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Volumn 14, Issue 2, 2012, Pages 490-494

Catalytic decarbonylation of biomass-derived carboxylic acids as efficient route to commodity monomers

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EID: 84857180358     PISSN: 14639262     EISSN: 14639270     Source Type: Journal    
DOI: 10.1039/C2GC16115J     Document Type: Article
Times cited : (53)

References (36)
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    • Clostridia enzymatically produce hydrocinnamic acid from l-phenylalanine. See
    • Clostridia enzymatically produce hydrocinnamic acid from l-phenylalanine. See C. W. Moss M. A. Lambert D. J. Goldsmith Appl. Microbiol. 1970 19 375-378.
    • (1970) Appl. Microbiol. , vol.19 , pp. 375-378
    • Moss, C.W.1    Lambert, M.A.2    Goldsmith, D.J.3
  • 12
    • 85034381910 scopus 로고    scopus 로고
    • Hydrocinnamic acid can also be prepared from cinnamaldehyde, a renewable resource. See, 5 939 581
    • Hydrocinnamic acid can also be prepared from cinnamaldehyde, a renewable resource. See A. J. Muller, J. S. Bowers, J. R. I. Eubanks, C. C. Geiger and J. G. Santobianco, US Pat., 5 939 581, 1999.
    • (1999) US Pat.
    • Muller, A.J.1    Bowers, J.S.2    Eubanks, J.R.I.3    Geiger, C.C.4    Santobianco, J.G.5
  • 13
    • 79953832583 scopus 로고    scopus 로고
    • 3-cyanopropanoic acid can be prepared from glutamic acid, a biorenewable resource. See
    • 3-cyanopropanoic acid can be prepared from glutamic acid, a biorenewable resource. See J. Le Nôtre E. L. Scott M. C. R. Franssen J. P. N. Sanders Green Chem. 2011 13 807-809.
    • (2011) Green Chem. , vol.13 , pp. 807-809
    • Le Nôtre, J.1    Scott, E.L.2    Franssen, M.C.R.3    Sanders, J.P.N.4
  • 22
    • 2642654941 scopus 로고
    • Wiley & Sons, New York
    • J. Cason, Organic Syntheses, Wiley & Sons, New York, 1955, vol III, pp 169.
    • (1955) Organic Syntheses , vol.3 , pp. 169
    • Cason, J.1
  • 30
    • 85034358941 scopus 로고    scopus 로고
    • The separation of styrene from pivalic acid and pivalic anhydride through fractional distillation was unsuccessful due to co-distillation of styrene and pivalic acid and polymerization of styrene
    • The separation of styrene from pivalic acid and pivalic anhydride through fractional distillation was unsuccessful due to co-distillation of styrene and pivalic acid and polymerization of styrene.
  • 33
    • 85034386722 scopus 로고    scopus 로고
    • 2O, and ligands were left open to the atmosphere for 24 h. The hydrocinnamic acid was used as received without purification and left open to the atmosphere for 4 months
    • 2O, and ligands were left open to the atmosphere for 24 h. The hydrocinnamic acid was used as received without purification and left open to the atmosphere for 4 months.
  • 34
    • 85034346221 scopus 로고    scopus 로고
    • 2O, and ligands were left open to the atmosphere for 48 h. The hydrocinnamic acid was used as received without purification and left open to the atmosphere for 4 months
    • 2O, and ligands were left open to the atmosphere for 48 h. The hydrocinnamic acid was used as received without purification and left open to the atmosphere for 4 months.
  • 35
    • 37049129819 scopus 로고
    • The bio-derived substrates levulinic acid, α- and β-angelica lactone can be decarbonylated to methyl vinyl ketone over a solid acid catalyst at high temperatures (290–500 °C), (see J. A. Dumesic, and R. M. West, US Pat. 7 960 592, 2011) as well as photochemically (see,) and in the gas phase through a quartz tube at high temperatures (above 500 °C)
    • The bio-derived substrates levulinic acid, α- and β-angelica lactone can be decarbonylated to methyl vinyl ketone over a solid acid catalyst at high temperatures (290–500 °C), (see J. A. Dumesic, and R. M. West, US Pat. 7 960 592, 2011) as well as photochemically (see O. L. Chapman C. L. McIntosh J. Chem. Soc. D 1971 383-384.) and in the gas phase through a quartz tube at high temperatures (above 500 °C).
    • (1971) J. Chem. Soc. D , pp. 383-384
    • Chapman, O.L.1    McIntosh, C.L.2


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