Chain length effects in isoflavonoid daidzein alkoxy derivatives as antioxidants: A quantum mechanical approach

Journal of Agricultural and Food Chemistry

Volumn 59, Issue 23, 2011, Pages 12652-12657

  An, Cun Bin ^a   Li, Dan ^a   Liang, Ran ^a   Bu, Ya Zhong ^a   Wang, Sha ^a   Zhang, Er Hai ^a   Wang, Peng ^a   Ai, Xi Cheng ^a   Zhang, Jian Ping ^a   Skibsted, Leif H ^b  

^a RENMIN UNIVERSITY OF CHINA   (China)

^b UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

antioxidation; daidzein derivative; dipole moment; frontier orbital energy gap; Isoflavonoid

Indexed keywords

ALKYL CHAIN LENGTHS; ANTI OXIDATIVE ACTIVITY; ANTI-OXIDATION; AQUEOUS PHASE; BOND DISSOCIATION ENERGIES; DAIDZEIN; FLUORESCENCE ANISOTROPY; FLUORESCENT PROBES; FRONTIER ORBITAL ENERGIES; HYDROGEN ATOMS; ISOFLAVONOIDS; LIPID OXIDATION; MICROSCOPIC PROPERTIES; O-H BOND; OXIDATION POTENTIALS; PROOXIDATIVE EFFECTS; QUANTUM MECHANICAL; QUANTUM-MECHANICAL CALCULATION; TETRA-HYDROFURAN; TROLOX EQUIVALENT ANTIOXIDANT CAPACITIES;

AGENTS; CHAIN LENGTH; DENSITY FUNCTIONAL THEORY; DIHEDRAL ANGLE; DIPOLE MOMENT; ENERGY GAP; FLUORESCENCE; HYDROGEN; LIPID BILAYERS; LIPOSOMES; PHENOLS; PHOSPHOLIPIDS; QUANTUM THEORY; SOLIDS;

CYCLIC VOLTAMMETRY;

ANTIOXIDANT; DAIDZEIN; ISOFLAVONE DERIVATIVE; LIPOSOME; OXIDIZING AGENT;

ARTICLE; CHEMISTRY; LIPID PEROXIDATION; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTITATIVE STRUCTURE ACTIVITY RELATION; SYNTHESIS; THERMODYNAMICS;

ANTIOXIDANTS; ISOFLAVONES; LIPID PEROXIDATION; LIPOSOMES; MAGNETIC RESONANCE SPECTROSCOPY; MASS SPECTROMETRY; OXIDANTS; QUANTITATIVE STRUCTURE-ACTIVITY RELATIONSHIP; THERMODYNAMICS;

EID: 83055196916     PISSN: 00218561     EISSN: 15205118     Source Type: Journal    
DOI: 10.1021/jf2030314     Document Type: Article

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