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Volumn 134, Issue 4, 2012, Pages 1914-1917

Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing

Author keywords

[No Author keywords available]

Indexed keywords

CARBON-CARBON BOND; CYCLOADDITION TRANSITION; CYCLOADDITIONS; DICHLOROKETENE; DIELS-ALDER REACTION; ENERGY SURFACE; ENTROPIC BARRIER; ISOTOPE EFFECT; KINETIC ISOTOPE EFFECTS; ORGANOCATALYTIC; RATE LIMITING; RATE-LIMITING STEPS; STATISTICAL MODELS; TRANSITION STATE;

EID: 84856466877     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja208779k     Document Type: Article
Times cited : (88)

References (22)
  • 15
    • 77949369386 scopus 로고    scopus 로고
    • The trajectory times are very long compared to ordinary cycloadditions. See: Xu, L.; Doubleday, C. E.; Houk, K. N. J. Am. Chem. Soc. 2010, 132, 3029-3037
    • (2010) J. Am. Chem. Soc. , vol.132 , pp. 3029-3037
    • Xu, L.1    Doubleday, C.E.2    Houk, K.N.3
  • 16
    • 77952600723 scopus 로고    scopus 로고
    • Recent work has used "hidden" to describe prospective transition states that might arise if a reaction is changed. Kraka, E.; Cremer, D. Acc. Chem. Res. 2010, 43, 591-601
    • (2010) Acc. Chem. Res. , vol.43 , pp. 591-601
    • Kraka, E.1    Cremer, D.2
  • 22
    • 84856456452 scopus 로고    scopus 로고
    • POLYRATE -version 2010; University of Minnesota: Minneapolis, MN
    • Zheng, J.; POLYRATE -version 2010; University of Minnesota: Minneapolis, MN, 2010.
    • (2010)
    • Zheng, J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.