The conversion of nickel-bound CO into an acetyl thioester: Organometallic chemistry relevant to the acetyl coenzyme A synthase active site

Angewandte Chemie - International Edition

Volumn 50, Issue 52, 2011, Pages 12621-12625

  Horn, Bettina ^a   Limberg, Christian ^a   Herwig, Christian ^a   Mebs, Stefan ^a  

^a HUMBOLDT UNIVERSITY   (Germany)

Author keywords

diketiminates; acetyl coenzyme A synthase; coordination chemistry; enzyme models; nickel

Indexed keywords

ACETYL COENZYME A; ACTIVE SITE; BINDING SEQUENCE; COORDINATION CHEMISTRY; DIKETIMINATES; ENZYME MODELS; MODEL SYSTEM; ORGANOMETALLIC CHEMISTRY; SYNTHASES; THIOESTERS;

COORDINATION REACTIONS; ORGANOMETALLICS;

NICKEL;

ALDEHYDE DEHYDROGENASE; CARBON MONOXIDE; CARBON MONOXIDE DEHYDROGENASE; MULTIENZYME COMPLEX; NICKEL; ORGANOMETALLIC COMPOUND; THIOL DERIVATIVE;

ARTICLE; CHEMISTRY; ENZYME ACTIVE SITE; METABOLISM; SYNTHESIS;

ALDEHYDE OXIDOREDUCTASES; CARBON MONOXIDE; CATALYTIC DOMAIN; MULTIENZYME COMPLEXES; NICKEL; ORGANOMETALLIC COMPOUNDS; SULFHYDRYL COMPOUNDS;

EID: 84255162431     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201105281     Document Type: Article

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