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Volumn 109, Issue 51, 2005, Pages 24236-24243

A site-isolated rhodium-diethylene complex supported on highly dealuminated Y zeolite: Synthesis and characterization

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; ETHYLENE; INFRARED SPECTROSCOPY; OXYGEN; REACTION KINETICS; RHODIUM; SPECTRUM ANALYSIS; X RAY ANALYSIS;

EID: 30344454695     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp054623g     Document Type: Article
Times cited : (48)

References (59)
  • 25
    • 84906368877 scopus 로고    scopus 로고
    • note
    • -1 is the result of subtraction of the background spectrum collected with the evacuated cell from the spectrum of the sample formed by adsorption of the rhodium ethylene complex on the zeolite.
  • 27
    • 84906412134 scopus 로고    scopus 로고
    • note
    • 13C resonance in such complexes is close to its gas-phase value of >120 ppm, and therefore such an assignment does not explain the 60 ppm resonance.
  • 33
    • 84906368878 scopus 로고    scopus 로고
    • note
    • -1 (w).
  • 37
    • 84906412130 scopus 로고    scopus 로고
    • note
    • Because of the width of peaks corresponding to acac, the IR spectra do not determine whether all the precursor acac groups reacted.
  • 38
    • 84906383224 scopus 로고    scopus 로고
    • note
    • 22
  • 43
    • 84906368874 scopus 로고    scopus 로고
    • note
    • The only product observed was ethane, and there was no measurable conversion of ethylene and hydrogen in the absence of catalyst or in the presence of the support alone under the conditions of the experiments.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.