Entropy-controlled and enantiodivergent Lewis acid catalysis in water

Synthesis

Volumn 44, Issue 6, 2012, Pages 848-856

  Aplander, Karolina ^a   Lindström, U Marcus ^b   Wennerberg, Johan ^c  

^a LUND UNIVERSITY   (Sweden)

^b MCGILL UNIVERSITY   (Canada)

^c DUPONT COMPANY   (United States)

Author keywords

catalysis; enantioselective; Lewis acid; Michael reaction; water

Indexed keywords

AQUEOUS MEDIUM; AQUEOUS SOLVATION; ASYMMETRIC CATALYSIS; ENANTIOSELECTIVE; GREEN CHEMISTRY; LEWIS ACID; LEWIS ACID CATALYSIS; MICHAEL ADDITION REACTIONS; MICHAEL REACTIONS; RATE ACCELERATION; REACTION TEMPERATURE; RESOURCE EFFICIENCIES; STEREOSPECIFIC; THERMODYNAMIC ACTIVATION PARAMETERS; TRANSITION STATE;

ADDITION REACTIONS; AMINO ACIDS; CATALYSIS; ENANTIOMERS; ENTROPY; SOLVATION; WATER; YTTERBIUM;

ENANTIOSELECTIVITY;

ALPHA AMINO ACID; LEWIS ACID; WATER; YTTERBIUM;

AQUEOUS SOLUTION; ARTICLE; ASYMMETRIC CATALYSIS; CONTROLLED STUDY; DIASTEREOISOMER; ENANTIOSELECTIVITY; ENTROPY; MICHAEL ADDITION; SOLVATION; STEREOSPECIFICITY; TEMPERATURE; THERMODYNAMICS;

EID: 84858080916     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1289725     Document Type: Article

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