Thin-zone TAP reactor versus differential PFR: Analysis of concentration nonuniformity for gas-solid systems

Industrial and Engineering Chemistry Research

Volumn 44, Issue 16, 2005, Pages 6518-6522

  Shekhtman, Sergiy O ^a   Yablonsky, Gregory S ^b  

^a QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

^b WASHINGTON UNIVERSITY IN ST LOUIS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CONVECTIONAL TRANSPORT; DIFFUSIONAL TRANSPORT; THIN-ZONE TAP REACTOR (TZTR);

CATALYSTS; DIFFUSION; TRANSPORT PROPERTIES;

CHEMICAL REACTORS;

GAS-SOLID MIXING;

EID: 23944487157     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie050554g     Document Type: Article

References (17)

1. Temkin, M. I.; Kiperman, S. L.; Luk'anova, L. I. Dokl. Akad. Nauk SSSR 1950, 74, 363-368.
2. Temkin, M. I. Kinetics of some industrial heterogeneous catalytic reactions. Adv. Catal. 1979, 28, 173-291.
3. Dautzenberg, F. M. Ten guidelines for catalyst testing. In Characterization and Catalyst Development; Bradley, S. A., Galhuso, M. J., Bertolacini, R. J., Eds.; ACS Symposium Series 411; American Chemical Society, Washington, DC, 1989.
4. Kobayashi, H.; Kobayashi, M. Transient response method in heterogeneous catalysis. Catal. Rev.-Sci. Eng. 1974, 10 (2), 139-176.
5. Bennett, C. O. Experiments and processes in the transient regime for heterogeneous catalysis. Adv. Catal. 1999, 44, 329-416.
6. Shekhtman, S. O.; Yablonsky, G. S.; Gleaves, J. T.; Chen, S. Thin-zone TAP-reactor: theory and application. Chem. Eng. Sci. 1999, 54, 4371-4378.
7. Phanawadee, P.; Shekhtman, S. O.; Jarungmanorom, C.; Yablonsky, G. S.; Gleaves, J. T. Uniformity in a thin-zone multipulse TAP experiment: numerical analysis. Chem. Eng. Sci. 2003, 58, 2215-2227.
8. Shekhtman, S. O.; Yablonsky, G. S.; Gleaves, J. T.; Fushimi, R. Thin-zone TAP reactor as a basis of "state-by-state transient screening". Chem. Eng. Sci. 2004, 59, 5493-5500.
9. Yablonsky, G. S.; Olea, M.; Marin, G. B. Temporal analysis of products (TAP): basic principles, applications and theory. J. Catal. 2003, 216, 120-134.
10. Bhattachacharya, M.; Harold, M.; Balakotajah, V. Low-dimensional models for homogeneous stirred tank reactor. Chem. Eng. Sci. 2004, 59, 5587-5596.
11. Bennett, C. O. A dynamic method for the study of heterogeneous catalytic kinetics. AIChE J. 1967, 13, 890-895.
12. Eigen, M. Technique of Organic Chemistry; Weissberger, A., Ed.; Interscience: New York, 1963; Vol. 8, Pt. II.
13. Borman, P. C.; Bos, A. N. R.; Westerterp, K. R. A novel reactor for determination of kinetics for solid gas reactions. AIChE J. 1994, 40, 5, 862-869.
14. Froment, G. F.; Bischoff, K. B. Chemical Reactor Analysis and Design, 2nd ed.; John Wiley & Sons: New York, 1990; 86 pp.
15. Gleaves, J. T.; Ebner, J. R.; Kuechler, T. C. Temporal analysis of products (TAP) - a unique catalyst evaluation system with submillisecond time resolution. Catal. Rev.-Sci. Eng. 1988, 30, 49-116.
16. Gleaves, J. T.; Yablonskii, G. S.; Phanawadee, Ph.; Schuurman, Y. TAP-2: an interrogative kinetics approach. Appl. Catal., A 1997, 160, 55-87.
17. Shekhtman, S. O.; Yablonsky, G. S.; Gleaves, J. T.; Fushimi, R. "State defining" experiment in chemical kinetics-primary characterization of catalyst activity in a TAP experiment. Chem. Eng. Sci. 2003, 58, 4843-4859.