Development of Solid Contact Micropipette Zn-Ion Selective Electrode for Corrosion Studies

Analytical Letters

Volumn 44, Issue 18, 2011, Pages 2876-2886

  Varga, Ágnes ^a   Nagy, Lívia ^a   Izquierdo, Javier ^b   Bitter, István ^c   Souto, Ricardo M ^b   Nagy, Géza ^a,b  

^a UNIVERSITY OF PÉCS   (Hungary)

^b UNIVERSIDAD DE LA LAGUNA   (Spain)

^c BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

Author keywords

Corrosion; SECM; Zinc ion selective electrode

Indexed keywords

EID: 84857738959     PISSN: 00032719     EISSN: 1532236X     Source Type: Journal    
DOI: 10.1080/00032719.2011.582545     Document Type: Article

References (28)

1. Amman, D., E. Pretsch, W. Simon, E. Lindner, E. Bezegh, and E. Pungor. 1985. Liophilic salts as membrane additives and their influence on the properties of macro- and micro-electrodes based on neutral carriers. Anal. Chim. Acta 171: 119 - 129.
2. Bastos, A. C., A. M. Simões, S. González, Y. González-García, and R. M. Souto. 2004. Imaging concentration profiles of redox-active species in open-circuit corrosion processes with the scanning electrochemical microscope. Electrochem. Comm. 6: 1212 - 1215.
3. 2+ relevant to corrosion studies. Electrochem. Comm. 12: 394 - 397.
4. Csóka, B., B. Kovács, and G. Nagy. 2003. Investigation of concentration profiles inside operating biocatalytic sensors with scanning electrochemical microscopy (SECM). Biosens. Bioelectron. 18: 141 - 149.
5. Denuault, G., G. Nagy, and K. Toth. 2001. Potentiometric probes in Scanning Electrochemical Microscopy, eds. A. J. Bard and M. V. Mirkin. New York: Marcel Dekker.
6. Gabrielli, C., E. Ostermann, H. Perrot, V. Vivier, L. Beitone, and C. Mace. 2005. Concentration mapping around copper microelectrodes studied by scanning electrochemical microscopy. Electrochem. Commun. 7: 962 - 968.
7. González-García, Y., G. T. Burstein, S. González, and R. M. Souto. 2004. Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential. Electrochem. Comm. 6: 637 - 642.
8. González-García, Y. 2007. Degradation of anticorrosive polymeric coatings applied on metallic materials: Electrochemical and nanoscopic research. Ph.D. Thesis. University of La Laguna (Tenerife, Spain). Ch. 5.
9. González-García, Y., J. J. Santana, J. González-Guzmán, J. Izquierdo, S. González, and R. M. Souto. 2010. Scanning electrochemical microscopy for the investigation of localized degradation processes in coated metals. Progress Org. Coatings 69: 110 - 117.
10. 2+ determination. Sensors 3: 223 - 235.
11. Gyetvai, G., L. Nagy, A. Ivaska, I. Hernadi, and G. Nagy. 2009. Solid contact micropipette ion selective electrode for potentiometric SCEM. II: Potassium electrode. Electroanalysis21: 970-1976.
12. Gyetvai, G., S. Sundblom, L. Nagy, A. Ivaska, and G. Nagy. 2007. Solid contact micropipette ion selective electrode for potentiometric SECM. Electroanalysis 19: 1116 - 1122.
13. Lamaka, S. V., R. M. Souto, and M. G. S. Ferreira. 2010. In-situ visualization of local corrosion by scanning ion-selective electrode technique (SIET). In Microscopy: Science, technology, applications and education, vol. 4, eds. A. Méndez-Vilas and J. Díaz. Badajoz, Spain: Formatex Research Center.
14. Lindner, E., M. Horváth, K. Tóth, E. Pungor, I. Bitter, B. Ágai, and L. Tõke. 1992. Zinc selective ionophores for potentiometric and optical sensors. Anal. Lett. 25: 453 - 470.
15. Messerli, M. A., L. P. Collis, and P. J. S. Smith. 2009a. Ion trapping with fast-response ion-selective microelectrodes enhances detection of extracellular ion channel gradients. Biophys. J. 96: 1597 - 1605.
16. Messerli, M. A., L. P. Collis, and P. J. S. Smith. 2009b. Fast response, noninvasive, potentiometric microelectrodes resolve single potassium channel activity in the diffusive boundary layer of a single cell. Electroanalysis 21: 1906 - 1913.
17. Niu, L., Y. Yin, W. Guo, M. Lu, R. Qin, and S. Chen. 2009. Application of scanning electrochemical microscope in the study of corrosion of metals. J. Mater. Sci. 44: 4511 - 4521.
18. Ogle, K., S. Morel, and D. Jacquet. 2006. Observation of self-healing functions on the cut edge of galvanized steel using SVET and pH microscopy. J. Electrochem. Soc. 153: B1 - B5.
19. Pust, S. E., W. Maier, and G. Wittstock. 2008. Investigation of localized catalytic and electrocatalytic processes and corrosion reactions with scanning electrochemical microscopy (SECM). Z. Physikal. Chem. 222: 1463 - 1517.
20. Santana, J. J., J. González-Guzmán, L. Fernández-Mérida, S. González, and R. M. Souto. 2010. Visualization of local degradation processes in coated metals by means of scanning electrochemical microscopy in the redox competition mode. Electrochim. Acta 55: 4488 - 4494.
21. Simões, A. M., A. C. Bastos, M. G. Ferreira, Y. González-García, S. González, and R. M. Souto. 2007. Use of SVET and SECM to study the galvanic corrosion of an iron-zinc cell. Corros. Sci. 49: 726 - 739.
22. Simões, A. M., J. Torres, R. Picciochi, J., and C. S. Fernandes. 2009. Corrosion inhibition at galvanized steel cut edges by phosphate pigments. Electrochim. Acta 54: 3857 - 3865.
23. Souto, R. M., Y. González-García, A. C. Bastos, and A. M. Simões. 2007. Investigating corrosion processes in the micrometric range: A SVET study of the galvanic corrosion of zinc coupled with iron. Corros. Sci. 49: 4568 - 4580.
24. Souto, R. M., L. Fernández-Mérida, and S. González. 2009. SECM imaging of interfacial processes in defective organic coatings applied on metallic substrates using oxygen as redox mediator. Electroanalysis 21: 2640 - 2646.
25. Souto, R. M., S. V. Lamaka, and S. González. 2010. Uses of scanning electrochemical microscopy in corrosion research. In Microscopy: Science, technology, applications and education, vol. 4, eds. A. Méndez-Vilas and J. Díaz. Badajoz, Spain: Formatex Research Center.
26. Volker, E., C. G. Inchauspe, and E. J. Calvo. 2006. Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel. Electrochem. Comm. 8: 179 - 183.
27. Wei, Ch., A. J. Bard, G. Nagy, and K. Tóth. 1995. Scanning electrochemical microscopy. 28. Ion-selective neutral carrier-based microelectrode potentiometry. Anal. Chem. 67: 1346 - 1356.
28. Zamani, H. A., M. R. Ganjali, and M. J. Pooyamanesh. 2006. Zinc(II) PVC-based membrane sensor based on 5,6-benzo-4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8,8,8]hexacos-5-ene. J. Braz. Chem. Soc. 17: 149 - 155.