Structural properties and transformations of precipitated FeS

Chemical Geology

Volumn 294-295, Issue , 2012, Pages 249-258

  Csákberényi Malasics, Dorottya ^a   Rodriguez Blanco, Juan Diego ^b   Kis, Viktória Kovács ^c   Rečnik, Aleksander ^d   Benning, Liane G ^b   Pósfai, Mihály ^a  

^a UNIVERSITY OF PANNONIA   (Hungary)

^b UNIVERSITY OF LEEDS   (United Kingdom)

^c RESEARCH INSTITUTE FOR TECHNICAL PHYSICS AND MATERIALS SCIENCE   (Hungary)

^d JO EF STEFAN INSTITUTE   (Slovenia)

Author keywords

Amorphous iron sulfide; Greigite; Mackinawite; Phase transformations; TEM; XRD

Indexed keywords

AMORPHOUS IRON; GREIGITE; MACKINAWITE; PHASE TRANSFORMATION; XRD;

ANALYTICAL GEOCHEMISTRY; ANOXIC SEDIMENTS; CRYSTALLINE MATERIALS; DISTRIBUTION FUNCTIONS; ELECTRON DIFFRACTION; EXPERIMENTS; IRON ORES; OXIC SEDIMENTS; PHASE TRANSITIONS; SEDIMENTOLOGY; SUBMARINE GEOLOGY; SULFUR; SULFUR COMPOUNDS; TRANSMISSION ELECTRON MICROSCOPY; X RAY POWDER DIFFRACTION;

IRON;

AMORPHOUS MEDIUM; BIOGEOCHEMICAL CYCLE; CRYSTAL STRUCTURE; EXPERIMENTAL MINERALOGY; GREIGITE; IRON SULFIDE; MINERAL PROPERTY; PHASE TRANSITION; PRECIPITATION (CHEMISTRY); SCANNING ELECTRON MICROSCOPY; SOLUTION; TEMPERATURE EFFECT; TRANSITION ZONE; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION;

EID: 84855793929     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2011.12.009     Document Type: Article

References (45)

1. Benning L.G., Wilkin R.T., Barnes H.L. Reaction pathways in the Fe-S system below 100°C. Chemical Geology 2000, 167:25-51.
2. Berner R.A. Thermodynamic stability of sedimentary iron sulfides. American Journal of Science 1967, 265:773-785.
3. 1-x mackinawite. Physics and Chemistry of Minerals 2001, 600-611.
4. Cahill C.L., Benning L.G., Barnes H.L., Parise J.B. In situ time-resolved X-ray diffraction of iron sulfides during hydrothermal pyrite growth. Chemical Geology 2000, 167:53-63.
5. 4) nanocrystallites and magnetic properties through a simple solution-based route. Chemical Physics Letters 2005, 403:396-399.
6. De Villiers J.P.R., Liles D.C. The crystal-structure and vacancy distribution in 6C pyrrhotite. American Mineralogist 2010, 95(1):148-152.
7. Devey A.J., Grau-Crespo R., de Leeuw N.H. Combined density functional theory and interatomic potential study of the bulk and surface structures and properties of the iron sulfide mackinawite (FeS). Journal of Physical Chemistry C 2009, 112:10,960-10,967.
8. Gallegos T.J., Han Y.-S., Hayes K.F. Model predictions of realgar precipitation by reaction of As (III) with synthetic mackinawite under anoxic conditions. Environmental Science & Technology 2008, 42:9338-9343.
9. Gramp J.P., Bigham J.M., Jones F.S., Tuovinen O.H. Formation of Fe-sulfides in cultures of sulfate-reducing bacteria. Journal of Hazardous Materials 2010, 175:1062-1067.
10. Harmandas N.G., Koutsoukos P.G. The formation of iron (II) sulfides in aqueous environments. Journal of Crystal Growth 1996, 167:719-724.
11. Herbert R.B., Benner S.G., Pratt A.R., Blowes D.W. Surface chemistry and morphology of poorly crystalline iron sulfides precipitated in media containing sulfate-reducing bacteria. Chemical Geology 1998, 144:87-97.
12. Holmes J. Fate of incorporated metals during mackinawite oxidation in sea water. Applied Geochemistry 1999, 14:277-281.
13. 4) durch Elektronenstrahlen. Zeitschrift für Anorganische und Allgemeine Chemie 1971, 386:208-212.
14. Horng C.-S., Roberts A.P. Authigenic or detrital origin of pyrrhotite in sediments? Resolving a paleomagnetic conundrum. Earth and Planetary Science Letters 2006, 241:750-762.
15. Hunger S., Benning L.G. Greigite: a true intermediate on the polysulfide pathway to pyrite. Geochemical Transactions 2007, 8(1):1-20.
16. Jeong H.Y., Lee J.H., Hayes K.F. Characterization of synthetic nanocrystalline mackinawite: crystal structure, particle size, and specific surface area. Geochimica et Cosmochimica Acta 2008, 72:493-505.
17. Kornicker, W.A., 1988. Interactions of Divalent Cations with Pyrite and Mackinawite in Seawater and Sodium-chloride Solutions. Ph.D. Thesis. Texas A&M University.
18. Lábár J.L. Consistent indexing of a (set of) single crystal SAED pattern(s) with the ProcessDiffraction program. Ultramicroscopy 2005, 103:237-249.
19. Larrasoana J.C., Roberts A.P., Musgrave R.J., Grácia E., Pinero E., Vega M., Martínez-Ruiz F. Diagenetic formation of greigite and pyrrhotite in gas hydrate marine sedimentary systems. Earth and Planetary Science Letters 2007, 261:350-366.
20. Lennie A.R., Redfern S.A.T., Schofield P.F., Vaughan D.J. Synthesis and Rietveld crystal structure refinement of mackinawite, tetragonal FeS. Mineralogical Magazine 1995, 59:677-683.
21. Lennie A.R., Redfern S.A.T., Champness P.E., Stoddart C.P., Schofield P.F., Vaughan D.J. Transformation of mackinawite to greigite: an in situ X-ray powder diffraction and transmission electron microscope study. American Mineralogist 1997, 82:302-309.
22. Liu J., Valsaraj K.T., Devai I., DeLaune R.D. Immobilization of aqueous Hg(II) by mackinawite (FeS). Journal of Hazardous Materials 2008, 157:432-440.
23. Livens F.R., Jones M.J., Hynes A.J., Charnock J.M., Mosselmans J.F.W., Hennig C., Steele H., Collison D., Vaughan D.J., Pattrick R.A.D., Reed W.A., Moyes L.N. X-ray absorption specctroscopic studies of reactions of technetium, uranium and neptunium with mackinawite. Journal of Environmental Radioactivity 2004, 74:211-219.
24. Michel F.M., Antao S.M., Chupas P.J., Lee P.L., Parise J.B., Schoonen M.A.A. Short- to medium range atomic order and crystallite size of the initial FeS precipitate from pair distribution function analysis. Chemistry of Materials 2005, 17:6246-6255.
25. Mullet M., Boursiquot S., Abdelmoula M., Génin J.-M., Ehrhardt J.-J. Surface chemistry and structural properties of mackinawite prepared by reaction of sulfide ions with metallic iron. Geochimica et Cosmochimica Acta 2002, 66:829-836.
26. Mullet M., Boursiquot S., Ehrhardt J.-J. Removal of hexavalent chromium from solutions by mackinawite, tetragonal FeS. Colloids and Surfaces 2004, 244:77-85.
27. Ohfuji H., Rickard D. High resolution transmission electron microscopic study of synthetic nanocrystalline mackinawite. Earth and Planetary Science Letters 2006, 241:227-233.
28. Pósfai M., Dunin-Borkowski R.E. Sulfides in biosystems. Reviews in Mineralogy and Geochemistry 2006, 61:679-714.
29. Pósfai M., Buseck P.R., Bazylinski D.A., Frankel R.B. Iron sulfides from magnetotactic bacteria: structure, composition, and phase transitions. American Mineralogist 1998, 83:1469-1481.
30. m). Chemical Geology 2009, 268:116-125.
31. 2S oxidation of iron (II) monosulfide in aqueous solutions between 25 and 125°C: the mechanism. Geochimica et Cosmochimica Acta 1997, 61:135-147.
32. Rickard D., Luther G.W. Chemistry of iron sulfides. Chemical Reviews 2007, 107:514-562.
33. Rickard D., Morse J.W. Acid volatile sulfide (AVS). Marine Chemistry 2005, 97:141-197.
34. 4). Earth and Planetary Science Letters 1995, 134:227-236.
35. Schoonen M.A.A., Barnes H.L. Mechanisms of pyrite and marcasite formation from solution: III. Hydrothermal processes. Geochimica et Cosmochimica Acta 1991, 55:3491-3504.
36. Schoonen M.A.A., Barnes H.L. Reactions forming pyrite and marcasite from solution: II. Via FeS precursors below 100°C. Geochimica et Cosmochimica Acta 1991, 55:1505-1514.
37. Shi X., Sun K., Balogh L.P., Baker J.B. Synthesis, characterization, and manipulation of dendrimer-stabilized iron sulfide nanoparticles. Nanotechnology 2006, 17:4554-4560.
38. Skála R., Císařová I., Drábek M. Inversion twinning in troilite. American Mineralogist 2006, 91(5-6):917-921.
39. Skinner B.J., Erd R.C., Grimaldi F.S. Greigite, the thiospinel of iron; a new mineral. American Mineralogist 1964, 49:543-555.
40. Taylor P., Rummery T.E., Owen D.G. On the conversion of mackinawite and greigite. Journal of Inorganic and Nuclear Chemistry 1979, 41:595-596.
41. Vaughan D.J., Ridout M.S. Mössbauer studies of some sulphide minerals. Journal of Inorganic and Nuclear Chemistry 1971, 33:741-746.
42. Watson J.H.P., Ellwood D.C., Deng Q., Mikhalowsky S., Hayter C.E., Evans J. Heavy metal adsorption on bacterially produced FeS. Minerals Engineering 1995, 8:1097-1108.
43. Watson J.H.P., Cressey B.A., Roberts A.P., Ellwood D.C., Charnock J.M., Soper A.K. Structural and magnetic studies on heavy-metal-adsorbing iron sulphide nanoparticles produced by sulphate-reducing bacteria. Journal of Magnetism and Magnetic Materials 2000, 214:13-30.
44. Wolthers M., Van der Gaast S., Rickard D. The structure of disordered mackinawite. American Mineralogist 2003, 88:2007-2015.
45. Wolthers M., Charlet L., van Der Weijden C.H., van Der Linde P.R., Rickard D. Arsenic mobility in the ambient sulfidic environment: sorption of arsenic(V) and arsenic(III) onto disordered mackinawite. Geochimica et Cosmochimica Acta 2005, 69:3483-3492.