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Volumn 136, Issue 2, 2012, Pages

Infrared spectra and ultraviolet-tunable laser induced photochemistry of matrix-isolated phenol and phenol-d 5

Author keywords

[No Author keywords available]

Indexed keywords

ARGON MATRICES; IN-SITU; INFRARED SPECTRUM; ISOTOPOLOGUES; LASER INDUCED; PHENOXYL RADICAL; PHOTOCHEMICAL TRANSFORMATIONS; PHOTOPRODUCTS; PHOTOREACTIONS; PHOTOTRANSFORMATIONS; SECONDARY PRODUCT; THEORETICAL CALCULATIONS; UV LASER LIGHTS;

EID: 84855947484     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3666018     Document Type: Article
Times cited : (49)

References (64)
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    • A few studies involving the matrix isolated phenol do exist, but the main focus of these studies is devoted to the changes in the OH stretching frequency of phenol acting as a hydrogen bond donorhydrogen bond acceptor in different complexes (see, for example, Ref.).
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    • -1. No photoproduct having absorption around this frequency was observed in the present study.
    • -1. No photoproduct having absorption around this frequency was observed in the present study.
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    • -1 was observed in the reaction of oxygen atoms with benzene at 280 nm, in the study of Parker and Davis (Ref.). In that study, the carrier of this doublet band remained unassigned.
    • -1 was observed in the reaction of oxygen atoms with benzene at 280 nm, in the study of Parker and Davis (Ref.). In that study, the carrier of this doublet band remained unassigned.
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    • 5OH isomers do not yield cyclopentadiene upon decomposition, as deduced from the experiments using irradiations at shorter wavelengths of UV light (see below).
    • 5OH isomers do not yield cyclopentadiene upon decomposition, as deduced from the experiments using irradiations at shorter wavelengths of UV light (see below).
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    • -1 due to the antisymmetric C=C=C stretching vibration.
    • -1 due to the antisymmetric C=C=C stretching vibration.
  • 60
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    • -1 due to the antisymmetric CH stretching vibration.
    • -1 due to the antisymmetric CH stretching vibration.
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    • In particular, cyclopentadiene does not look to be among the products generated from 2,5-cyclohexadienone (5). Decrease of population of (5), induced by irradiation at 245 nm, was not accompanied by any increase of IR bands ascribed to cyclopentadiene.
    • In particular, cyclopentadiene does not look to be among the products generated from 2,5-cyclohexadienone (5). Decrease of population of (5), induced by irradiation at 245 nm, was not accompanied by any increase of IR bands ascribed to cyclopentadiene.
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    • -1 below the OD stretching frequency of HCCOD.
    • -1 below the OD stretching frequency of HCCOD.
  • 64
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    • 5-analogs of (2, 5, 7, 8) and their proposed assignments (Table S3). The original experimental spectra related to Figures are available in numeric format (.SPA files for OMNIC software).
    • 5-analogs of (2, 5, 7, 8) and their proposed assignments (Table S3). The original experimental spectra related to Figures are available in numeric format (.SPA files for OMNIC software).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.