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Volumn 50, Issue 24, 2011, Pages 12844-12851

Synthesis and molecular structure of gold triarylcorroles

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EID: 84055176350     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic202023r     Document Type: Article
Times cited : (105)

References (48)
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    • While this paper was under review, a report of gold(III) β-octabromo-meso-tris(pentafluorphenyl)corrole, Au[Br8TPFPC], including an X-ray crystal structure, appeared in the literature: Rabinovitch, E.; Goldberg, I.; Gross, Z. Chem.-Eur. J. 2011, 17, 12294-12301.
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    • Rabinovitch, E.1    Goldberg, I.2    Gross, Z.3
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    • Reviews on DFT studies of porphyrins and related compounds: (a) Ghosh, A. Acc. Chem. Res. 1998, 31, 189-198.
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    • Kadish, K. M., Guilard, R., Smith, K. M., Eds.; Academic: San Diego, Chapter 47
    • (b) Ghosh, A. In The Porphyrin Handbook; Kadish, K. M., Guilard, R., Smith, K. M., Eds.; Academic: San Diego, 1999; Vol. 7, Chapter 47, pp 1-38.
    • (1999) The Porphyrin Handbook , vol.7 , pp. 1-38
    • Ghosh, A.1
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    • The fact that these distances are all fairly similar is dictated by the steric constraints of the corrole macrocycle. The fact that the bond distances involving silver and gold are similar is explained by their similar ionic radii, 0.89 and 0.99 Å, respectively, for the 3+ ions, which may be compared with significantly smaller values of 0.54 Å for CuIII and 0.73 Å for CuII: Shannon, R. D. Acta Crystallogr. 1976, A32, 751-767.
    • (1976) Acta Crystallogr. , vol.A32 , pp. 751-767
    • Shannon, R.D.1
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    • The term "inherent" or "intrinsic" refers to the fact that the saddling is driven primarily by metal-ligand orbital interactions and not by peripheral substituents, although the latter can accentuate the saddling. The term "intrinsic ruffling" has been used for nickel porphyrins: Kozlowski, P. M.; Rush, T. S.; Jarzecki, A. A.; Zgierski, M. Z.; Chase, B.; Piffat, C.; Ye, B.-H.; Li, X.-Y.; Pulay, P.; Spiro, T. G. J. Phys. Chem. A 1999, 103, 1357-1366.
    • (1999) J. Phys. Chem. A , vol.103 , pp. 1357-1366
    • Kozlowski, P.M.1    Rush, T.S.2    Jarzecki, A.A.3    Zgierski, M.Z.4    Chase, B.5    Piffat, C.6    Ye, B.-H.7    Li, X.-Y.8    Pulay, P.9    Spiro, T.G.10
  • 22
    • 0034738115 scopus 로고    scopus 로고
    • The two HOMOs of corrole, a2 and b1 in C2v symmetry, are very similar in shape to the porphyrin a1u and a2u HOMOs, respectively. We will therefore continue to use the D4h porphyrin irreps to describe the corrole HOMOs: Ghosh, A.; Wondimagegn, T.; Parusel, A. B. J. J. Am. Chem. Soc. 2000, 122, 5100-5104.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 5100-5104
    • Ghosh, A.1    Wondimagegn, T.2    Parusel, A.B.J.3
  • 23
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    • For reviews on nonplanar porphyrins, see: (a) Senge, M. Chem. Commun. 2006, 243-256.
    • (2006) Chem. Commun. , pp. 243-256
    • Senge, M.1
  • 31
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    • Ligand noninnocence is ubiquitous for metallocorroles. For key studies, see: (a) Cai, S.; Walker, F. A.; Licoccia, S. Inorg. Chem. 2000, 39, 3466-3478.
    • (2000) Inorg. Chem. , vol.39 , pp. 3466-3478
    • Cai, S.1    Walker, F.A.2    Licoccia, S.3
  • 33
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    • Addition/correction
    • Addition/correction: J. Phys. Chem. B 2002, 106, 5312.
    • (2002) J. Phys. Chem. B , vol.106 , pp. 5312
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    • (a) Becke, A. D. Phys. Rev. 1988, A38, 3098-3100.
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    • Erratum
    • Erratum: Perdew, J. P. Phys. Rev. 1986, B34, 7406.
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    • Perdew, J.P.1
  • 44
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    • The noninnocent nature of copper corroles has been confirmed by ab initio CASPT2 calculations: Pierloot, K.; Zhao, H.; Vancoillie, S. Inorg. Chem. 2010, 49, 10316-10329.
    • (2010) Inorg. Chem. , vol.49 , pp. 10316-10329
    • Pierloot, K.1    Zhao, H.2    Vancoillie, S.3
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    • Thomas, K. E.; Wasbotten, I. H.; Ghosh, A. 2008, 47, 10469-10478
    • Much higher p's have been measured for copper β-octakis- (trifluoromethyl)-meso-triarylcorroles:17 Thomas, K. E.; Wasbotten, I. H.; Ghosh, A. 2008, 47, 10469-10478. Addition/correction: Inorg. Chem. 2009, 48, 1257-1257.
    • (2009) Inorg. Chem. , vol.48 , pp. 1257-1257


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