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Volumn 130, Issue 25, 2008, Pages 7786-7787

Iridium corroles

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM; IRIDIUM CORROLE;

EID: 45749084171     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja801049t     Document Type: Article
Times cited : (111)

References (35)
  • 25
    • 45749088965 scopus 로고    scopus 로고
    • Iridium(II) porphyrins react readily with olefins; they also form Ir-Ir bonded dimers: de Bruin, B.; Hetterscheid, D. G. H. Eur. J. Inorg. Chem. 2007, 211-230.
    • Iridium(II) porphyrins react readily with olefins; they also form Ir-Ir bonded dimers: de Bruin, B.; Hetterscheid, D. G. H. Eur. J. Inorg. Chem. 2007, 211-230.
  • 27
    • 45749102490 scopus 로고    scopus 로고
    • Nearly all reported iridium(III) porphyrins are organometallic in nature: Zhai, H.; Bunn, A.; Wayland, B. Chem. Commun. 2001, 1294-1295.
    • Nearly all reported iridium(III) porphyrins are organometallic in nature: Zhai, H.; Bunn, A.; Wayland, B. Chem. Commun. 2001, 1294-1295.
  • 28
    • 45749083782 scopus 로고    scopus 로고
    • H3tpfc (80 mg, Ir(cod)Cl]2 (335 mg, and K 2CO3 (140 mg) were dissolved/suspended in 150 mL of degassed THF, and the mixture was refluxed under argon for 90 min (until the corrole fluorescence was negligible to the eye upon long-wave irradiation with a hand-held lamp, Tma N-oxide (110 mg) was added, and the solution was allowed to slowly cool to room temperature while open to the laboratory atmosphere. Column chromatography of the black solution (silica, 4:1 hexanes/CH 2Cl2) provided purple crystals of (tpfc)Ir(III)(tma) 2 (30 mg, 27% yield, 1H NMR (CD2Cl 2, δ 8.93 (d, 2H, 8.54 (d, 2H, 8.42 (d, 2H, 8.12 (d, 2H, 2.96 (s, 18H, 19F NMR (CD2Cl2, δ-139.1 (m, 6H, 156.2 (m, 3H, 164.3 (m, 6H, MS (ESI, 1105.1, M, 1046.0, M+-tma, 986.5, M+-2tma, UV-vis (nm, 390, 412, 448 sh, 572, 63
    • +-2tma]). UV-vis (nm): 390, 412, 448 (sh), 572, 638.
  • 29
    • 45749101275 scopus 로고    scopus 로고
    • Complex 1 (15 mg) and Br2 (70 μL) were dissolved in 20 mL of MeOH and stirred overnight. Column chromatography (silica, 4:1 hexanes/CH2Cl2) of the red solution provided green crystals of (Br8-tpfc)Ir(III)(tma)2 (15 mg, 63% yield, 1H NMR (CD2Cl2, δ-2.59 (s, 18H, 19F NMR (CD2Cl2, δ-138.4 (q, 2H, 139.0 (q, 4H, 153.9 (t, 3H, 164.4 (m, 4H, 164.7 (m, 2H, UV-vis (nm, 406, 422, 458 sh, 580, 646
    • 2): δ-138.4 (q, 2H),-139.0 (q, 4H),-153.9 (t, 3H),-164.4 (m, 4H),-164.7 (m, 2H). UV-vis (nm): 406, 422, 458 (sh), 580, 646.
  • 31
    • 45749098529 scopus 로고    scopus 로고
    • 4, using a glassy carbon disk working electrode, a Pt wire auxiliary electrode, and a Ag/AgCl quasi-reference electrode.
    • 4, using a glassy carbon disk working electrode, a Pt wire auxiliary electrode, and a Ag/AgCl quasi-reference electrode.
  • 34
    • 0035951561 scopus 로고    scopus 로고
    • The macrocyclic framework of a fully brominated cobalt corroie also is flat: Paolesse, R.; Nardis, S.; Sagone, F.; Khoury, R. G. J. Org. Chem. 2001, 66, 550-556.
    • The macrocyclic framework of a fully brominated cobalt corroie also is flat: Paolesse, R.; Nardis, S.; Sagone, F.; Khoury, R. G. J. Org. Chem. 2001, 66, 550-556.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.