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For conceptually related transformations on a NiPd binuclear platform, see
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For conceptually related transformations on a NiPd binuclear platform, see: Rampersad, M. V.; Jeffery, S. P.; Reibenspies, J. H.; Ortiz, C. G.; Darensbourg, D. J.; Darensbourg, M. Y. Angew. Chem. 2005, 44, 1217.
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53849146215
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31P NMR resonances consistent with the presence of the two expected isomers, i.e., species in which the Ni(dppe)Me fragment is bound either to Cys1 or Cys3.
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31P NMR resonances consistent with the presence of the two expected isomers, i.e., species in which the Ni(dppe)Me fragment is bound either to Cys1 or Cys3.
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27
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37049075261
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+ fragment could exist as a DMSO-bound, i.e., solvento species. Alternatively, there are precedents for three-coordinate nickel alkyls: Conroy-Lewis, F. M.; Mole, L.; Redhouse, A. D.; Litster, S. A.; Spencer, J. L. Chem. Commun. 1991, 1601-1603.
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+ fragment could exist as a DMSO-bound, i.e., solvento species. Alternatively, there are precedents for three-coordinate nickel alkyls: Conroy-Lewis, F. M.; Mole, L.; Redhouse, A. D.; Litster, S. A.; Spencer, J. L. Chem. Commun. 1991, 1601-1603.
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