Origin of initial uncontrolled polymerization and its suppression in the copper(0)-mediated living radical polymerization of methyl acrylate in a nonpolar solvent

Macromolecules

Volumn 44, Issue 20, 2011, Pages 8034-8041

  West, Andrew G ^a   Hornby, Ben ^a   Tom, Jessica ^a   Ladmiral, Vincent ^a,c   Harrisson, Simon ^b,d   Perrier, Sébastien ^a  

^a UNIVERSITY OF SYDNEY   (Australia)

^b CSIRO   (Australia)

^c UNIVERSITY OF SHEFFIELD   (United Kingdom)

^d UNIVERSITÉ PARIS SACLAY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SPECIES; ALKYL HALIDES; CONTROLLED POLYMERIZATION; COPPER (II); COPPER CATALYST; DISPROPORTIONATIONS; HIGH EFFICIENCY; LIVING RADICAL POLYMERIZATION; LOSS OF CONTROL; METHYL ACRYLATES; NON-POLAR SOLVENTS; RADICAL INITIATORS; RADICAL SCAVENGERS; RADICAL SPECIES; ROOM TEMPERATURE; SINGLE ELECTRON TRANSFER; SYSTEM DISPLAYS;

ACRYLIC MONOMERS; ATOM TRANSFER RADICAL POLYMERIZATION; CATALYSTS; COPPER; DISPLAY DEVICES; FREE RADICAL REACTIONS; POLYMERS; TRANSIENTS;

LIVING POLYMERIZATION;

EID: 80055003724     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma201568h     Document Type: Article

References (56)

1. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721
2. Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614
3. Matyjaszewski, K. Curr. Org. Chem. 2002, 6, 67
4. Ayres, N. Polym. Rev. 2011, 51, 138
5. Sawamoto, M.; Ouchi, M.; Terashima, T. Chem. Rev. 2009, 109, 4963
6. Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7572
7. Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901
8. Matyjaszewski, K.; Davis, K. A.; Paik, H. J. Macromolecules 1999, 32, 1767
9. Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 2216
10. Haddleton, D. M.; Jasieczek, C. B.; Hannon, M. J.; Shooter, A. J. Macromolecules 1997, 30, 2190
11. Matyjaszewski, K.; Jo, S. M.; Paik, H. J.; Shipp, D. A. Macromolecules 1999, 32, 6431
12. Matyjaszewski, K.; Xia, J. H. Chem. Rev. 2001, 101, 2921
13. Fischer, H. Macromolecules 1997, 30, 5666
14. Shipp, D. A.; Matyjaszewski, K. Macromolecules 1999, 32, 2948
15. Matyjaszewski, K.; Jakubowski, W.; Min, K.; Tang, W.; Huang, J. Y.; Braunecker, W. A.; Tsarevsky, N. V. Proc. Natl. Acad. Sci. U. S. A. 2006, 103, 15309
16. Matyjaszewski, K.; Jakubowski, W. Macromolecules 2005, 38, 4139
17. Percec, V.; Guliashvili, T.; Ladislaw, J. S.; Wistrand, A.; Stjerndahl, A.; Sienkowska, M. J.; Monteiro, M. J.; Sahoo, S. J. Am. Chem. Soc. 2006, 128, 14156
18. Percec, V.; Rosen, B. M. Chem. Rev. 2009, 109, 5069
19. Monteiro, M. J.; Guliashvili, T.; Percec, V. J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 1835
20. Percec, V.; Fleischmann, S.; Rosen, B. M. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 1190
21. Percec, V.; Jiang, X.; Rosen, B. M. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 403
22. Percec, V.; Fleischmann, S. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 2236
23. Percec, V.; Fleischmann, S. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 2243
24. Percec, V.; Nguyen, N. H.; Rosen, B. M. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 1752
25. Percec, V.; Hatano, T.; Rosen, B. M. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 164
26. Matyjaszewski, K.; Coca, S.; Gaynor, S. G.; Wei, M. L.; Woodworth, B. E. Macromolecules 1997, 30, 7348
27. Percec, V.; Barboiu, B.; van der Sluis, M. Macromolecules 1998, 31, 4053
28. Otsu, T.; Yamaguch., M.; Takemura, Y.; Kusuki, Y.; Aoki, S. J. Polym. Sci., Part C: Polym. Lett. 1967, 5, 697
29. Percec, V.; Grigoras, C. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 5609
30. Lligadas, G.; Percec, V. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 2745
31. Percec, V.; Nguyen, N. H.; Rosen, B. M.; Jiang, X.; Fleischmann, S. J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 5577
32. Percec, V.; Popov, A. V.; Ramirez-Castillo, E.; Monteiro, M.; Barboiu, B.; Weichold, O.; Asandei, A. D.; Mitchell, C. M. J. Am. Chem. Soc. 2002, 124, 4940
33. Lligadas, G.; Percec, V. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 6880
34. Percec, V.; Nguyen, N. H. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 5109
35. Nguyen, N. H.; Percec, V. J. Polym. Sci., Part A: Polym. Chem. 2011, 49, 4241
36. Monge, S.; Darcos, V.; Haddleton, D. M. J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 6299
37. Perrier, S.; Haddleton, D. M. Macromol. Symp. 2000, 182, 271
38. Perrier, S.; Armes, S. P.; Wang, X. S.; Malet, F.; Haddleton, D. M. J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 1696
39. Lligadas, G.; Rosen, B. M.; Bell, C. A.; Monteiro, M. J.; Percec, V. Macromolecules 2008, 41, 8365
40. Nguyen, N. H.; Rosen, B. M.; Lligadas, G.; Percec, V. Macromolecules 2009, 42, 2379
41. Matyjaszewski, K.; Tsarevsky, N. V.; Braunecker, W. A.; Dong, H.; Huang, J.; Jakubowski, W.; Kwak, Y.; Nicolay, R.; Tang, W.; Yoon, J. A. Macromolecules 2007, 40, 7795
42. Tom, J.; Hornby, B.; West, A.; Harrisson, S.; Perrier, S. Polym. Chem. 2010, 1, 420
43. Hornby, B. D.; West, A. G.; Tom, J. C.; Waterson, C.; Harrisson, S.; Perrier, S. Macromol. Rapid Commun. 2010, 31, 1276
44. Wright, P. M.; Mantovani, G.; Haddleton, D. M. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 7376
45. Nguyen, N. H.; Percec, V. J. Polym. Sci., Part A: Polym. Chem. 2011, 49, 4227
46. Lligadas, G.; Rosen, B. M.; Monteiro, M. J.; Percec, V. Macromolecules 2008, 41, 8360
47. Buback, M.; Kurz, C. H.; Schmaltz, C. Macromol. Chem. Phys. 1998, 199, 1721
48. Buback, M.; Kuelpmann, A.; Kurz, C. Macromol. Chem. Phys. 2002, 203, 1065
49. Bencherif, S. A.; Srinivasan, A.; Horkay, F.; Hollinger, J. O.; Matyjaszewski, K.; Washburn, N. R. Biomaterials 2008, 29, 1739
50. Tang, W.; Matyjaszewski, K. Macromolecules 2007, 40, 1858
51. Harrisson, S.; Couvreur, P.; Nicolas, J. Polym. Chem. 2011, 2, 1859
52. Matyjaszewski, K.; Woodworth, B. E.; Zhang, X.; Gaynor, S. G.; Metzner, Z. Macromolecules 1998, 31, 5955
53. Benoit, D.; Grimaldi, S.; Robin, S.; Finet, J. P.; Tordo, P.; Gnanou, Y. J. Am. Chem. Soc. 2000, 122, 5929
54. Hawker, C. J.; Bosman, A. W.; Harth, E. Chem. Rev. 2001, 101, 3661
55. Moad, G.; Rizzardo, E.; Solomon, D. H. Polym. Bull. 1982, 6, 589
56. Britovsek, G. J. P.; England, J.; White, A. J. P. Inorg. Chem. 2005, 44, 8125