Photocatalytic degradation kinetics and mechanism of antivirus drug-lamivudine in TiO 2 dispersion

Journal of Hazardous Materials

Volumn 197, Issue , 2011, Pages 229-236

  An, Taicheng ^a   An, Jibin ^a,b,d   Yang, Hai ^a,d   Li, Guiying ^a   Feng, Huixia ^b   Nie, Xiangping ^c  

^a GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

^b LANZHOU UNIVERSITY OF TECHNOLOGY   (China)

^c JINAN UNIVERSITY   (China)

^d UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Central composite design; Kinetics; Lamivudine; Mechanism; Photocatalytic degradation

Indexed keywords

ANTI VIRUS; CENTRAL COMPOSITE DESIGNS; DEGRADATION EFFICIENCY; DEGRADATION INTERMEDIATES; FRONTIER ELECTRON DENSITIES; HPLC/MS/MS; HYDROXYL RADICALS; INDEPENDENT VARIABLES; INITIAL PH; LAMIVUDINE; MODELING RESULTS; PHOTOCATALYTIC DEGRADATION; PHOTOCATALYTIC DEGRADATION MECHANISM; POINT CHARGE; REACTIVE SPECIES; RESPONSE SURFACE METHODOLOGY; TIO; TOTAL ORGANIC CARBON;

DISPERSIONS; EFFICIENCY; ENZYME KINETICS; ION CHROMATOGRAPHY; KINETICS; MECHANISMS; ORGANIC CARBON; PHOTOCATALYSIS; PHOTODEGRADATION; SURFACE PROPERTIES; TITANIUM DIOXIDE;

DEGRADATION;

HYDROXYL RADICAL; LAMIVUDINE; ORGANIC CARBON; TITANIUM DIOXIDE;

ANTIMICROBIAL ACTIVITY; CATALYSIS; CHROMATOGRAPHY; CONCENTRATION (COMPOSITION); DATA SET; DISPERSION; DRUG; EXPERIMENTAL STUDY; HYDROXYL RADICAL; OPTIMIZATION; ORGANIC CARBON; OXIDE; PHOTODEGRADATION; REACTION KINETICS; THEORETICAL STUDY;

ARTICLE; DEGRADATION KINETICS; DISPERSION; DRUG DEGRADATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; ION PAIR CHROMATOGRAPHY; MASS SPECTROMETRY; PH; PHOTOCATALYSIS; RESPONSE SURFACE METHOD; ULTRAVIOLET RADIATION;

CATALYSIS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; KINETICS; LAMIVUDINE; PHOTOCHEMISTRY; REVERSE TRANSCRIPTASE INHIBITORS; TITANIUM;

EID: 82155162459     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2011.09.077     Document Type: Article

References (30)

1. Cahill J.D., Furlong E.T., Burkhardt M.R., Kolpin D., Anderson L.G. Determination of pharmaceutical compounds in surface- and ground-water samples by solid-phase extraction and high-performance liquid chromatography-electrospray ionization mass spectrometry. J. Chromatogr. A 2004, 1041:171-180.
2. Clara M., Strenn B., Kreuzinger N. Carbamazepine as a possible anthropogenic marker in the aquatic environment: investigations on the behaviour of Carbamazepine in wastewater treatment and during groundwater infiltration. Water Res. 2004, 38:947-954.
3. Guardabassi L., Lo Fo Wong D.M.A., Dalsgaard A. The effects of tertiary wastewater treatment on the prevalence of antimicrobial resistant bacteria. Water Res. 2002, 36:1955-1964.
4. Sumpter J.P. Xenoendocrine disrupters - environmental impacts. Toxicol. Lett. 1998, 102-103:337-342.
5. Halling-Sørensen B., Nors Nielsen S., Lanzky P.F., Ingerslev F., Holten Lützhøft H.C., Jørgensen S.E. Occurrence, fate and effects of pharmaceutical substances in the environment - a review. Chemosphere 1998, 36:357-393.
6. Prasse C., Schlüsener M.P., Schulz R., Ternes T.A. Antiviral drugs in wastewater and surface waters: a new pharmaceutical class of environmental relevance?. Environ. Sci. Technol. 2010, 44:1728-1735.
7. n. J. Pharm. Biomed. Anal. 2009, 49:55-63.
8. Rizzo L., Meric S., Guida M., Kassinos D., Belgiorno V. Heterogenous photocatalytic degradation kinetics and detoxification of an urban wastewater treatment plant effluent contaminated with pharmaceuticals. Water Res. 2009, 43:4070-4078.
9. 2 heterogeneous catalysis. J. Phys. Chem. A 2010, 114:2569-2575.
10. 2: a case of sulfa drugs. Catal. Today 2010, 153:200-207.
11. Sakkas V.A., Calza P., Medana C., Villioti A.E., Baiocchi C., Pelizzetti E., Albanis T. Heterogeneous photocatalytic degradation of the pharmaceutical agent salbutamol in aqueous titanium dioxide suspensions. Appl. Catal. B: Environ. 2007, 77:135-144.
12. Kaneco S., Li N., Itoh K.K., Katsumata H., Suzuki K., Ohta K. Titanium dioxide mediated solar photocatalytic degradation of thiram in aqueous solution: kinetics and mineralization. Chem. Eng. J. 2009, 148:50-56.
13. Pérez M., Torrades F., Peral J., Lizama C., Bravo C., Casas S., Freer J., Mansilla H.D. Multivariate approach to photocatalytic degradation of a cellulose bleaching effluent. Appl. Catal. B: Environ. 2001, 33:89-96.
14. 2 suspended solution. J. Hazard. Mater. 2008, 157:300-307.
15. An T.C., Yang H., Li G.Y., Song W.H., Cooper W.J., Nie X.P. Kinetics and mechanism of advanced oxidation processes (AOPs) in degradation of ciprofloxacin in water. Appl. Catal. B: Environ. 2010, 94:288-294.
16. 2 dispersions by computer simulation. J. Photochem. Photobiol. A: Chem. 2001, 141:201-207.
17. 2: a case of beta-blockers. J. Hazard. Mater. 2010, 179:834-839.
18. Ollis D.F. Kinetics of liquid phase photocatalyzed reactions: an illuminating approach. J. Phys. Chem. B 2005, 109:2439-2444.
19. Emeline A.V., Ryabchuk V.K., Serpone N. Dogmas and misconceptions in heterogeneous photocatalysis. Some enlightened reflections. J. Phys. Chem. B 2005, 109:18515-18521.
20. An T.C., Xiong Y., Li G.Y., Zha C.H., Zhu X.H. Synergetic effect in degradation of formic acid using a new photoelectrochemical reactor. J. Photochem. Photobiol. A: Chem. 2002, 152:155-165.
21. Candal R.J., Zeltner W.A., Anderson M.A. Effects of pH and applied potential on photocurrent and oxidation rate of saline solutions of formic acid in a photoelectrocatalytic reactor. Environ. Sci. Technol. 2000, 34:3443-3451.
22. 2 thin films. J. Photochem. Photobiol. A: Chem. 1996, 94:221-229.
23. Hoffmann M.R., Martin S.T., Choi W., Bahnemann D.W. Environmental applications of semiconductor photocatalysis. Chem. Rev. 1995, 95:69-96.
24. 2 surface characteristic in UV-illuminated photodegradation of Acid Orange 7. J. Photochem. Photobiol. A: Chem. 2005, 172:47-54.
25. Minero C., Mariella G., Maurino V., Vione D., Pelizzetti E. Photocatalytic transformation of organic compounds in the presence of inorganic ions. 2. Competitive reactions of phenol and alcohols on a titanium dioxide-fluoride system. Langmuir 2000, 16:8964-8972.
26. 2. Appl. Catal. B: Environ. 2005, 59:147-154.
27. Rabani J., Yamashita K., Ushida K., Stark J., Kira A. Fundamental reactions in illuminated titanium dioxide nanocrystallite layers studied by pulsed laser. J. Phys. Chem. B 1998, 102:1689-1695.
28. 2/UV system: optimization and modeling using a response surface methodology (RSM) based on the central composite design. Dyes Pigments 2007, 75:533-543.
29. 2. Appl. Catal. B: Environ. 2004, 48:205-211.
30. Fernández J., Kiwi J., Lizama C., Freer J., Baeza J., Mansilla H.D. Factorial experimental design of Orange II photocatalytic discolouration. J. Photochem. Photobiol. A: Chem. 2002, 151:213-219.