The Y-Procedure methodology for the interpretation of transient kinetic data: Analysis of irreversible adsorption

Chemical Engineering Science

Volumn 66, Issue 24, 2011, Pages 6441-6452

  Redekop, Evgeniy A ^a   Yablonsky, Gregory S ^b   Constales, Denis ^c   Ramachandran, Palghat A ^a   Pherigo, Cathryn ^d   Gleaves, John T ^a  

^a WASHINGTON UNIVERSITY IN ST LOUIS   (United States)

^b Saint Louis University   (United States)

^c GHENT UNIVERSITY   (Belgium)

^d Francis Howell North High School   (United States)

Author keywords

Heterogeneous catalysis; Irreversible adsorption; Temporal analysis of products (TAP); Thin zone; Transient kinetics; Y Procedure

Indexed keywords

IRREVERSIBLE ADSORPTION; TEMPORAL ANALYSIS OF PRODUCT; THIN-ZONE; TRANSIENT KINETICS; Y-PROCEDURE;

CATALYSIS; KINETICS; PLATINUM; REACTION RATES;

GAS ADSORPTION;

EID: 80054934886     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2011.08.055     Document Type: Article

References (38)

1. Benesi H.A., Atkins L.T., Mosely R.B. Rapid measurement of hydrogen chemisorption by supported catalytic metals. J. Catal. 1971, 23:211-213.
2. Bennett C.O., Gates B.C., Haag H.K.W.O. Experiments and processes in the transient regime for heterogeneous catalysis. Adv. Catal. 1999, 44:329-416.
3. Berger R.J., Kapteijn F., Moulijn J.A., Marin G.B., Wilde J.D., Olea M., Chen D., Holmen A., Lietti L., Tronconi E., Schuurman Y. Dynamic methods for catalytic kinetics. Appl. Catal. A: Gen. 2008, 342:3-28.
4. Biegler L.T., Damiano J.J., Blau G.E. Nonlinear parameter estimation: a case study comparison. AIChE J. 1986, 32:29-45.
5. Bond G.C. The use of kinetics in evaluating mechanisms in heterogeneous catalysis. Catal. Rev.: Sci. Eng. 2008, 50:532.
6. Chorkendorff I., Niemantsverdriet J.W. Concepts of Modern Catalysis and Kinetics 2007, Wiley-VCH, (2nd revised and enlarged edition).
7. Constales D., Yablonsky G., Marin G., Gleaves J. Multi-zone TAP-reactors theory and application: I. The global transfer matrix equation. Chem. Eng. Sci. 2001, 56:133-149.
8. Dumesic J.A., Rudd D.F., Aparicio L.M., Rekoske J.E., Treviño A.A. The Microkinetics of Heterogeneous Catalysis 1993, An American Chemical Society Publication. first ed.
9. Elokhin V.I., Matveev A.V., Kovalyov E.V., Gorodetskii V.V. From single crystals to supported nanoparticles in oscillatory behavior of CO + O2 reaction on platinum and palladium surfaces: experiment and stochastic models. Chem. Eng. J. 2009, 154:94-106.
10. Gee A.T., Hayden B.E. The dynamics of O2 adsorption on Pt(533): step mediated molecular chemisorption and dissociation. J. Chem. Phys. 2000, 113:10333.
11. Gleaves J.T., Ebner J.R., Kuechler T.C. Temporal analysis of products (TAP)A unique catalyst evaluation system with submillisecond time resolution. Catal. Rev.: Sci. Eng. 1988, 30:49.
12. Gleaves J.T., Yablonskii G.S., Phanawadee P., Schuurman Y. TAP-2: an interrogative kinetics approach. Appl. Catal. A: Gen. 1997, 160:55-88.
13. Gleaves J.T., Yablonsky G., Zheng X., Fushimi R., Mills P.L. Temporal analysis of products (TAP)-recent advances in technology for kinetic analysis of multi-component catalysts. J. Mol. Catal. A: Chem. 2010, 315:108-134.
14. Hoebink J., Huinink J., Marin G. A quantitative analysis of transient kinetic experiments: the oxidation of CO by O2 over Pt. Appl. Catal. A: Gen. 1997, 160:139-151.
15. Jones, E., Oliphant, T., Peterson, P., et al., 2001-2011. SciPy: open source scientific tools for Python, http://www.scipy.org/Citing_SciPy.
16. Kim M.H., Ebner J.R., Friedman R.M., Vannice M.A. Determination of metal dispersion and surface composition in supported Cu-Pt catalysts. J. Catal. 2002, 208:381-392.
17. Kondratenko E.V., Pérez-Ramírez J. Mechanism and kinetics of direct N2O decomposition over FeMFI zeolites with different iron speciation from temporal analysis of products. J. Phys. Chem. B 2006, 110:22586-22595.
18. Moulijn J., Tarfaoui A., Kapteijn F. General aspects of catalyst testing. Catal. Today 1991, 11:1-12.
19. Nijhuis T., Makkee M., van Langeveld A., Moulijn J. New insight in the platinum-catalyzed CO oxidation kinetic mechanism by using an advanced TAP reactor system. Appl. Catal. A: Gen. 1997, 164:237-249.
20. Phanawadee P., Shekhtman S.O., Jarungmanorom C., Yablonsky G.S., Gleaves J.T. Uniformity in a thin-zone multi-pulse TAP experiment: numerical analysis. Chem. Eng. Sci. 2003, 58:2215-2227.
21. Prasad V., Karim A.M., Arya A., Vlachos D.G. Assessment of overall rate expressions and multiscale, microkinetic model uniqueness via experimental data injection: ammonia decomposition on Ru/-Al2O3 for hydrogen production. Ind. Eng. Chem. Res. 2009, 48:5255-5265.
22. Ribeiro F.H., Wittenau A.E.S.V., Bartholomew C.H., Somorjai G.A. Reproducibility of turnover rates in heterogeneous metal catalysis: compilation of data and guidelines for data analysis. Catal. Rev.: Sci. Eng. 1997, 39:49.
23. Rissmann E.F., Parry J.M. Low temperature chemisorption of molecular nitrogen on platinum. J. Phys. Chem. 1975, 79:1975-1978.
24. Roelant R., Constales D., Yablonsky G.S., Keer R.V., Rude M.A., Marin G.B. Noise in temporal analysis of products (TAP) pulse responses. Catal. Today 2007, 121:269-281.
25. Shekhtman S., Goguet A., Burch R., Hardacre C., Maguire N. CO multipulse TAP studies of 2% Pt/CeO2 catalyst: influence of catalyst pretreatment and temperature on the number of active sites observed. J. Catal. 2008, 253:303-311.
26. Shekhtman S.O., Yablonsky G.S. Thin-Zone TAP reactor versus differential PFR: analysis of concentration nonuniformity for Gas-solid systems. Ind. Eng. Chem. Res. 2005, 44:6518-6522.
27. Shekhtman S.O., Yablonsky G.S., Gleaves J.T., Fushimi R. "State defining" experiment in chemical kinetics-primary characterization of catalyst activity in a TAP experiment. Chem. Eng. Sci. 2003, 58:4843-4859.
28. Shekhtman S.O., Yablonsky G.S., Gleaves J.T., Fushimi R.R. Thin-zone TAP reactor as a basis of "state-by-state transient screening". Chem. Eng. Sci. 2004, 59:5493-5500.
29. Strohmayer D.E., Geoffroy G.L., Vannice M.A. Measurement of silver surface area by the H2 titration of chemisorbed oxygen. Appl. Catal. 1983, 7:189-198.
30. van der Linde S.C., Nijhuis T., Dekker F., Kapteijn F., Moulijn J.A. Mathematical treatment of transient kinetic data: combination of parameter estimation with solving the related partial differential equations. Appl. Catal. A: Gen. 1997, 151:27-57.
31. Verdasca J., Borckmans P., Dewel G. A generalized reaction-diffusion model to describe spatio-temporal patterns in the catalytic CO oxidation on Pt (110). Phys. Chem. Chem. Phys. 2002, 4:1355-1366.
32. Widmann D., Liu Y., Schüth F., Behm R. Support effects in the Au-catalyzed CO oxidation-correlation between activity, oxygen storage capacity, and support reducibility. J. Catal. 2010, 276:292-305.
33. Yablonskii, 1991. Kinetic models of catalytic reactions. Compr. Chem. Kinet. 32.
34. Yablonsky G., Constales D., Shekhtman S., Gleaves J. The y-procedure: how to extract the chemical transformation rate from reaction-diffusion data with no assumption on the kinetic model. Chem. Eng. Sci. 2007, 62:6754-6767.
35. Yang Z., Wang J., Yu X. Density functional theory studies on the adsorption, diffusion and dissociation of O2 on Pt(111). Phys. Lett. A 2010, 374:4713-4717.
36. Zaera F. Kinetics of chemical reactions on solid surfaces: deviations from conventional theory. Acc. Chem. Res. 2002, 35:129-136.
37. Zambelli T., Barth J.V., Wintterlin J., Ertl G. Complex pathways in dissociative adsorption of oxygen on platinum. Nature 1997, 390:495-497.
38. Zheng X., Veith G.M., Redekop E., Lo C.S., Yablonsky G.S., Gleaves J.T. Oxygen and CO adsorption on Au/SiO2 catalysts prepared by magnetron sputtering: the role of oxygen storage. Ind. Eng. Chem. Res. 2010, 49:10428-10437.