Thiosemicarbazonates of palladium(II): The presence of methyl/phenyl substituents (R 2) at C 2 carbon atom induces C-H activation of R 1 rings of thiosemicarbazones {R 1R 2C 2N 3-N 2H-C 1(S)-N 1HR 3}

Journal of Organometallic Chemistry

Volumn 701, Issue , 2012, Pages 17-26

  Lobana, Tarlok S ^a   Kumari, Poonam ^a   Butcher, Ray J ^b   Akitsu, Takashiro ^c   Aritake, Yoshikazu ^c   Perles, Josefina ^d   Fernandez, Francisco J ^e   Vega, M Cristina ^e  

^a GURU NANAK DEV UNIVERSITY   (India)

^b HOWARD UNIVERSITY   (United States)

^c TOKYO UNIVERSITY OF SCIENCE   (Japan)

^d UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^e CENTRO DE INVESTIGACIONES BIOLÓGICAS   (Spain)

Author keywords

2 Acetylpyrrole N 1 phenyl thiosemicarbazone; 2 Acetylthiopheneyl N 1 methyl thiosemicarbazone; Cyclometallation; Palladium(II); Triphenyl phosphine

Indexed keywords

ANALYTICAL DATA; C-H ACTIVATION; CARBON ATOMS; CH-BOND ACTIVATION; CYCLOMETALLATED COMPLEXES; CYCLOMETALLATION; METHYL GROUP; N-H ACTIVATION; N-H BOND ACTIVATION; PALLADIUM COMPLEXES; PHENYL RINGS; PHENYL SUBSTITUENTS; PYRROLE RING; SINGLE CRYSTAL X-RAY CRYSTALLOGRAPHY; SPECTROSCOPIC TECHNIQUE; THIOSEMICARBAZONES; TRIPHENYL PHOSPHINES;

ACTIVATION ANALYSIS; AMINES; CARBON; CHELATION; CHEMICAL ACTIVATION; FUNCTIONAL GROUPS; PHENOLS; PHOSPHORUS COMPOUNDS; SINGLE CRYSTALS; X RAY CRYSTALLOGRAPHY;

PALLADIUM COMPOUNDS;

EID: 84856210927     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2011.11.028     Document Type: Article

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