The influence of impurities on the acid-catalyzed reaction of glycerol with acetone

Biomass and Bioenergy

Volumn 35, Issue 8, 2011, Pages 3547-3551

  da Silva, Carolina X A ^a   Mota, Claudio J A ^a  

^a FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

Author keywords

2,2 dimethyl 1,3 dioxolan 4 yl)methanol; Biodiesel; Catalysis; Impurities; Propan 1,2,3 triol

Indexed keywords

2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)METHANOL; ACID CATALYST; ACID-CATALYZED REACTIONS; AMBERLYST-15; BIODIESEL PRODUCTION; PROPAN-1,2,3-TRIOL; ZEOLITE BETA;

ACETONE; BIODIESEL; CATALYSIS; IMPURITIES; INDUSTRIAL PLANTS; METHANOL; SODIUM; SODIUM CHLORIDE; WATER CONTENT;

GLYCEROL;

ACETONE; ACID; ALCOHOL; BIOFUEL; CATALYSIS; CATALYST; CHLORIDE; ZEOLITE;

EID: 79960371945     PISSN: 09619534     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biombioe.2011.05.004     Document Type: Article

References (31)

1. Meher L.C., Sagar D.V., Naik S.N. Technical aspects of biodiesel produced by transesterification: a review. Renew Sustain Energy Rev 2006, 10:248-268.
2. Zhou C.H., Beltramini J.N., Fan Y.X., Lu G.Q. Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals. Chem Soc Rev 2008, 37:527-549.
3. Behr A., Eilting J., Irawadi K., Leschinski J., Lindner F. Improved utilisation of renewable resources: new important derivatives of glycerol. Green Chem 2008, 10:13-30.
4. Jérôme F., Pouilloux Y., Barrault J. Rational design of solid catalysts for the selective use of glycerol as a natural organic building block. ChemSusChem 2008, 1:586-613.
5. Pagliaro M., Ciriminna R., Kimura H., Rossi M., Pina C.D. From glycerol to value-added products. Angew Chem Int Ed 2007, 46:4434-4440.
6. Dasari M.A., Kiatsimkul P.P., Sutterlin W.R., Suppes G.J. Low-pressure hydrogenolysis of glycerol to propylene glycol. Appl Catal A 2005, 281:225-231.
7. Kusunoki Y., Miyazawa T., Kunimori K., Tomishige K. Highly active metal-acid bifunctional catalyst system for hydrogenolysis of glycerol under mild reaction conditions. Catal Commun 2005, 6:645-649.
8. Miyazawa T., Kusunoki Y., Kunimori K., Tomishige K. Glycerol conversion in the aqueous solution under hydrogen over Ru/C plus an ion-exchange resin and its reaction mechanism. J Catal 2006, 240:213-221.
9. 5 catalyst. J Catal 2007, 250:342-349.
10. Tsukuda E., Sato S., Takahashi R., Sodesawa T. Production of acrolein from glycerol over silica-supported heteropoly acids. Catal Commun 2007, 8:1349-1353.
11. Simonetti D.A., Rass-Hansen J., Kunkes E.L., Soares R.R., Dumesic J.A. Coupling of glycerol processing with Fischer-Tropsch synthesis for production of liquid fuels. Green Chem 2007, 9:1073-1083.
12. Soares R.R., Simonetti D.A., Dumesic J.A. Glycerol as a source for fuels and chemicals by low-temperature catalytic processing. Angew Chem Int Ed 2006, 45:3982-3985.
13. Gu Y., Azzouzi A., Pouilloux Y., Jerome F., Barrault J. Heterogeneously catalyzed etherification of glycerol: new pathways for transformation of glycerol to more valuable chemicals. Green Chem 2008, 10:164-167.
14. da Silva C.R.B., Gonçalves V.L.C., Lachter E.R., Mota C.J.A. Etherification of glycerol with benzyl alcohol catalyzed by solid acids. J Braz Chem Soc 2009, 20:201-204.
15. Klepacova K., Mravec D., Bajus M. tert-butylation of glycerol catalysed by ion-exchange resins. Appl Catal A 2005, 294:141-147.
16. Cho G.H.P., Yeong S.K., Ooi T.L., Chuah C.H. Glycerol esters from the reaction of glycerol with dicarboxylic acid esters. J Surf Deter 2006, 9:147-152.
17. Gonçalves V.L.C., Pinto B.P., da Silva J.C., Mota C.J.A. Acetylation of glycerol catalyzed by different solid acids. Catal Today 2008, 133-135:673-677.
18. Silva L.N., Gonçalves V.L.C., Mota C.J.A. Catalytic acetylation of glycerol with acetic anhydride. Catal Commun 2010, 11:1036-1039.
19. Luque R., Budarin V., Clark J.H., Macquirre D.J. Glycerol transformation on polysaccharide derived mesoporous materials. Appl Catal B 2008, 82:157-162.
20. Climent M.J., Velty A., Corma A. Design of a solid catalyst for the synthesis of a molecule with blossom orange scent. Green Chem 2002, 4:565-569.
21. Climent M.J., Corma A., Veltry A. Synthesis of hyacinth, vanilla, and blossom orange fragrances: the benefit of using zeolites and delaminated zeolites as catalysts. Appl Catal A 2004, 263:155-161.
22. da Silva C.X.A., Gonçalves V.L.C., Mota C.J.A. Water-tolerant zeolite catalyst for the acetalisation of glycerol. Green Chem 2009, 11:38-41.
23. Deusch J., Martin A., Lieske H. Investigations on heterogeneously catalysed condensations of glycerol to cyclic acetals. J Catal 2007, 245:428-435.
24. Karinen R.S., Krause A.O.I. New biocomponents from glycerol. Appl Catal A 2006, 306:128-133.
25. Garcia E., Laca M., Perez E., Garrido A., Peinado J. New class of acetal derived from glycerin as a biofuel component. Energy Fuel 2008, 22:4274-4280.
26. Silva P.H.R., Gonçalves V.L.C., Mota C.J.A. Glycerol acetals as anti-freezing additives for biodiesel. Bioresour Technol 2010, 101:6225-6229.
27. Mota C.J.A., da Silva C.X.A., Rosenbach N., Costa J., da Silva F. Glycerin derivatives as fuel additives: the addition of glycerol/acetone ketal(solketal) in gasolines. Energy Fuels 2010, 24:2733-2736.
28. Okuhara T. Water-tolerant solid acid catalysts. Chem Rev 2002, 102:3641-3666.
29. Lynden-Bell R.M., Rasaiah J.C. Mobility and solvations of ions in channels. J Chem Phys 1996, 105:9266-9280.
30. Carmona M., Valverde J.R., Perez A., Warchol J., Rodrigues J.F. Purification of glycerol/water solutions from biodiesel synthesis by ion exchange: sodium removal part I. J Chem Tech Biotech 2009, 84:738-744.
31. Carmona M., Lech A., de Lucas A., Perez A., Rodrigues J.F. Purification of glycerol/water solutions from biodiesel synthesis by ion exchange: sodium and chloride removal Part II. J Chem Tech Biotech 2009, 84:1130-1135.