Bis(diphenylphosphino)methane induces unusual cyclometalation of thiophene and phenyl rings (R) at the C2 carbon of thiosemicarbazones {R-C 2(H) = N3-N2 H-C(=S)-N1H2 in ruthenium(II) complexes

Organometallics

Volumn 27, Issue 2, 2008, Pages 175-180

  Lobana, Tarlok S ^a   Bawa, Gagandeep ^a   Castineiras, A ^b   Butcher, Ray J ^c   Zeller, M ^d  

^a GURU NANAK DEV UNIVERSITY   (India)

^b UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

^c HOWARD UNIVERSITY   (United States)

^d Youngstown University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOMETALATION; HETEROCYCLIC RING; THIOSEMICARBAZONES;

ALDEHYDES; CARBON; CHELATION; ORGANOMETALLICS; REACTION KINETICS; STOICHIOMETRY; THIOPHENE;

METHANE;

EID: 38949140485     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700804s     Document Type: Article

References (36)

1. (a) Main, L.; Nicholson, B. K. Adv. Met.-Org. Chem. 1994, 3, 1.
2. (b) Spencer, J.; Pfeffer, M. Adv. Met.-Org. Chem. 1998, 6, 103.
3. (c) Dopont, J.; Pfeffer, M.; Spencer, J. Eur. J. Inorg. Chem. 2001, 1917.
4. (d) Botella, L.; Najera, C. Angew. Chem., Int. Ed. 2002, 41, 179.
5. (e) Marcos, M In Metallomesogens. Synthesis, Properties and Applications; Serrano J. L., Ed.; VCH: Weinheim, 1996.
6. (f) Urriolabeitia, E. P.; Diaz-de-Villegas, M. D. J. Chem. Educ 1999, 76, 77.
7. (g) Albert, J.; Cadena, J. M.; Granell, J. R.; Solans, X.; Font-Bardia, M. Tetrahedron Asymmetry 2000, 11, 1943.
8. (h) Quiroga, A. G.; Perez, J. M.; Lopez-Solera, I.; Masuguer, J. R.; Luque, A.; Roman, P.; Edwards, A.; Alonso, C.; Navarro-Ranninger, C. J. Med. Chem. 1998, 41, 1399.
9. (i) Song, D.; Wu, Q.; Hook, A.; Kozin, I.; Wang, S. Organometallics 2000, 20, 4683.
10. (a) Acharya, R.; Dutta, S.; Basuli, F.; Peng, S.-M.; Lee, G.-H.; Falvello, L. R.; Bhattacharya, S. Inorg. Chem. 2006, 45, 1252.
11. (b) Vila, J. M.; Pereira, M. T.; Ortigueira, J. M.; Grana, M.; Lata, D.; Suarez, A.; Fernandez, J. J.; Fernandez, A.; Lopez-Torres, M.; Adams, H. J. Chem. Soc., Dalton Trans. 1999, 4193.
12. (c) Yadav, P. N.; Demertzis, M. A.; Kovala-Demertzi, D.; Castineiras, A.; West, D. X. Inorg. Chim. Acta 2002, 32, 204.
13. (d) Martinez, J.; Pereira, M. T.; Buceta, I.; Alberdi, G.; Amoeda, A.; Fernanadez, J. J.; Lopez-Torres, M.; Vila, J. M. Organometallics 2003, 22, 5581.
14. (e) Martinez, J.; Adiro, L. A.; Antelo, J. M.; Teresa-Pereira, M.; Fernandez, J. J.; Vila, J. M. Polyhedron 2006, 25, 2848.
15. (f) Amoedo, A.; Grana, M.; Martinez, J.; Pereira, T.; Lopez-Torres, M.; Fernandez, A.; Fernanadez, J. J.; Vila, J. M.; Eur. J. Inorg. Chem., 2002, 613.
16. (g) Vazquez-Garcia, D.; Fernanadez, A.; Fernanadez, J. J.; Lopez-Torres, M.; Suarez, A.; Ortigueira, J. M.; Vila, J. M.; Adams, H. J. Organomet. Chem. 2000, 59, 5-199.
17. (a) Lobana, T. S.; Bawa, G.; Butcher, R. J.; Liaw, B.-J.; Liu, C. W. Polyhedron 2006, 25, 2897.
18. (b) Mishra, D.; Naskar, S.; Drew, M. G. B.; Chattopadhyay, S. K. Polyhedron 2005, 24, 1861.
19. (c) Basuli, F.; Ruf, M.; Pierpont, C. G.; Bhattacharya, S. Inorg. Chem. 1998, 37, 6113.
20. (d) Basuli, F.; Peng, S. M.; Bhattacharya, S. Inorg. Chem. 1997, 36, 5645.
21. Adrio, L.; Antelo, J. M.; Ortigueira, J. M.; Lata, D.; Pereira, M. T.; Lopez-Torres, M.; Vila, J. M. Z. Anorg. Allg. Chem. 2007, 633, 1875.
22. (a) Casas, J. S.; Garcia-Tasende, M. S.; Sordo, J. Coord. Chem. Rev. 2000, 209, 197.
23. (b) West, D. X.; Liberta, A. E.; Padhye, S. B.; Chikate, R. C.; Sonawane, P. B.; Kumbhar, A. S.; Yerande, A. S. Coord. Chem. Rev. 1993, 123, 49.
24. (c) Baylak, S.; Balaban, A.; Turker, A. R.; Erk, B. J. Anal. Chem. 2006, 61, 476.
25. (d) Mahajan, R. K.; Kaur, I.; Lobana, T. S. Talanta 2003, 59, 101.
26. (e) Kovala-Demertzi, D.; Demertzis, M. A.; Varagi, V.; Papageorgiou, A.; Mourelatos, D.; Mioglou, E.; Iakovidou, Z.; Kotsis, A. Chemotherapy 1998, 44, 421.
27. (a) Lobana, T. S.; Kaur, P. J.; Castineiras, A. J. Coord. Chem. 2005, 58, 429.
28. (b) Lobana, T. S.; Verma, R.; Indian, J. Chem. Sect. A 2003, 42, 534.
29. (c) Lobana, T. S.; Verma, R.; Singh, R.; Castineiras, A. Transition Met. Chem. 1998, 23, 25.
30. (d) Lobana, T. S.; Singh, R. Polyhedron 1995, 14, 907.
31. (e) Tiekink, E. R. T.; Lobana, T. S.; Singh, R. J. Cryst. Spectrosc. Res. 1991, 21, 205.
32. (a) Chakravarty, A. R.; Cotton, F. A.; Schwotzer, W. Inorg. Chim. Acta 1984, 84, 179.
33. (b) Stephenson, T. A.; Wilkinson, G. J. J. Inorg. Nucl. Chem., 1966, 28, 945.
34. Wada, S.; Yuge, H.; Miyamoto, T. K. Acta Crystallogr. Sect. C: Cryst. Struct. Commun. 2003, C59, m369.
35. Lobana, T. S.; Sanchez, A.; Casas, J. S.; Castineiras, A.; Sordo, J.; Garcia-Tasende, M. S.; Vazquez-Lopez, E. M. J. Chem. Soc., Dalton Trans 1997, 4289.
36. See Supporting Information.