaolong, C.; Yinchu, S. Commodity Chemicals Derived from Glycerol, an Important Biorefinery Feedstock Chem. Rev. 2008, 108, 5253
7. Pagliaro, M.; Ciriminna, R.; Kimura, H.; Rossi, M.; Della Pina, C. From Glycerol to Value-Added Products Angew. Chem., Int. Ed. 2007, 46, 4434
8. 2 solid acid catalyst J. Mol. Catal. A: Chem. 2009, 310, 150
9. da Silva, C. X. A.; Goncalves, V. L. C.; Mota, C. J. A. Water-tolerant zeolite catalyst for the acetalisation of glycerol Green Chem. 2009, 11, 38
10. Kim, Y. T.; Jung, K. D.; Park, E. D. Gas-phase dehydration of glycerol over ZSM-5 catalysts Microporous Mesoporous Mater. 2010, 131, 28
11. Katryniok, B.; Paul, S.; Capron, M.; Lancelot, C.; Baca, V. B.; Reye, P.; Dumeignil, F. A long-life catalyst for glycerol dehydration to acrolein Green Chem. 2010, 12, 1922
12. Bossaert, W. D.; De Vos, D. E; Rhijn, W. M. V.; Bullen, J.; Grobet, P. J.; Jacobs, P. A. Mesoporous Sulfonic Acids as Selective Heterogeneous Catalysts for the Synthesis of Monoglycerides J. Catal. 1999, 182, 156
13. Macierzanka, A.; Szelag, H. Esterification Kinetics of Glycerol with Fatty Acids in the Presence of Zinc Carboxylates: Preparation of Modified Acylglycerol Emulsifiers Ind. Eng. Chem. Res. 2004, 43, 7744
14. Karinen, R. S.; Krause, A. O. I. New biocomponents from glycerol Appl. Catal., A 2006, 306, 128
15. Melero, J. A.; Vicente, G.; Morales, G.; Paniagua, M.; Bustamante, J. Oxygenated compounds derived from glycerol for biodiesel formulation: Influence on EN 14214 quality parameters Fuel 2010, 89, 2011
16. King, D. L.; Zhang, L.; Xia, G.; Karim, A. M.; Heldebrant, D. J.; Wang, X.; Peterson, T.; Wang, Y. Aqueous phase reforming of glycerol for hydrogen production over Pt-Re supported on carbon Appl. Catal., B 2010, 99, 206
17. Luo, N.; Fu, X.; Cao, F.; Xiao, T.; Edwards, P. P. Glycerol aqueous phase reforming for hydrogen generation over Pt catalyst-Effect of catalyst composition and reaction conditions Fuel 2008, 87, 3483
18. Demirel, S.; Lucas, M.; Warna, J.; Salmi, T.; Murzin, D.; Claus, P. Reaction kinetics and modeling of the gold catalysed glycerol oxidation Top. Catal. 2007, 44, 299
19. Porta, F.; Prati, L. Selective oxidation of glycerol to sodium glycerate with gold-on-carbon catalyst: an insight into reaction selectivity J. Catal. 2004, 224, 397
20. Pagliaro, M.; Rossi, M. Future of glycerol: New usages for a versatile as raw material, 2 nd ed.; RSC Publishing: 2010.
21. Montassier, C.; Giraud, D.; Barbier, J. Polyol Conversion by Liquid Phase Heterogeneous Catalysis over Metals Stud. Surf. Sci. Catal. 1988, 41, 165
22. Dasari, M. A.; Kiatsimkul, P. P.; Sutterlin, W. R.; Suppes, G. J. Low-pressure hydrogenolysis of glycerol to propylene glycol Appl. Catal., A 2005, 281, 225
23. Maris, E. P.; Davis, R. J. Hydrogenolysis of glycerol over carbon-supported Ru and Pt catalysts J. Catal. 2007, 249, 328
24. Lahr, D. G.; Shanks, B. H. Kinetic Analysis of the Hydrogenolysis of Lower Polyhydric Alcohols: Glycerol to Glycols Ind. Eng. Chem. Res. 2003, 42, 5467
25. Chaminand, J.; Djakovitch, L.; Gallezot, P.; Marion, P.; Pinel, C.; Rosier, C. Glycerol hydrogenolysis on heterogeneous catalysts Green Chem. 2004, 6, 359
26. Miyazawa, T.; Kusunoki, Y.; Kunimori, K.; Tomishige, K. Glycerol conversion in the aqueous solution under hydrogen over Ru/C + ion exchange resin and its reaction mechanism J. Catal. 2006, 240, 213
27. Guo, X.; Li, Y.; Shi, R.; Liu, Q.; Zhan, E.; Shen, W. Co/MgO catalysts for hydrogenolysis of glycerol to 1,2-propanediol Appl. Catal., A 2009, 371, 108
28. Marinoiu, A.; Ionita, G.; Gaspar, C. L.; Cobzoru, C.; Oprea, S. Glycerol hydrogenolysis to propylene glycol React. Kinet. Catal. Lett. 2009, 97, 315
29. Maris, E. P.; Ketchie, W. C.; Muroyama, M.; Davis, R. J. Glycerol hydrogenolysis on carbon-supported PtRu and AuRu catalysts J. Catal. 2007, 251, 281
30. Ma, L.; He, D. Hydrogenolysis of glycerol to propanediols over highly active Ru-Re bimetallic catalysts Top. Catal. 2009, 52, 834
31. Jiang, T.; Zhou, Y.; Liang, S.; Liu, H.; Han, B. Hydrogenolysis of glycerol catalyzed by Ru-Cu bimetallic catalysts supported on clay with the aid of ionic liquids Green Chem. 2009, 11, 1000
32. Meher, L. C.; Gopinath, R.; Naih, S. N.; Dalai, A. K. Catalytic hydrogenolysis of glycerol to propylene glycol over mixed oxides derived from a hydrotalcite-type precursor. Ind. Eng. Chem. Res. 2009, 48, 1840.
33. Bienholz, A.; Schwab, F.; Claus, P. Hydrogenolysis of glycerol over highly active CuO/ZnO catalyst prepared by an oxalate gel method: influence of solvent and reaction temperature on catalyst deactivation Green Chem. 2010, 12, 290
34. Feng, J.; Fu, H.; Wang, J.; Li, R.; Chen, H.; Li, X. Hydrogenolysis of glycerol to glycols over ruthenium catalysts: Effect of support and catalyst reduction temperature Catal. Commun. 2008, 9, 1458
35. Huang, Z.; Cui, F.; Kong, H.; Chen, J.; Zhang, X.; Xia, C. Highly dispersed silica supported copper nanoparticles prepared by precipitation-gel method: A simple out efficient and stable catalyst for glycerol hydrogenolysis Chem. Mater. 2008, 5090
36. Alhanash, A.; Kozheznikova, E. F.; Kozheznikov, I. V. Hydrogenolysis of glycerol to propanediol over Ru:polyoxometalate bifunctional catalyst Catal. Lett. 2008, 120, 307
37. Balaraju, M.; Rekha, V.; Prasad, P. S. S.; Prasad, R. B. N.; Lingaiah, N. Selective hydrogenolysis of glycerol to 1,2 propanediol over Cu-ZnO catalyst Catal. Lett. 2008, 126, 119
38. 2 in vapor phase Catal. Lett. 2009, 131, 312
39. Balaraju, M.; Rekha, V.; Prasad, P. S. S.; Devi, B. L. A. P.; Prasad, R. B. N.; Lingaiah, N. Influence of solid acids as co-catalysts on glycerol hydrogenolysis to 1,2 propanediol over Ru/C catalysts Appl. Catal., A 2009, 354, 82
40. Vasiliadou, E. S.; Heracleous, E.; Vasolos, I. A.; Lemanidou, A. A. Ru based catalysts for glycerol hydrogenolysis-Effect of support and metal precursor Appl. Catal., B 2009, 92, 90
41. Guo, L.; Zhou, J.; Mao, J.; Guo, X.; Zhang, S. Supported Cu catalysts for the selective hydrogenolysis of glycerol to propanediols Appl. Catal., A 2009, 367, 93
42. Yuan, Z.; Wong, J.; Wong, L.; Xie, W.; Chen, P.; Hou, Z.; Zhang, X. Biodiesel derived glycerol hydrogenolysis to 1,2-propanediol on Cu/MgO catalyst Bioresour. Technol. 2010, 101, 7088
43. Bolado, S.; Trevino, R. E.; Garcia-Cubero, M. T.; Gonzales-Benito, G. Glycerol hydrogenolysis to 1,2 propanediol over Ru/C catalyst Catal. Commun. 2010, 12, 122
44. Zheng, J.; Zhu, W.; Ma, C.; Hou, Y.; Zhang, W.; Wang, Z. Hydrogenolysis of glycerol to 1,2 propanediol on the high dispersed SBA-15 supported copper catalyst prepared by ion exchange method React. Kinet., Mech. Catal. 2010, 99, 455
45. Zhou, J.; Guo, L.; Guo, X.; Maoa, J.; Zhang, S. Selective hydrogenolysis of glycerol to propanediols on supported Cu-containing bimetallic catalysts Green Chem. 2010, 12, 1835
46. Mane, R. B.; Hengne, A. M.; Ghalwadkar, A. A.; Vijayanand, S.; Mohite, P. H.; Potdar, H. S.; Chandrashekhar, V. R. Cu:Al Nano catalyst for selective hydrogenolysis of glycerol to 1,2 propanediol Catal. Lett. 2010, 135, 141
47. Mukhopadhyay, S.; Chandnani, K. H.; Chandalia, S. B. Kinetics of highly selective catalytic hydrogenation of 2,3,5-trimethylbenzoquinone on Raney nickel catalyst Org. Process Res. Dev. 2000, 4, 254
48. Hoffer, B. W.; Schoenmakers, P. H. J.; Mooijmen, P. R. M.; Hamminga, G. M.; Berger, R. J.; van Langeveld, A. D.; Moulijn, J. A. Mass transfer and kinetics of the three-phase hydrogenation of a dinitrile over a Raney-type nickel catalyst Chem. Eng. Sci. 2004, 59, 259
49. Bowane, S. P.; Sawent, S. B. Reaction kinetics of the liquid phase hydrogenation of benzonitrile to benzylamine using Raney nickel catalyst Chem. Eng. J. 2004, 103, 13
50. Perosa, A.; Tundo, P. Selective Hydrogenolysis of Glycerol with Raney Nickel Ind. Eng. Chem. Res. 2005, 44, 8535
51. da Silva, C. X. A.; Mota, C. J. A. The influence of impurities on the acid-catalyzed reaction of glycerol with acetone Biomass Bioenergy 2011, 35, 3547
52. Manosak, R.; Limpattayanate, S.; Hunsom, M. Sequential-refining of crude glycerol derived from waste used-oil methyl ester plant via a combined process of chemical and adsorption Fuel Process. Technol. 2011, 92, 92
53. Maglinao, R. L.; He, B. B. Catalytic thermochemical conversion of glycerol to simple and polyhydric alcohols using raney nickel catalyst Ind. Eng. Chem. Res. 2011, 50, 6028
54. Torres, A.; Roy, D.; Subramaniam, B.; Chaudhari, R. V. Kinetic modeling of aqueous-phase glycerol hydrogenolysis in a batch slurry reactor Ind. Eng. Chem. Res. 2010, 49, 10826
55. Roy, D.; Subramaniam, B. Chaudhari. Aqueous phase hydrogenolysis of glycerol to 1,2-propanediol without external hydrogen addition Catal. Today 2010, 156, 31
56. 2 Fuel Process. Technol. 2011, 92, 330
57. Huang, L.; Zhu, Y. L.; Zheng, H. Y.; Li, Y. W.; Zeng, Z. Y. Continuous production of 1,2-propanediol by the selective hydrogenolysis of solvent-free glycerol under mild conditions J. Chem. Technol. Biotechnol. 2008, 83, 1670