Tetrapalladium complex with bridging germylene ligands. Structural change of the planar Pd4Ge3 core

Journal of the American Chemical Society

Volumn 133, Issue 46, 2011, Pages 18598-18601

  Tanabe, Makoto ^a   Ishikawa, Naoko ^a   Chiba, Mai ^a   Ide, Tomohito ^a   Osakada, Kohtaro ^a   Tanase, Tomoaki ^b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b NARA WOMEN'S UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

DFT CALCULATION; GERMYLENES; NMR MEASUREMENTS; STRUCTURAL CHANGE; TIME-SCALES;

DENSITY FUNCTIONAL THEORY; GERMANIUM; LIGANDS; SILVER HALIDES;

PALLADIUM COMPOUNDS;

COPPER; LIGAND; PALLADIUM COMPLEX; SILVER;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; SURFACE PROPERTY; X RAY ANALYSIS;

EID: 83055161572     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja208565q     Document Type: Article

References (42)

1. Braunstein, P., Oro, L. A., Raithby, P. R., Eds. Metal Clusters in Chemistry, Vol. 1; Wiley-VCH: Weinheim, 1999.
2. (a) Doyle, G.; Eriksen, K. A.; van Engen, D. J. Am. Chem. Soc. 1986, 108, 445-451.
3. (b) Albano, V. G.; Azzaroni, F.; Iapalucci, M. C.; Longoni, G.; Monari, M.; Mulley, S.; Proserpio, D. M.; Sironi, A. Inorg. Chem. 1994, 33, 5320-5328.
4. (c) Albano, V. G.; Iapalucci, M. C.; Longoni, G.; Manzi, L.; Monari, M. Organometallics 1997, 16, 497-499.
5. (d) Egold, H.; Schraa, M.; Flörke, U.; Partyka, J. Organometallics 2002, 21, 1925-1932.
6. (e) Sculfort, S.; Croizat, P.; Messaoudi, A.; Bénard, M.; Rohmer, M.-M.; Welter, R.; Braunstein, P. Angew. Chem., Int. Ed. 2009, 48, 9663-9667.
7. (a) Murahashi, T.; Fujimoto, M.; Oka, M.; Hashimoto, Y.; Uemura, T.; Tatsumi, Y.; Nakao, Y.; Ikeda, A.; Sakaki, S.; Kurosawa, H. Science 2006, 313, 1104-1107.
8. (b) Murahashi, T.; Inoue, R.; Usui, K.; Ogishi, S. J. Am. Chem. Soc. 2009, 131, 9888-9889.
9. Cerrada, E.; Contel, M.; Valencia, A. D.; Laguna, M.; Gelbrich, T.; Hursthouse, M. B. Angew. Chem., Int. Ed. 2000, 39, 2353-2356.
10. Reviews: (a) Ogino, H.; Tobita, H. Adv. Organomet. Chem. 1998, 42, 223-290.
11. (b) Corey, J. Y.; Braddock-Wilking, J. Chem. Rev. 1999, 99, 175-292.
12. (c) Braunstein, P.; Boag, N. M. Angew. Chem., Int. Ed. 2001, 40, 2427-2433.
13. (d) Osakada, K.; Tanabe, M. Bull. Chem. Soc. Jpn. 2005, 78, 1887-1898.
14. (e) Shimada, S.; Tanaka, M. Coord. Chem. Rev. 2006, 250, 991-1011.
15. (f) Waterman, R.; Hays, P. G.; Tilley, T. D. Acc. Chem. Res. 2007, 40, 712-719.
16. (g) Corey, J. Y. Chem. Rev. 2011, 111, 863-1071.
17. (a) Yang, J.; Rosal, I. D.; Fasulo, M.; Sangtrirutnugul, P.; Maron, L.; Tilley, T. D. Organometallics 2010, 29, 5544-5550.
18. (b) Chen, W.; Shimada, S.; Tanaka, M. Science 2002, 295, 308-310.
19. (c) Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 1917-1919.
20. (d) Osakada, K.; Tanabe, M.; Tanase, T. Angew. Chem., Int. Ed. 2000, 39, 4053-4055.
21. (e) Braddock-Wilking, J.; Corey, J. Y.; Dill, K.; Rath, N. P. Organometallics 2002, 21, 5467-5469.
22. (f) Arii, H.; Takahashi, M.; Nanjo, M.; Mochida, K. Organometallics 2009, 28, 4629-4631.
23. (g) Hirotsu, M.; Nishida, T.; Sasaki, H.; Muraoka, T.; Yoshimura, T.; Ueno, K. Organometallics 2007, 26, 2495-2498.
24. (a) Anema, S. G.; Lee, S. K.; Mackay, K. M.; Nicholson, B. K. J. Organomet. Chem. 1993, 444, 211-218.
25. (b) Evans, C. E.; Harfoot, G. J.; McIndoe, J. S.; McAdam, C. J.; Mackay, K. M.; Nicholson, B. K.; Robinson, B. H.; van Tiel, M. L. J. Chem. Soc., Dalton Trans. 2002, 4678-4683.
26. Shimada, S.; Li, Y.-H.; Choe, Y.-K.; Tanaka, M.; Bao, M.; Uchimaru, T. Proc. Natl. Acad. Sci. U. S. A. 2007, 104, 7758-7763.
27. Arii, H.; Takahashi, M.; Nanjo, M.; Mochida, K. Organometallics 2011, 30, 917-920.
28. Yamada, T.; Mawatari, A.; Tanabe, M.; Osakada, K.; Tanase, T. Angew. Chem., Int. Ed. 2009, 48, 568-571.
29. 3 complex with bridging germylene ligands, see: Campbell, G. K.; Hitchcock, P. B.; Lappert, M. F.; Misra, M. C. J. Organomet. Chem. 1985, 289, C1-C4.
30. Tanabe, M.; Ishikawa, N.; Hanzawa, M.; Osakada, K. Organometallics 2008, 27, 5152-5158.
31. Tanabe, M.; Hanzawa, M.; Osakada, K. Organometallics 2010, 29, 3535-3540.
32. Tanabe, M.; Ishikawa, N.; Osakada, K. Organometallics 2006, 25, 796-798.
33. Cygan, Z. T.; Bender, J. E., IV; Litz, K. E.; Kampf, J. W.; Banaszak Holl, M. M. Organometallics 2002, 21, 5373-5381.
34. Frisch, M. J.; et al. Gaussian 09, revision B.01; Gaussian, Inc.: Wallingford, CT, 2009.
35. 6 core stabilized by the Ni-Si and Si-Si bonds. See: Tang, H.; Hoffman, D. M.; Albright, T. A.; Deng, H.; Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1993, 32, 1616-1618.
36. Okazaki, M.; Kimura, H.; Komuro, T.; Okada, H.; Tobita, H. Chem. Lett. 2007, 36, 990-991.
37. Shimada, S.; Rao, M. L. N.; Tanaka, M. Organometallics 1999, 18, 291-293.
38. Adams, R. D.; Pearl, W. C., Jr.; Wong, Y. O.; Zhang, Q.; Hall, M. B.; Walensky, J. R. J. Am. Chem. Soc. 2011, 133, 12994-12997.
39. (a) Puddephatt, R. J.; Manojlovic-Muir, L.; Muir, K. W. Polyhedron 1990, 9, 2767-2802.
40. (b) Imhof, D.; Venanzi, L. M. Chem. Soc. Rev. 1994, 185-193.
41. (c) Burrows, A. D.; Mingos, D. M. P. Coord. Chem. Rev. 1996, 154, 19-69.
42. (d) Burrows, A. D.; Jeffrey, J. G.; Machell, J. C.; Mingos, D. M. P. J. Organomet. Chem. 1991, 406, 399-408.