The structure of disordered mackinawite

American Mineralogist

Volumn 88, Issue 11-12 PART 2, 2003, Pages 2007-2015

  Wolthers, Mariëtte ^a   Van Der Gaast, Steerk J ^b   Rickard, David ^c  

^a UTRECHT UNIVERSITY   (Netherlands)

^b ROYAL NETHERLANDS INSTITUTE FOR SEA RESEARCH   (Netherlands)

^c CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLITE SIZE; IRON COMPOUNDS; LATTICE CONSTANTS; MOLECULES; NANOCRYSTALS; PARTICLE SIZE;

ACID VOLATILE SULFIDES; LATTICE EXPANSION; LATTICE RELAXATION; LONG RANGE ORDERS; NATURAL ENVIRONMENTS; PRIMARY PARTICLE SIZE; STRUCTURAL MODELING; TETRAHEDRAL SHEETS;

SULFUR COMPOUNDS;

CRYSTAL STRUCTURE; IRON SULFIDE; MACKINAWITE; MINERALOGY; SCAVENGING (CHEMISTRY);

EID: 0347723773     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2003-11-1245     Document Type: Article

References (48)

1. Arakaki, T. and Morse, J.W. (1993) Coprecipitation and adsorption of Mn(II) with mackinawite (FeS) under conditions similar to those found in anoxic sediments. Geochimica et Cosmochimica Acta, 57, 9-14.
2. Benning, L., Wilkin, R.T., and Barnes, H.L. (2000) Reaction pathways in the Fe-S system below 100°C. Chemical Geology, 167, 25-51.
3. Berner, R.A. (1964) Stability fields of iron minerals in anaerobic marine sediments. Journal of Geology, 72, 826-834.
4. Berner, R.A. (1967) Diagenesis of iron sulfide in recent marine sidements. In G.H. Lauf, Ed., Estuaries (papers of a conference on estuaries, Jekyll Island 1964). American Association for the Advancement of Science, Washington, 268-272.
5. Berner, R.A. (1970) Sedimentary pyrite formation. American Journal of Science, 268, 1-23.
6. Berner, R.A. (1974) Iron sulfides in Pleistocene deep Black Sea sediments and their paleooceanographic significance. In E.T. Degens and D.A. Ross, Eds., The Black Sea: Geology, Chemistry and Biology. Max-Planck-Gesellschaft Memoir, 20, 524-531.
7. Brindley, G.W. (1980) Order-disorder in clay mineral structures. In G.W. Brindley and G. Brown, Eds., Crystal Structures of Clay Minerals and Their X-ray Identification, 125-195. Mineralogical Society London.
8. Browne, P.R.L. and Wood, C.P. (1974) Mackinawite and pyrite in a hot springs deposit, Mohaka River, New Zealand. Neues Jahrbuch für Mineralogie, Monatshefte, 10, 468-475.
9. Cornell, R.M. and Schwertman, U. (1996) The iron oxides, 573 p. VCH Verlag, Weinheim.
10. Dang, M.-Z., Rancourt, D.G., Dutrizac, J.E., Lamarche, G., and Provencher, R. (1998) Interplay of surface conditions, particle size, stoichiometry, cell parameters, and magnetism in synthetic hematite-like materials. Hyperfine Interactions, 117, 271-319.
11. Dixit, S. and Van Cappellen, P. (2002) Surface chemistry and reactivity of biogenic silica. Geochimica et Cosmochimica Acta, 66, 2559-2568.
12. Dzombak, D.A. and Morel, F.M.M. (1990) Surface Complexation Modelling, Hydrous Ferric Oxide. Wiley, New York.
13. 6 clusters. Berichte der Bunse-Gesellschaft für Physikalische Chemie, 86, 860-865.
14. Evans, Jr., H.T., Milton, C., Chao, E.C.T., Adler, I., Mead, C., Ingram, B., and Berner, R.A. (1964). Vallerite and the new iron sulfide, mackinawite. USGS Professional Paper 475-D, 64-69.
15. 2S in iron sulfide transformations: examples from Effingham Inlet, Orca Basin, and the Black Sea. American Journal of Science, 299, 556-588.
16. Kornicker, W.A. (1988) Interactions of divalent cations with pyrite and mackinawite in seawater and sodium-chloride solutions. Ph.D. thesis. Texas A&M University.
17. Kuovo, O., Vuorelainen, Y., and Long, J.V.P. (1963) A tetragonal iron sulfide. American Mineralogist, 48, 511-524.
18. Lennie, A.R. and Vaughan, D.J. (1996) Spectroscopic studies of iron sulfide formation and phase relations at low temperatures. Mineral Spectroscopy, 5, 117-131.
19. Lennie, A.R., Redfern, S.A.T., Schofield, P.F., and Vaughan, D.J (1995) Synthesis and Rietveld crystal structure refinement of mackinawite, tetragonal FeS. Mineralogical Magazine, 59, 677-683
20. Luther, III, G.W., Theberge, S.M., and Rickard, D.T. (1999) Evidence for aqueous clusters as intermediates during zinc sulfide formation. Geochimica et Cosmochimica Acta, 63, 3159-3169.
21. Luther, III, G.W., Rozan, T.F., Taillefert, M., Nuzzio, D.B., Di Meo, C., Shank, T.M., Lutz, R.A., and Cary, S.C. (2001) Chemical speciation drives hydrothermal vent ecology. Nature, 410, 813-816.
22. McEwan, D.M.C., Ruiz, A.A., and Brown, G. (1961) Interstratified clay minerals. In G.W. Brindley and G. Brown, Eds., Crystal Structure of Clay Minerals and Their X-ray Identification. Mineralogical Society London, 393-445.
23. Morse, J.W. and Arakaki, T. (1993) Adsorption and coprecipitation of divalent metals with mackinawite (FeS). Geochimica et Cosmochimica Acta, 57, 3635-3640.
24. Morse, J.W. and Luther, III, G.W. (1999) Chemical influences on trace metal-sulfide interactions in anoxic sediments. Geochimica et Cosmochimica Acta, 63, 3373-3378.
25. Morse, J.W., Millero, F.J., Cornwell, J.C., and Rickard, D. (1987) The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters. Earth-Science Review, 24, 1-42.
26. Mullet, M., Boursiquot, S., Abdelmoula, M., Génin, J.-M., and Ehrhardt, J.-J. (2002) Surface chemistry and structural properties of mackinawite prepared by reaction of sulfide ions with metallic iron. Geochimica et Cosmochimica Acta, 66, 829-836.
27. Murowchick, J.B. and Rickard, D.T. (1997) Structural changes during ripening of synthetic mackinawite formed by corrosion of alpha-iron. Abstracts with Programs. Geological Society of America, 29, 402.
28. Parfitt, R.L., Van der Gaast, S.J., and Childs, C.W. (1992) A structural model for natural siliceous ferrihydrite. Clays and Clay Minerals, 40, 675-681.
29. Rickard, D.T. (1968) The geological and microbiological formation of iron sulfides. Ph.D. thesis, London University.
30. Rickard, D.T. (1969) The chemistry of iron sulphide formation at low temperatures. Stockholm Contributions in Geology, 20, 67-95.
31. Rickard, D.T. (1975) Kinetics and mechanism of pyrite formation at low temperatures, American Journal of Science, 275, 636-652.
32. Rickard, D.T. (1995) Kinetics of FeS precipitation: Part 1. Competing reaction mechanism. Geochimica et Cosmochimica Acta, 59, 4367-4379.
33. 2S oxidation of iron(II) monusulfide in aqueous solutions between 25 and 125°C: The rate equation. Geochimica et Cosmochimica Acta, 61, 115-134.
34. 2S oxidation of iron(II) monusulfide in aqueous solutions between 25 and 125°C: The mechanism. Geochimica et Cosmochimica Acta, 61, 135-147.
35. Rickard, D., Schoonen, M.A.A., and Luther, III, G.W. (1995). The chemistry of iron sulfides in sedimentary environments. In M.A. Vairavamurthy and M.A.A. Schoonen, Eds., Geochemical transformations of sedimentary sulfur. ACS symposium series 612, 168-193.
36. Rickard, D., Oldroyd, A., and Cramp, A. (1999) Voltammetric evidence for soluble FeS complexes in anoxic estuarine muds. Estuaries, 22, 693-701.
37. Spadini, L., Bott, M., Wehrli, B., and Manceau, A. (2003) Analysis of the major Fe bearing phases in recent lake sediments by EXAFS spectroscopy, in press.
38. Taylor, L.A. and Finger, L.W. (1970) Structural refinement and composition of mackinawite. Carnegie Instution of Washington, Geophysical Laboratory Annual Report, 69, 318-322.
39. Taylor, P., Rummery, T.E., and Owen, D.G. (1979) On the conversion of mackinawite and greigite. Journal of Inorganic and Nuclear Chemistry, 41, 595-596.
40. Theberge, S.M. and Luther, III G.W. (1997) Determination of the electrochemical properties of a soluble aqueous FeS species present in sulfidic solutions. Aquatic Geochemistry, 3, 191-211.
41. Van der Gaast, S.J., Wada, K., Wada, S.I., and Kakuto, Y. (1985) Small-angle X-ray powder diffraction, morphology, and structure of allophane and imogolite. Clays and Clay Minerals, 33, 237-243.
42. Van der Gaast, S.J., Mizota, C., and Jansen, J.H.F. (1986) Curved smectite in soils from volcanic ash in Kenya and Tanzania: a low-angle X-ray powder diffraction study. Clays and Clay Minerals, 34, 665-671.
43. Vaughan, D.J. (1970) Nickelian mackinawite from Vlakfontein: a reply. American Mineralogist, 55, 1807-1808.
44. Vaughan, D.J. and Craig, J.R. (1978) Mineml chemistry of metal sulfides, 493 p. Cambridge University Press, Cambridge.
45. Watson, J.H.P., Cressey, B.A., Roberts, A.P., Ellwood, D.C., Charnock, J.M., and Soper, A.K. (2000) Structural and magnetic studies on heavy-metal-adsorbing iron sulphide nanoparticles produced by sulphate-reducing bacteria. Journal of Magnetism and Magnetic Materials, 214, 13-30.
46. Waychunas, G.A. (2001) Structure, aggregation and characterization of nanoparticles. In J.F. Banfield and A. Navrotsky, Eds., Nanoparticles and the environment, vol. 44, 105-166. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America. Washington, D.C.
47. Wharton, M.J., Atkins, B., Charnock, J.M., Livens, F.R., Pattrick, R.A.D., and Collison, D. (2000) An X-ray absorption spectroscopy study of the coprecipitation of Te and Re with mackinawite (FeS). Applied Geochemistry, 15, 347-354.
48. Widler, A.M. and Seward, T. M. (2002) The adsorption of gold(I) hydrosulphide complexes by iron sulphide surfaces. Geochimica et Cosmochimica Acta, 66, 383-402.