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Iridium(II) porphyrins react readily with olefins; they also form Ir-Ir bonded dimers: de Bruin, B.; Hetterscheid, D. G. H. Eur. J. Inorg. Chem. 2007, 211-230.
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Iridium(II) porphyrins react readily with olefins; they also form Ir-Ir bonded dimers: de Bruin, B.; Hetterscheid, D. G. H. Eur. J. Inorg. Chem. 2007, 211-230.
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27
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45749102490
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Nearly all reported iridium(III) porphyrins are organometallic in nature: Zhai, H.; Bunn, A.; Wayland, B. Chem. Commun. 2001, 1294-1295.
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Nearly all reported iridium(III) porphyrins are organometallic in nature: Zhai, H.; Bunn, A.; Wayland, B. Chem. Commun. 2001, 1294-1295.
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28
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45749083782
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H3tpfc (80 mg, Ir(cod)Cl]2 (335 mg, and K 2CO3 (140 mg) were dissolved/suspended in 150 mL of degassed THF, and the mixture was refluxed under argon for 90 min (until the corrole fluorescence was negligible to the eye upon long-wave irradiation with a hand-held lamp, Tma N-oxide (110 mg) was added, and the solution was allowed to slowly cool to room temperature while open to the laboratory atmosphere. Column chromatography of the black solution (silica, 4:1 hexanes/CH 2Cl2) provided purple crystals of (tpfc)Ir(III)(tma) 2 (30 mg, 27% yield, 1H NMR (CD2Cl 2, δ 8.93 (d, 2H, 8.54 (d, 2H, 8.42 (d, 2H, 8.12 (d, 2H, 2.96 (s, 18H, 19F NMR (CD2Cl2, δ-139.1 (m, 6H, 156.2 (m, 3H, 164.3 (m, 6H, MS (ESI, 1105.1, M, 1046.0, M+-tma, 986.5, M+-2tma, UV-vis (nm, 390, 412, 448 sh, 572, 63
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+-2tma]). UV-vis (nm): 390, 412, 448 (sh), 572, 638.
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29
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45749101275
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Complex 1 (15 mg) and Br2 (70 μL) were dissolved in 20 mL of MeOH and stirred overnight. Column chromatography (silica, 4:1 hexanes/CH2Cl2) of the red solution provided green crystals of (Br8-tpfc)Ir(III)(tma)2 (15 mg, 63% yield, 1H NMR (CD2Cl2, δ-2.59 (s, 18H, 19F NMR (CD2Cl2, δ-138.4 (q, 2H, 139.0 (q, 4H, 153.9 (t, 3H, 164.4 (m, 4H, 164.7 (m, 2H, UV-vis (nm, 406, 422, 458 sh, 580, 646
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2): δ-138.4 (q, 2H),-139.0 (q, 4H),-153.9 (t, 3H),-164.4 (m, 4H),-164.7 (m, 2H). UV-vis (nm): 406, 422, 458 (sh), 580, 646.
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30
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0001226248
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Golubkov, G.; Bendix, J.; Gray, H. B.; Mahammed, A.; Goldberg, I.; DiBilio, A. J.; Gross, Z. Angew. Chem., Int. Ed. 2001, 40, 2132-2134.
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Golubkov, G.1
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Gray, H.B.3
Mahammed, A.4
Goldberg, I.5
DiBilio, A.J.6
Gross, Z.7
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31
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4, using a glassy carbon disk working electrode, a Pt wire auxiliary electrode, and a Ag/AgCl quasi-reference electrode.
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4, using a glassy carbon disk working electrode, a Pt wire auxiliary electrode, and a Ag/AgCl quasi-reference electrode.
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32
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23344435636
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Kadish, K. M.; Deng, Y. J.; Yao, C.-L.; Anderson, J. E. Organomet. 1988, 7, 1979-1983.
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Organomet
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Kadish, K.M.1
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Anderson, J.E.4
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34
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0035951561
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The macrocyclic framework of a fully brominated cobalt corroie also is flat: Paolesse, R.; Nardis, S.; Sagone, F.; Khoury, R. G. J. Org. Chem. 2001, 66, 550-556.
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The macrocyclic framework of a fully brominated cobalt corroie also is flat: Paolesse, R.; Nardis, S.; Sagone, F.; Khoury, R. G. J. Org. Chem. 2001, 66, 550-556.
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35
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3343022816
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and references therein
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Ou, Z.; Shao, J.; D'Souza, F.; Tagliatesta, P.; Kadish, K. M. J. Porphyrins Pthalocyanines 2004, 8, 201-214, and references therein.
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Ou, Z.1
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D'Souza, F.3
Tagliatesta, P.4
Kadish, K.M.5
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