Ordering phenomena in nanostructured poly(styrene-b-butadiene-b-styrene) (SBS) membranes for selective ethanol transport

Journal of Membrane Science

Volumn 385-386, Issue 1, 2011, Pages 162-170

  Buonomenna, M G ^a   Golemme, G ^a,b   Tone, C M ^a   De Santo, M P ^a   Ciuchi, F ^a   Perrotta, E ^a   Zappone, B ^a   Galiano, F ^b   Figoli, A ^b  

^a UNIVERSITY OF CALABRIA   (Italy)

^b INSTITUTE ON MEMBRANE TECHNOLOGY   (Italy)

Author keywords

Interaction parameters; Nanostructured domains; Poly(styrene b butadiene b styrene); Selective transport

Indexed keywords

AFM; INTERACTION PARAMETERS; NANO-STRUCTURED; NANOSCALE MORPHOLOGY; ORDERING PHENOMENA; POLY(STYRENE-B-BUTADIENE-B-STYRENE); SBS BLOCK COPOLYMER; SELECTIVE TRANSPORT;

BLOCK COPOLYMERS; BUTADIENE; COPOLYMERIZATION; ETHANOL; POLYBUTADIENES; POLYSTYRENES; STYRENE;

NANOSTRUCTURES;

1,3 BUTADIENE; ALCOHOL; COPOLYMER; NANOMATERIAL; POLY(STYRENE B BUTADIENE B STYRENE); POLYBUTADIENE; POLYSTYRENE; SOLVENT; STYRENE DERIVATIVE; UNCLASSIFIED DRUG; WATER;

ARTICLE; ATOMIC FORCE MICROSCOPY; FOURIER TRANSFORMATION; IMAGE ANALYSIS; MORPHOLOGY; PRIORITY JOURNAL; SOLUBILITY; SURFACE PROPERTY; TRANSMISSION ELECTRON MICROSCOPY;

EID: 80755136645     PISSN: 03767388     EISSN: 18733123     Source Type: Journal    
DOI: 10.1016/j.memsci.2011.09.035     Document Type: Article

References (30)

1. 2 capture. Nanotechnology 2010, 21:395301-395308.
2. Zhang Q., Tsui O.K.C., Du B., Zhang F., Tang T., He T. Observation of inverted phases in poly(styrene-b-butadiene-b-styrene) triblock copolymer by solvent-induced order-disorder phase transition. Macromolecules 2000, 33:9561-9567.
3. Thurn-Albrecht T., Schotter J., Kästle G.A., Emley N., Shibauchi T., Krusin-Elbaum L., Guarini K., Black C.T., Tuominen M.T., Russell T.P. Ultrahigh-density nanowire arrays grown in self-assembled diblock copolymer templates. Science 2000, 290:2126-2129.
4. Kim S.O., Solak H.H., Stoykovich M.P., Ferrier N.J., De Pablo J.J., Nealey P.F. Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates. Nature 2003, 424:411-414.
5. Cheng J.Y., Ross C.A., Thomas E.L., Smith H.I., Vancso G.J. Fabrication of nanostructures with long-range order using block copolymer lithography. Appl. Phys. Lett. 2002, 81:3657-3660.
6. Huang E., Rockford L., Russell T.P., Hawker C. Nanodomain control in copolymer thin films. Nature 1998, 395:757-758.
7. Faridi N., Duda J.L., Hadi-Romdhane I. Unsteady-state diffusion in block copolymers with lamellar domains. Ind. Eng. Chem. Res. 1995, 34:3556-3567.
8. Rehse N., Knoll A., Magerle R., Krausch G. Surface reconstruction of lamellar ABC triblock copolymer mesostructures. Macromolecules 2003, 36:3261-3271.
9. Ruzette A.V., Leibler L. Block copolymers in tomorrow's plastics. Nat. Mater. 2005, 4:19-31.
10. Yave W. Membranes from block copolymers. Advanced Materials for Membrane Preparation 2011, 143-153. Bentham Science Publishers, Sharjah, UAE, (Chapter 10). M.G. Buonomenna, G. Golemme (Eds.).
11. Srinivasan K., Palanivelu K., Navaneetha Gopalakrishnan A. Recovery of 1-butanol from a model pharmaceutical aqueous waste by pervaporation. Chem. Eng. Sci. 2007, 62:2905-2914.
12. Vane M. A review of pervaporation for product recovery from biomass fermentation processes. J. Chem. Technol. Biotechnol. 2005, 80:603-629.
13. Verhoef A., Figoli A., Leen B., Bettens B., Drioli E., Van der Bruggen B. Performance of a nanofiltration membrane for removal of ethanol from aqueous solutions by pervaporation. Sep. Purif. Technol. 2008, 60:54-63.
14. Hasanoglu A., Salt Y., Keleser S., Okzan S., Dinçer S. Pervaporation separation of organics from multicomponent aqueous mixtures. Chem. Eng. Process. 2007, 46:300-306.
15. Jia M.D., Peinemann K.-V., Behling R.-D. Preparation and characterization of thin-film zeolite-PDMS composite membranes. J. Membr. Sci. 1992, 73:119-128.
16. Vankelecom I.F.J., Depre D., De Beukelaer S., Uytterhoeven J.B. Influence of zeolites in PDMS membranes: pervaporation of water/alcohol mixtures. J. Phys. Chem. 1995, 99:13193-13197.
17. Chovau S., Dobrak A., Figoli A., Galiano F., Simone S., Drioli E., Sikdar S.K., Van der Bruggen B. Pervaporation performance of unfilled and filled PDMS membranes and novel SBS membranes for the removal of toluene from diluted aqueous solutions. Chem. Eng. J. 2010, 159:37-46.
18. Zhan X., Li J.-D., Fan C., Han X.-L. Pervaporation separation of ethanol/water mixtures with chlorosilane modified silicalite-1/PDMS hybrid membranes. Chin. J. Polym. Sci. 2010, 28(4):625-635.
19. Zhao C.T., de Pinho M.N. Design of polypropylene oxide/polybutadiene bi-soft segment urethane/urea polymer for pervaporation membranes. Polymer 1999, 40:6089-6097.
20. 2 capture applications. J. Membr. Sci. 2010, 359:54.
21. Husken D., Feijen J., Gaymans R.J. Segmented block copolymers with terephthalic-extended poly(ethylene oxide) segments. Macromol. Chem. Phys. 2008, 209(5):525-534.
22. Huang H., Hu Z., Chen Y., Zhang F., Gong Y., He T., Wu C. Effects of casting solvents on the formation of inverted phase in block copolymer thin films. Macromolecules 2004, 37:6523-6530.
23. Huang H., Zhang F., Hu Z., Du B., He T., Lee F.K., Wang Y., Tsui O.K.C. Study on the origin of inverted phase in drying solution-cast block copolymer films. Macromolecules 2003, 36:4084-4092.
24. Kim G., Libera M. Morphological development in solvent-cast polystyrene-polybutadiene-polystyrene (SBS) triblock copolymer thin films. Macromolecules 1998, 31:2569-2577.
25. Dobrak A., Figoli A., Chovau S., Galiano F., Simone S., Vankelecom I.F.J., Drioli E., Van der Bruggen B. Performance of PDMS membranes in pervaporation: effect of silicalite fillers and comparison with SBS membranes. J. Colloid Interface Sci. 2010, 346:254-264.
26. Jha A.K., Chen L., Offeman R.D., Balsara N.P. Effect of nanoscale morphology on selective ethanol transport through block copolymer membranes. J. Membr. Sci. 2011, 373:112-120.
27. Bazzarelli F., Bernardo P., Tasselli F., Clarizia G., Dzyubenko V.G., Vdovin P., Jansen J.C. Multilayer composite SBS membranes for pervaporation and gas separation. Sep. Purif. Technol. 2011, 80:635-642.
28. M.G. Buonomenna, G. Golemme, C.M. Tone, M.P. De Santo, F. Ciuchi, E. Perrotta, Nanostructured poly(styrene-b-butadiene-b-styrene) (SBS) membranes for the separation of nitrogen from natural gas, submitted for publication.
29. van Krevelen D.W., te Nijenhuis K. Properties of Polymers 2009, Elsevier, The Netherlands.
30. Matsen M.W., Bates F.S. Origins of complex self-assembly in block copolymers. Macromolecules 1996, 29:7641-7644.