Intact soil core total, inorganic, and organic carbon measurement using laser-induced breakdown spectroscopy

Soil Science Society of America Journal

Volumn 75, Issue 3, 2011, Pages 1006-1018

  Bricklemyer, Ross S ^a   Brown, David J ^a   Barefield, James E ^b   Clegg, Samuel M ^b  

^a WASHINGTON STATE UNIVERSITY   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AGRICULTURAL FIELDS; CALIBRATION MODEL; FIELD SCALE; MONTANA; PARTIAL LEAST SQUARES; PRECISE ANALYSIS; PREDICTION CAPABILITY; REGRESSION COEFFICIENT; SOIL CORES; SOIL MATRICES; SOIL ORGANIC C; SOIL PROFILES; SPECTRAL DATA; STANDARD ERROR OF PREDICTION;

ATOMIC EMISSION SPECTROSCOPY; C (PROGRAMMING LANGUAGE); CORE SAMPLES; GEOLOGIC MODELS; ORGANIC CARBON; ORGANIC LASERS; SOILS;

SOIL SURVEYS;

ACCURACY ASSESSMENT; AGRICULTURAL LAND; CALIBRATION; CARBON; CONCENTRATION (COMPOSITION); MATRIX; MEASUREMENT METHOD; NUMERICAL MODEL; REGRESSION ANALYSIS; SOIL ORGANIC MATTER; SOIL PROFILE; SOIL TYPE; SPECTROSCOPY; STOCHASTICITY;

EID: 83055160656     PISSN: 03615995     EISSN: None     Source Type: Journal    
DOI: 10.2136/sssaj2009.0244     Document Type: Article

References (53)

1. Andraos, J. 1996. On the propagation of statistical errors for a function of several variables. J. Chem. Educ. 73:150-154. doi:10.1021/ed073p150 (Pubitemid 126581696)
2. Belkov, M.V., V.S. Burakov, A. De Giacomo, V.V. Kiris, S.N. Raikov, and N.V. Tarasenko. 2009. Comparison of two laser-induced breakdown spectroscopy techniques for total carbon measurement in soils. Spectrochim. Acta Part B 64:899-904.
3. Bel'kov, M.V., V.S. Burakov, V.V. Kiris, V.A. Kononov, S.N. Raikov, V.N. Reshetnikov, and N.V. Tarasenko. 2008. Determination of carbon in soil by laser spectral analysis. J. Appl. Spectrosc. 75:275-282.
4. Bousquet, B., J.B. Sirven, and L. Canioni. 2007. Towards quantitative laserinduced breakdown spectroscopy analysis of soil samples. Spectrochim. Acta Part B 62:1582-1589. (Pubitemid 350213354)
5. Bousquet, B., G. Travaille, A. Ismael, L. Canioni, K.M.L. Pierres, E. Brasseur, et al. 2008. Development of a mobile system based on laser-induced breakdown spectroscopy and dedicated to in situ analysis of polluted soils. Spectrochim. Acta Part B 63:1085-1090.
6. Box, G.E.P., and D.R. Cox. 1964. An analysis of transformations (with discussion). J. R. Stat. Soc. Ser. B 26:211-252.
7. Bricklemyer, R.S., and D.J. Brown. 2010. On-the-go VisNIR: Potential and limitations for mapping soil clay and organic carbon. Comput. Electron. Agric. 70:209-216. doi:10.1016/j.compag.2009.10.006
8. Bricklemyer, R.S., P.R. Miller, K. Paustian, T. Keck, G.A. Nielsen, and J.M. Antle. 2005. Soil organic carbon variability and sampling optimization in Montana dryland wheat fields. J. Soil Water Conserv. 60:42-51. (Pubitemid 40234611)
9. Brown, D.J., R.S. Bricklemyer, and P.R. Miller. 2005. Validation requirements for diffuse reflectance soil characterization models with a case study of VNIR soil C prediction in Montana. Geoderma 129:251-267. doi:10.1016/j.geoderma.2005.01.001 (Pubitemid 41550347)
10. Brown, D.J., K.D. Shepherd, M.G. Walsh, M.D. Mays, and T.G. Reinsch. 2006. Global soil characterization with VNIR diffuse reflectance spectroscopy. Geoderma 132:273-290. doi:10.1016/j.geoderma.2005.04.025
11. Carbon and Climate Working Group. 1999. A U.S. carbon cycle science plan. U.S. Global Change Res. Progr., Washington, DC.
12. Castle, B.C., K. Talabardon, B.W. Smith, and J.D. Winefordner. 1998. Variables influencing the precision of laser-induced breakdown spectroscopy measurements. Appl. Spectrosc. 52:649-657. (Pubitemid 128618644)
13. Christy, C.D. 2008. Real-time measurement of soil attributes using on-the-go near infrared reflectance spectroscopy. Comput. Electron. Agric. 61:10-19. doi:10.1016/j.compag.2007.02.010 (Pubitemid 351220836)
14. Clark, R.N. 1999. Spectroscopy of rocks and minerals, and principles of spectroscopy. p. 3-52. In N. Rencz (ed.) Remote sensing for the earth sciences: Manual of remote sensing. John Wiley & Sons, New York.
15. Clegg, S.M., E. Sklute, M.D. Dyar, J.E. Barefield, and R.C. Wiens. 2009. Multivariate analysis of remote laser-induced breakdown spectroscopy spectra using partial least squares, principal component analysis, and related techniques. Spectrochim. Acta Part B 64:79-88. doi:10.1016/j.sab.2008.10.045
16. Cremers, D.A., M.H. Ebinger, D.D. Breshears, P.J. Unkefer, S.A. Kammerdiener, M.J. Ferris, K.M. Catlett, and J.R. Brown. 2001. Measuring total soil carbon with laser-induced breakdown spectroscopy (LIBS). J. Environ. Qual. 30:2202-2206. doi:10.2134/jeq2001.2202 (Pubitemid 33134408)
17. Cremers, D.A., and L.J. Radziemski. 2006. Handbook of laser-induced breakdown spectroscopy. John Wiley & Sons, Chichester, UK.
18. Dardenne, P., G. Sinnaeve, and V. Baeten. 2000. Multivariate calibration and chemometrics for near infrared spectroscopy: Which method? J. Near Infrared Spectrosc. 8:229-237. doi:10.1255/jnirs.283
19. Dudragne, L., P. Adam, and J. Amouroux. 1998. Time-resolved laser-induced breakdown spectroscopy: Application for qualitative and quantitative detection of fluorine, chlorine, sulfur, and carbon in air. Appl. Spectrosc. 52:1321-1327. (Pubitemid 128635135)
20. Ebinger, M.H., M.L. Norfleet, D.D. Breshears, D.A. Cremers, M.J. Ferris, P.J. Unkefer, M.S. Lamb, K.L. Goddard, and C.W. Meyer. 2003. Extending the applicability of laser-induced breakdown spectroscopy for total soil carbon measurement. Soil Sci. Soc. Am. J. 67:1616-1619. doi:10.2136/sssaj2003.1616 (Pubitemid 37143596)
21. Eppler, A.S., D.A. Cremers, D.D. Hickmott, M.J. Ferris, and A.C. Koskelo. 1996. Matrix effects in the detection of Pb and Ba in soils using laser-induced breakdown spectroscopy. Appl. Spectrosc. 50:1175-1181. (Pubitemid 126619399)
22. Ferreira, E.C., D.M.B.P. Milori, E.J. Ferreira, R.M. da Silva, and L. Martin-Neto. 2008. Artificial neural network for Cu quantitative determination in soil using a portable laser induced breakdown spectroscopy system. Spectrochim. Acta Part B 63:1216-1220.
23. Gauch, H.G., J.T.G. Hwang, and G.W. Fick. 2003. Model evaluation by comparison of model-based predictions and measured values. Agron. J. 95:1442-1446. doi:10.2134/agronj2003.1442 (Pubitemid 37515004)
24. Gehl, R.J., and C.W. Rice. 2007. Emerging technologies for in situ measurement of soil carbon. Clim. Change 80:43-54. doi:10.1007/s10584-006-9150-2 (Pubitemid 46144238)
25. Geladi, P., and B.R. Kowalski. 1986. Partial least-squares regression: A tutorial. Anal. Chim. Acta 185:1-17. doi:10.1016/0003-2670(86)80028-9
26. Gornushkin, S.I., I.B. Gornushkin, J.M. Anzano, B.W. Smith, and J.D. Winefordner. 2002. Effective normalization technique for correction of matrix effects in laser-induced breakdown spectroscopy detection of magnesium in powdered samples. Appl. Spectrosc. 56:433-436. (Pubitemid 34531085)
27. Hakkanen, H.J., and J.E.I. Korppi-Tommola. 1998. Laser-induced plasma emission spectrometric study of pigments and binders in paper coatings: Matrix effects. Anal. Chem. 70:4724-4729. doi:10.1021/ac980220j (Pubitemid 28532945)
28. Harris, R.D., D.A. Cremers, M.H. Ebinger, and B.K. Bluhm. 2004. Determination of nitrogen in sand using laser-induced breakdown spectroscopy. Appl. Spectrosc. 58:770-775. doi:10.1366/0003702041389201
29. Hunt, G.R. 1982. Spectroscopic properties of rocks and minerals. p. 295-385. In R.S. Carmichael (ed.) Handbook of physical properties of rocks. CRC Press, Boca Raton, FL.
30. Islam, K., B. Singh, and A. McBratney. 2003. Simultaneous estimation of several soil properties by ultra-violet, visible, and near-infrared reflectance spectroscopy. Aust. J. Soil Res. 41:1101-1114. doi:10.1071/SR02137 (Pubitemid 37457865)
31. Kaufman, L., and P.J. Rousseeuw. 1990. Finding groups in data: An introduction to cluster analysis. John Wiley & Sons, New York.
32. Martin, M.Z., N. Labbe, N. Andre, R. Harris, M. Ebinger, S.D. Wullschleger, and A.A. Vass. 2007. High resolution applications of laser-induced breakdown spectroscopy for environmental and forensic applications. Spectrochim. Acta Part B 62:1426-1432. (Pubitemid 350218210)
33. Martin, M.Z., N. Labbe, N. Andre, S.D. Wullschleger, R.D. Harris, and M.H. Ebinger. 2010. Novel multivariate analysis for soil carbon measurements using laser-induced breakdown spectroscopy. Soil Sci. Soc. Am. J. 74:87-93. doi:10.2136/sssaj2009.0102
34. Martin, M.Z., N. Labbe, T.G. Rials, and S.D. Wullschleger. 2005a. Analysis of preservative-treated wood by multivariate analysis of laser-induced breakdown spectroscopy spectra. Spectrochim. Acta Part B 60:1179-1185. doi:10.1016/j.sab.2005.05.022 (Pubitemid 41379071)
35. Martin, M.Z., S.D. Wullschleger, C.T. Garten, and A.V. Palumbo. 2003. Laser-induced breakdown spectroscopy for the environmental determination of total carbon and nitrogen in soils. Appl. Opt. 42:2072-2077. doi:10.1364/AO.42.002072
36. Martin, M.Z., S.D. Wullschleger, C.T. Garten, A.V. Palumbo, and J.G. Smith. 2005b. Elemental analysis of environmental and biological samples using laser-induced breakdown spectroscopy and pulsed Raman spectroscopy. J. Dispersion Sci. Technol. 25:687-694. doi:10.1081/DIS-200027329
37. Mevik, B.H., and R. Wehrens. 2007. The pls package: Principal component and partial least squares regression in R. J. Stat. Softw. 18(2).
38. Morgan, C.L.S., T.H. Waiser, D.J. Brown, and C.T. Hallmark. 2009. Simulated in situ characterization of soil organic and inorganic carbon with visible near-infrared diffuse reflectance spectroscopy. Geoderma 151:249-256. doi:10.1016/j.geoderma.2009.04.010
39. Mosier-Boss, P.A., S.H. Lieberman, and G.A. Theriault. 2002. Field demonstrations of a direct push FO-LIBS metal sensor. Environ. Sci. Technol. 36:3968-3976. doi:10.1021/es020528z (Pubitemid 35024508)
40. R Development Core Team. 2008. R: A language and environment for statistical computing. Available at www.R-project.org (verified 13 Mar. 2011). R Foundation for Statistical Computing, Vienna.
41. Radziemski, L.J., and D.A. Cremers. 1989. Spectrochemical analysis using laser plasma excitation. p. 295-325. In L.J. Radziemski and D.A. Cremers (ed.) Laser-induced plasmas and applications. Marcel Dekker, New York.
42. Salle, B., J.L. Lacour, P. Mauchien, P. Fichet, S. Maurice, and G. Manhes. 2006. Comparative study of different methodologies for quantitative rock analysis by laser-induced breakdown spectroscopy in a simulated Martian atmosphere. Spectrochim. Acta Part B 61:301-313.
43. Sherrod, L.A., G. Dunn, G.A. Peterson, and R.L. Kolberg. 2002. Inorganic carbon analysis by modified pressure-calcimeter method. Soil Sci. Soc. Am. J. 66:299-305. doi:10.2136/sssaj2002.0299 (Pubitemid 34108514)
44. Sirven, J.-B., B. Bousquet, L. Canioni, and L. Sarger. 2006. Laser-induced breakdown spectroscopy of composite samples: Comparison of advanced chemometrics methods. Anal. Chem. 78:1462-1469. doi:10.1021/ac051721p (Pubitemid 43346281)
45. Sposito, G. 2008. The chemistry of soils. 2nd ed. Oxford Univ. Press, New York.
46. Thompson, J.R., R.C. Wiens, J.E. Barefield, D.T. Vaniman, H.E. Newsom, and S.M. Clegg. 2006. Remote laser-induced breakdown spectroscopy analyses of Dar al Gani 476 and Zagami Martian meteorites. J. Geophys. Res. Planets 111:E05006.
47. Tucker, J.M., M.D. Dyar, M.W. Schaefer, S.M. Clegg, and R.C. Wiens. 2010. Optimization of laser-induced breakdown spectroscopy for rapid geochemical analysis. Chem. Geol. 277:137-148.
48. Venables, W.N., and B.D. Ripley. 2002. Modern applied statistics with S. 4th ed. Springer, New York.
49. Waiser, T.H., C.L.S. Morgan, D.J. Brown, and C.T. Hallmark. 2007. In situ characterization of soil clay content with visible near-infrared diffuse reflectance spectroscopy. Soil Sci. Soc. Am. J. 71:389-396. doi:10.2136/ sssaj2006.0211 (Pubitemid 46449493)
50. Wold, S., M. Sjostrom, and L. Eriksson. 2001. PLS-regression: A basic tool of chemometrics. Chemom. Intell. Lab. Syst. 58:109-130. doi:10.1016/S0169-7439(01)00155-1 (Pubitemid 33033283)
51. Workman, J.J., Jr. 2001. NIR spectroscopy: Calibration basics. p. 91-128. In D.A. Burns and E.W. Ciurczak (ed.) Handbook of near-infrared analysis. 2nd ed. Pract. Spectrosc. 27. Marcel Dekker, New York.
52. Yamamoto, K.Y., D.A. Cremers, M.J. Ferris, and L.E. Foster. 1996. Detection of metals in the environment using a portable laser-induced breakdown spectroscopy instrument. Appl. Spectrosc. 50:222-233. doi:10.1366/ 0003702963906519 (Pubitemid 126620517)
53. Yaroshchyk, P., D. Body, R.J.S. Morrison, and B.L. Chadwick. 2006. A semi-quantitative standard-less analysis method for laser-induced breakdown spectroscopy. Spectrochim. Acta Part B 61:200-209. doi:10.1016/j.sab.2006.01.004