Growth of uniformly oriented silica MFI and BEA zeolite films on substrates

Science

Volumn 334, Issue 6062, 2011, Pages 1533-1538

  Thanh, Tung Cao ^a   Kim, Hyun Sung ^a   Yoon, Kyung Byung ^a  

^a Sogang University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

SILICON DIOXIDE; TETRAETHOXYSILANE; TETRYLAMMONIUM; XYLENE; ZEOLITE;

CHEMICAL COMPOSITION; CRYSTALLIZATION; FILM; GEL; GROWTH; INTEGRATED APPROACH; NONLINEARITY; SILICA; SUBSTRATE; TEMPERATURE EFFECT; XYLENE; ZEOLITE;

ARTICLE; CRYSTAL; CRYSTALLIZATION; FILM; GEL; ISOMER; PRIORITY JOURNAL; ROOM TEMPERATURE; SCANNING ELECTRON MICROSCOPY; X RAY DIFFRACTION;

EID: 83755169492     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1212472     Document Type: Article

References (38)

1. J. O'Brien-Abraham, J. Y. S. Lin, in Zeolites in Industrial Separation and Catalysis, S. Kulprathipanja, Ed. (Wiley VCH, Verlag, Weinheim, Germany, 2010), chap. 3, pp. 307-329.
2. J. Caro, M. Noack, in Advances in Nanoporous Materials, S. Ernst, Ed. (Elsevier, Amsterdam, 2009), vol. 1, chap. 1, pp. 1-96.
3. J. Caro, M. Noack, Microporous Mesoporous Mater. 115, 215 (2008).
4. J. Choi et al., Science 325, 590 (2009).
5. J. Hedlund, F. Jareman, A. J. Bons, M. Anthonis, J. Membr. Sci. 222, 163 (2003).
6. Z. P. Lai, M. Tsapatsis, J. R. Nicolich, Adv. Funct. Mater. 14, 716 (2004).
7. C. J. Gump, V. A. Tuan, R. D. Noble, J. L. Falconer, Ind. Eng. Chem. Res. 40, 565 (2001).
8. Z. P. Lai et al., Science 300, 456 (2003).
9. M. A. Snyder, M. Tsapatsis, Angew. Chem. Int. Ed. 46, 7560 (2007).
10. H. H. Funke, A. M. Argo, J. L. Falconer, R. D. Noble, Ind. Eng. Chem. Res. 36, 137 (1997).
11. J. O'Brien-Abraham, M. Kanezashi, Y. S. Lin, J. Membr. Sci. 320, 505 (2008).
12. M. O. Daramola et al., Sep. Sci. Technol. 45, 21 (2009).
13. H. Guo et al., Angew. Chem. Int. Ed. 45, 7053 (2006).
14. H. S. Kim et al., J. Am. Chem. Soc. 126, 673 (2004).
15. H. S. Kim et al., Adv. Mater. 19, 260 (2007).
16. H. S. Kim, T. T. Pham, K. B. Yoon, J. Am. Chem. Soc. 130, 2131 (2008).
17. C. M. Lew, R. Cai, Y. Yan, Acc. Chem. Res. 43, 210 (2010).
18. Z. Li et al., Angew. Chem. Int. Ed. 45, 6329 (2006).
19. M. E. Davis, Nature 417, 813 (2002).
20. T. Bein, Chem. Mater. 8, 1636 (1996).
21. Y. Liu, Y. S. Li, W. S. Yang, J. Am. Chem. Soc. 132, 1768 (2010).
22. X. Li, Y. Peng, Z. Wang, Y. Yan, CrystEngComm 13, 3657 (2011).
23. MFI and BEA are two different framework-type codes assigned by the Structural Commission of the International Zeolite Association. Silicalite-1 and ZSM-5 belong to MFI. ZSM-5 has aluminosilicate frameworks with varying Si/Al ratios, whereas silicalite-1 has a pure silica framework. BEA is also often called beta zeolite. BEA has aluminosilicate frameworks with varying Si/Al ratios, whereas pure silica BEA (Si-BEA) has a pure silica framework.
24. C. Baerlocher, W. M. Meier, D. H. Olson, Atlas of Zeolite Framework Types (Elsevier, Amsterdam, ed. 5, 2001), pp. 184-185.
25. O. Larlus, V. Valtchev, Microporous Mesoporous Mater. 93, 55 (2006).
26. O. Larlus, V. Valtchev, Chem. Mater. 17, 881 (2005).
27. A. Mitra et al., Ind. Eng. Chem. Res. 43, 2946 (2004).
28. A. Mitra et al., J. Electrochem. Soc. 149, B472 (2002).
29. S. Mintova, M. Reinelt, T. H. Metzger, J. Senker, T. Bein, Chem. Commun. 2003, 326 (2003).
30. K. B. Yoon, Acc. Chem. Res. 40, 29 (2007).
31. R. Singh, P. K. Dutta, in Handbook of Zeolite Science and Technology, S. Auerbach, K. Carrado, P. Dutta, Eds. (Marcel Dekker, New York, 2003), chap. 2.
32. A. Marinkovic et al., Microporous Mesoporous Mater. 71, 117 (2004).
33. D. Bhange, V. Ramaswamy, Mater. Res. Bull. 41, 1392 (2006).
34. J. S. Lee, J. H. Kim, Y. J. Lee, N. C. Jeong, K. B. Yoon, Angew. Chem. Int. Ed. 46, 3087 (2007).
35. The transfer of nutrients from the dry gel to the seed layer seems to be carried out by a small amount of moisture, which vaporizes into steam at the reaction temperature.
36. As the reaction temperature increases, the growth rate increases. However, as a possible means to incorporate more second-order NLO dyes into the channels, we chose the relatively low reaction temperatures (140° to 180°C) with the hypothesis that the number of defect sites in the channels would decrease as the growth rate decreased.
37. The thickness of the seed crystal does not affect the growth rate. However, if one wants to reach the desired thickness faster, it will be beneficial to start with thicker seed crystals.
38. H. Karsli, A. Çulfaz, H. Yücel, Zeolites 12, 728 (1992).