Catalytic thermochemical conversion of glycerol to simple and polyhydric alcohols using raney nickel catalyst

Industrial and Engineering Chemistry Research

Volumn 50, Issue 10, 2011, Pages 6028-6033

  Maglinao, Randy L ^a   He, B Brian ^a  

^a UNIVERSITY OF IDAHO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIODIESEL INDUSTRY; BIODIESEL PRODUCTION; CRUDE GLYCEROL; ECONOMIC VALUES; POLYHYDRIC ALCOHOL; PRESSURE REACTORS; PRIMARY ALCOHOLS; PROPYLENE GLYCOLS; RANEY NICKEL CATALYSTS; REACTION TIME; THERMO CHEMICAL PROCESS; THERMOCHEMICAL CONVERSION;

BIODIESEL; ETHANOL; GLYCEROL; GLYCOLS; HYDROGEN; HYDROGENOLYSIS; HYDROLYSIS; ORGANIC POLYMERS; PROPYLENE; WATER CONTENT;

CATALYSTS;

EID: 79955906219     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie102573m     Document Type: Article

References (27)

1. Biofuels Market to Triple by 2020, Jun. 15, 2009. Biodiesel Magazine, http://www.biodieselmagazine.com (accessed Aug. 7, 2010).
2. Lefebvre, B. Glycerine (US Gulf) ICIS Pricing, June 2010, ICIS Pricing, www.icispricing.com (accessed Dec. 20, 2010).
3. Hartenbower, B.; French, W.; Hernandez, R.; Licha, M.; Benson, T. Biogas Production Using Glycerol, the Biodiesel By-Product, as the Carbon Source, http://aiche.confex.com/aiche/2006/techprogram (accessed Apr. 25, 2010), The 2006 Annual Meeting: Fuels and Petrochemical Division.
4. Allhanash, A.; Koszhevnikova, E.; Kozhevnikov, I. Hydrogenolysis of Glycerol to Propanediol over Ru:Polyoxymetalate Bifunctional Catalyst Catal. Lett. 2008, 120, 307
5. Huang, Z.; Cui, F.; Kang, H.; Chen, J.; Zhang, X.; Xia, C. Highly Dispersed Silica-Supported Copper Nanoparticles Prepared by Precipitation-Gel Method: A Simple but Efficient and Stable Catalyst for Glycerol Hydrogenolysis Chem. Mater. 2008, 20, 5090
6. Maris, E.; Davis, R. Hydrogenolysis of Glycerol over Carbon-supported Ru and Pt Catalysts J. Catal. 2007, 249, 328
7. Meher, L.; Gopinath, R.; Naik, S.; Dalai, A. Catalytic Hydrogenolysis of Glycerol to Propylene Glycol over Mixed Oxides Derived from a Hydrotalcite-type Precursor Ind. Eng. Chem. Res. 2009, 48, 1840
8. Miyazawa, T.; Koso, S.; Kunimoro, K.; Tomishige, K. Glycerol Hydrogenolysis to 1,2-Propanediol Catalyzed by a Heat-Resistant Ion-Exchange Resin Combined with Ru/C Appl. Catal., A 2007, 329, 30
9. Chiu, C.; Dasari, M.; Suppes, G.; Sutterlin, W. Dehydration of Glycerol to Acetol via Catalytic Reactive Distillation AIChE J. 2006, 52, 3543
10. Chiu, C.; Tekeei, A.; Ronco, J.; Banks, M.; Suppes, G. Reducing Byproduct Formation during Conversion of Glycerol to Propylene Glycol Ind. Eng. Chem. Res. 2008, 47, 6878
11. Suppes, G.; Sutterlin, W. Method of Producing Lower Alcohols from Glycerol. World Intellectual Property Organization, WO 2007/053705 A2, 2007.
12. Wojcik, B.; Adkins, H. Hydrogenolysis of Alcohols to Hydrocarbons J. Am. Chem. Soc. 1933, 55, 1293
13. Hirai, T.; Ikenaga, N.; Miyake, T.; Suzuki, T. Production of Hydrogen by Steam Reforming of Glycerin on Ruthenium Catalyst Energy Fuels 2005, 19, 1761
14. Slinn, M.; Kendall, K.; Mallon, C.; Andrews, J. Steam Reforming of Bio-diesel By-product to Make Renewable Hydrogen Bioresour. Technol. 2008, 99, 5851
15. Valliyappan, T.; Ferdous, D.; Bakhshi, N. Production of Hydrogen and Syngas via Steam Gasification in a Fixed-Bed Reactor Top. Catal. 2008, 49, 59
16. Zhang, B.; Tang, X.; Li, Y.; Xu, Y.; Shen, W. Hydrogen Production from Steam Reforming of Ethanol and Glycerol over Ceria-Supported Metal Catalysts Int. J. Hydrogen Energy 2007, 32, 2367
17. Buffoni, I.; Pompeo, F.; Santori, G.; Nichio, N. Nickel Catalysts Applied in Steam Reforming of Glycerol for Hydrogen Production Catal. Commun. 2009, 10, 1656
18. Dauenhauer, P.; Salge, J.; Schmidt, L. Renewable Hydrogen by Autothermal Steam Reforming of Volatile Carbohydrates J. Catal. 2006, 244, 238
19. Luo, N.; Fu, X.; Cao, F.; Xiao, T.; Edwards, P. Glycerol Aqueous Phase Reforming for Hydrogen Generation over Pt Catalysts-Effect of Catalyst Composition and Reaction Conditions Fuel 2008, 87, 3483
20. Adhikari, S.; Fernando, S.; Gwaltney, S. R.; Filip To, S. D.; Bricka, R. M.; Steele, P.; Haryanto, A. A Thermodynamic Analysis of Hydrogen Production by Steam Reforming of Glycerol Int. J. Hydrogen Energy 2007, 32, 2875
21. Adhikari, S.; Fernando, S.; Haryanto, A. A Comparative Thermodynamic and Experimental Analysis on Hydrogen Production by Steam Reforming of Glycerin Energy Fuels 2007, 21, 2306
22. Adhikari, S.; Fernando, S.; Haryanto, A. Production of Hydrogen by Steam Reforming of Glycerin over Alumina-Supported Metal Catalysts Catal. Today 2007, 129, 355
23. Adhikari, S.; Fernando, S.; To, S.; Bricka, R.; Steele, P.; Haryanto, A. Conversion of Glycerol to Hydrogen via a Steam Reforming Process over Nickel Catalysts Energy Fuels 2008, 22, 1220
24. Wen, G.; Xu, Y.; Ma, H.; Xu, Z.; Tian, Z. Production of Hydrogen by Aqueous-Phase Reforming of Glycerol Int. J. Hydrogen Energy 2008, 33, 6657
25. Hodgman, C.; Weast, R. S.; Selby, S. CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data, 44 th ed.; Chemical Rubber: Cleveland, OH, 1962.
26. Miall, L. A New Dictionary of Chemistry, 3 rd ed.; InterScience: New York, 1961.
27. Starling, K.; Han, M. Thermo Data Refined for LPG-14. Mixtures Hydrocarbon Process. (1966-2001) 1972, 51, 129-132