Investigation of the oxygen exchange mechanism on Ptyttria stabilized zirconia at intermediate temperatures: Surface path versus bulk path

Electrochimica Acta

Volumn 56, Issue 27, 2011, Pages 9727-9740

  Opitz, Alexander K ^a   Lutz, Alexander ^a   Kubicek, Markus ^a   Kubel, Frank ^a   Hutter, Herbert ^a   Fleig, Jürgen ^a  

^a VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

Impedance spectroscopy; Microelectrodes; Oxygen reduction; Platinum electrodes; Triple phase boundary

Indexed keywords

CO-LIMITATION; DECAY LENGTH; DIFFERENT GEOMETRY; ELECTROCHEMICAL OXYGEN; ELECTRODE AREAS; ELECTRODE SIZE; ELEMENTARY STEPS; HIGHER TEMPERATURES; IMPEDANCE SPECTROSCOPY; IMPURITY PHASE; INTERMEDIATE TEMPERATURES; LOW-ACTIVATION ENERGY; OXYGEN DIFFUSION; OXYGEN EXCHANGE; OXYGEN REDUCTION; PARALLEL PATHWAYS; PLATINUM ELECTRODES; POLARIZATION RESISTANCES; RATE LIMITING; RATE-LIMITING REACTION; STABILIZED ZIRCONIA; THREE-PHASE BOUNDARY; TRANSMISSION LINE; TRIPLE PHASE BOUNDARY; TWO-TEMPERATURE;

ACTIVATION ENERGY; CHARGE TRANSFER; DIFFUSION IN GASES; ELECTROLYTIC REDUCTION; EQUIVALENT CIRCUITS; GRAIN BOUNDARIES; ION EXCHANGE; MICROELECTRODES; PLATINUM; YTTRIA STABILIZED ZIRCONIA; ZIRCONIA;

OXYGEN;

EID: 80054936449     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2011.07.112     Document Type: Article

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