Formation of a germylyne complex: Dehydrogenation of a hydrido(hydrogermylene)tungsten complex with mesityl isocyanate

Angewandte Chemie - International Edition

Volumn 51, Issue 12, 2012, Pages 2930-2933

  Hashimoto, Hisako ^a   Fukuda, Tetsuya ^a   Tobita, Hiromi ^a   Ray, Mausumi ^b,d   Sakaki, Shigeyoshi ^c  

^a TOHOKU UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

^c KYOTO UNIVERSITY   (Japan)

^d NORTHWESTERN UNIVERSITY   (United States)

Author keywords

germanium; germylene complexes; germylyne complexes; multiple bonds; tungsten

Indexed keywords

COMPLEX 1; DFT CALCULATION; GERMYLENES; GERMYLYNE COMPLEXES; KINETIC STUDY; MULTIPLE BONDS; ROOM TEMPERATURE; TUNGSTEN COMPLEX;

DEHYDROGENATION; DENSITY FUNCTIONAL THEORY; GERMANIUM; TUNGSTEN;

TUNGSTEN COMPOUNDS;

EID: 84858207412     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201107501     Document Type: Article

References (26)

1. A. C. Filippou, O. Chernov, K. W. Stumpf, G. Schnakenburg, Angew. Chem. 2010, 122, 3368-3372
2. Angew. Chem. Int. Ed. 2010, 49, 3296-3300
3. a transition-metal complex having a considerable silylyne character is reported in:, B. V. Mork, T. D. Tilley, Angew. Chem. 2003, 115, 371-374
4. Angew. Chem. Int. Ed. 2003, 42, 357-360.
5. R. S. Simons, P. P. Power, J. Am. Chem. Soc. 1996, 118, 11966-11967
6. L. Pu, B. Twamley, S. T. Haubrich, M. M. Olmstead, B. V. Mork, R. S. Simons, P. P. Power, J. Am. Chem. Soc. 2000, 122, 650-656
7. A. C. Filippou, A. I. Philippopoulos, P. Portius, D. U. Neumann, Angew. Chem. 2000, 112, 2881-2884
8. Angew. Chem. Int. Ed. 2000, 39, 2778-2781
9. A. C. Filippou, P. Portius, A. I. Philippopoulos, Organometallics 2002, 21, 653-661
10. A. C. Filippou, G. Schnakenburg, A. I. Philippopoulos, N. Weidemann, Angew. Chem. 2005, 117, 6133-6139
11. Angew. Chem. Int. Ed. 2005, 44, 5979-5985
12. A. C. Filippou, N. Weidemann, A. I. Philippopoulos, G. Schnakenburg, Angew. Chem. 2006, 118, 6133-6137
13. Angew. Chem. Int. Ed. 2006, 45, 5987-5991.
14. A. C. Filippou, P. Portius, A. I. Philippopoulos, H. Rohde, Angew. Chem. 2003, 115, 461-464
15. Angew. Chem. Int. Ed. 2003, 42, 445-447
16. A. C. Filippou, A. I. Philippopoulos, G. Schnakenburg, Organometallics 2003, 22, 3339-3341.
17. A. C. Filippou, H. Rohde, G. Schnakenburg, Angew. Chem. 2004, 116, 2293-2297
18. Angew. Chem. Int. Ed. 2004, 43, 2243-2247
19. A. C. Filippou, N. Weidemann, G. Schnakenburg, H. Rohde, A. I. Philippopoulos, Angew. Chem. 2004, 116, 6674-6678
20. Angew. Chem. Int. Ed. 2004, 43, 6512-6516
21. A. C. Filippou, N. Weidemann, G. Schnakenburg, Angew. Chem. 2008, 120, 5883-5886
22. Angew. Chem. Int. Ed. 2008, 47, 5799-5802.
23. H. Hashimoto, T. Tsubota, T. Fukuda, H. Tobita, Chem. Lett. 2009, 38, 1196-1197.
24. H. Hashimoto, T. Fukuda, H. Tobita, New J. Chem. 2010, 34, 1723-1730.
25. G. C. Vougioukalakis, R. G. Grubbs, J. Am. Chem. Soc. 2008, 130, 2234-2245.
26. Translational entropy was evaluated according to:, M. Mammen, E. I. Shakhnovich, J. M. Deutch, G. M. Whitesides, J. Org. Chem. 1998, 63, 3821-3830.