Research progress in LiBH4 for hydrogen storage: A review

International Journal of Hydrogen Energy

Volumn 36, Issue 22, 2011, Pages 14512-14526

  Li, C ^a   Peng, P ^a   Zhou, D W ^a   Wan, L ^a  

^a HUNAN UNIVERSITY   (China)

Author keywords

Complex hydrides; Hydrogen storage materials; LiBH4; Review

Indexed keywords

COMPLEX HYDRIDES; DIRECT SYNTHESIS; ENERGY CARRIERS; FAST-ION CONDUCTORS; HIGH TEMPERATURE; HYDROGEN CAPACITIES; HYDROGEN DESORPTION; HYDROGEN GAS; HYDROGEN STORAGE MATERIALS; HYDROGEN STORAGE TECHNOLOGIES; INTERMEDIATE COMPOUND; LIBH4; LITHIUM BOROHYDRIDE; RESEARCH PROGRESS; STATIONARY APPLICATIONS;

DESORPTION; HYDROGEN; HYDROLYSIS; INDUSTRIAL APPLICATIONS; LITHIUM; REACTION INTERMEDIATES; STORAGE (MATERIALS); SYNTHESIS (CHEMICAL);

HYDROGEN STORAGE;

EID: 80054035523     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.08.030     Document Type: Review

References (232)

1. L. Schlapbach, and A. Züttel Hydrogen storage materials for mobile applications Nature 414 2001 353 358 (Pubitemid 33097818)
2. DOE targets for onboard Hydrogen storage systems for light-duty vehicles: current R&D focus is on 2015 targets with potential to meet ultimate targets. http://www1.eere.energy.gov/hydrogenandfuelcells/storage/pdfs/targets- onboard-hydro-storage.pdf.
3. S.I. Orimo, Y. Nakamori, J.R. Eliseo, A. Züttel, and C.M. Jensen Complex hydrides for hydrogen storage Chem Rev 107 2007 4111 4132 (Pubitemid 350054218)
4. A. Züttel, A. Borgschulte, and S.I. Orimo Tetrahydroborates as new hydrogen storage materials Scripta Mater 56 2007 823 828 (Pubitemid 46371490)
5. B. Sakintuna, F. Lamari-Darkrim, and M. Hirscher Metal hydride materials for solid hydrogen storage: a review Int J Hydrogen Energ 32 2007 1121 1140 (Pubitemid 46777202)
6. L. George, and S.K. Saxena Structural stability of metal hydrides, alanates and borohydrides of alkali and alkali-earth elements: a review Int J Hydrogen Energ 35 2010 5454 5470
7. I.P. Jain, P. Jain, and A. Jain Novel hydrogen storage materials: a review of lightweight complex hydrides J Alloy Comp 503 2010 303 339
8. H.I. Schlesinger, and H.C. Brown Metallo borohydrides. III. Lithium borohydride J Am Chem Soc 62 1940 3429 3435
9. 4 J Alloy Comp 356-357 2003 515 520
10. H.I. Schlesinger, H.C. Brown, H.R. Hoekstra, and L.R. Rapp Reactions of diborane with alkali metal hydrides and their addition compounds. new syntheses of borohydrides. sodium and potassium borohydrides1 J Am Chem Soc 75 1953 199 204
11. 4 by gas-solid reaction Chem Eur J 15 2009 5531 5534
12. H.C. Brown, Y.M. Choi, and S. Narasimhan Convenient procedure for the conversion of sodium borohydride into lithium borohydride in simple ether solvents Inorg Chem 20 1981 4454 4456
13. H.I. Schlesinger, H.C. Brown, B. Abraham, A.C. Bond, N. Davidson, and A.E. Finholt New developments in the chemistry of diborane and the borohydrides. I. general summary J Am Chem Soc 75 1953 186 190
14. 4] from the elements Acta Mater 56 2008 949 954
15. 4 J Phys Chem B 110 2008 906 910 (Pubitemid 351212531)
16. 4 from its elements by ball milling method Renew Energ 33 2008 2388 2392
17. 4 observed by in situ neutron diffraction Phys Chem Chem Phys 10 2008 5859 5862
18. 2 adsorption on LiB (0 1 0) surface Phys B Condens Matter 405 2010 1792 1795
19. E. Fakiolu, Y. Yürüma, and T.N. Vezirolu A review of hydrogen storage systems based on boron and its compounds Int J Hydrogen Energ 29 2004 1371 1376
20. R. Aiello, J.H. Sharp, and M.A. Matthews Production of hydrogen from chemical hydrides via hydrolysis with steam Int J Hydrogen Energ 24 1999 1123 1130 (Pubitemid 30509355)
21. R. Aiello, M.A. Matthews, D.L. Reger, and J.E. Collins Production of hydrogen gas from novel chemical hydrides Int J Hydrogen Energ 23 1998 1103 1108 (Pubitemid 128411203)
22. V.C.Y. Kong, F.R. Foulkes, D.W. Kirk, and J.T. Hinatsu Development of hydrogen storage for fuel cellgenerators. I: hydrogen generation using hydrolysishydrides Int J Hydrogen Energ 24 1999 665 675
23. 3 mixture for fuel cell applications Int J Hydrogen Energy 36 17 2011 10870 10876
24. J.E. Stearns, M.A. Matthews, D.L. Reger, and J.E. Collins The thermal characterization of novel complex hydrides Int J Hydrogen Energ 23 1998 469 474 (Pubitemid 128390276)
25. H.I. Schlesinger, H.C. Brown, A.E. Finholt, J.R. Gilbreath, H.R. Hoekstra, and E.K. Hyde Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen1 J Am Chem Soc 75 1953 215 219
26. Y. Kojima, Y. Kawai, M. Kimbara, H. Nakanishi, and S. Matsumoto Hydrogen generation by hydrolysis reaction of lithium borohydride Int J Hydrogen Energ 29 2004 1213 1217
27. 4 J Therm Anal Calorim 94 2008 785 790
28. J.P. Goudon, F. Bernard, J. Renouard, and P. Yvart Experimental investigation on lithiumborohydride hydrolysis Int J Hydrogen Energ 35 2010 11071 11076
29. L. Zhu, D. Kim, H. Kim, R.I. Masel, and M.A. Shannon Hydrogen generation from hydrides in millimeter scale reactors for micro proton exchange membrane fuel cell applications J Power Sourc 185 2008 1334 1339
30. 4 doped with multiwalled carbon nanotubes for micro proton exchange membrane fuel cell application J Power Sourc 196 2011 5095 5101
31. 2 J Power Sourc 155 2006 325 328
32. 2 mixture Corros Sci 53 2011 1115 1119
33. 4 on the hydrogen desorption mechanism Phys Chem Chem Phys 12 2010 10950 10955
34. 4 J Am Chem Soc 69 1947 1231 1232
35. 4: I Crystal Structure J Alloy Comp 346 2002 200 205
36. 4 Phys Rev B 69 2004 245120
37. 4 revisited Phys Rev Lett 93 2004 145501
38. 4 Chem Phys Lett 405 2005 73 78
39. 4 (A = Li, Na, K, Rb, Cs) from first principle calculation J Alloy Comp 387 2005 97 104
40. M.R. Hartman, J.J. Rush, T.J. Udovic Jr., R.C. Bowman, and S.-J. Hwang Structure and vibrational dynamics of isotopically labeled lithium borohydride using neutron diffraction and spectroscopy J Solid State Chem 180 2007 1298 1305 (Pubitemid 46627725)
41. Y. Filinchuk, D. Chernyshov, and R. Cerny Lightest borohydride probed by synchrotron X-ray diffraction: experiment calls for a new theoretical revision J Phys Chem C 112 2008 10579 10584
42. 4 Angew Chem Int Ed 47 2008 529 532 (Pubitemid 351412335)
43. 4 Phys Rev Lett 104 2010 215501
44. 4 from maximum entropy method Phys Rev B 83 2011 064107
45. D.B. Ravnsbæk, Y. Filinchuk, R. Cerný, and T.R. Jensen Powder diffraction methods for studies of borohydride-based energy storage materials Z Kristallogr 225 2010 557 569
46. H. Takamura, Y. Kuronuma, H. Maekawa, M. Matsuo, and S. Orimo Lithium ion conduction in lithium borohydrides under high pressure Solid State Ionics 2010 10.1016/j.ssi.2010.02.011
47. B. Sundqvist, and O. Andersson Thermal conductivity and phase diagrams of some potential hydrogen storage materials under pressure Int J Thermophys 30 2009 1118 1129
48. 4 J Solid State Chem 180 2007 510 517 (Pubitemid 46185414)
49. Pistorius CWFT Z Phys Chem Neue Folge 88 1974 253
50. 4: synchrotron x-ray diffraction experiments and theoretical analysis Phys Rev B 77 2008 174112
51. 2 in hydrogen diffusion in light metal borohydrides Phys Chem Chem Phys 11 2009 11106 11109
52. 4 J Phys Chem C 113 2009 5039 5042
53. 4 (M = Li, Na, K) from quasielastic neutron scattering and density functional calculations Phye Rev B 81 2010 214304
54. 4]- anion structure J Mol Struc Theochem 908 2009 114 116
55. 4) Appl Phys Lett 94 2009 141903
56. 4 from low-temperature Raman-scattering measurements and first-principles calculations Phys Rev B 80 2009 100301(R)
57. 4 J Phys Chem A 112 2008 4749 4753
58. 4 Phys Rev B 78 2008 094302
59. 4 and its decomposition products Phys Rev B 73 2006 174302
60. 4 by infrared pump-probe and 2D spectroscopy J Phys Chem A 113 2009 12838 12846
61. 4 by NMR J Phys Chem C 112 2008 18706 18710
62. 4 J Phys Condens Matter 20 2008 465210
63. 4: an insight from Raman and X-ray diffraction experiments Phase Trans 80 2009 344 355
64. Z. Łodziana, and M.J.V. Setten Binding in alkali and alkaline-earth tetrahydroborates: special position of magnesium tetrahydroborate Phys Rev B 81 2010 024117
65. 4: II Raman Spectroscopy J Alloy Comp 346 2002 206 210
66. 4 J Phys Chem C 112 2008 18701 18705
67. - anionsin alkali borohydrides J Alloy Comp 363 2004 126 129
68. 4 J Phys Chem A 112 2008 9716 9722
69. T. Tsang, and T.C. Farrar Nuclear magnetic relaxation studies of internal rotations and phase transitions in borohydrides of lithium, sodium, and potassium J Chem Phys 50 1989 3498 3502
70. M. Matsuo, Y. Nakamori, S.I. Orimo, H. Maekawa, and H. Takamura Lithium superionic conduction in lithium borohydride accompanied by structural transition Appl Phys Lett 91 2007 224103
71. 4 complex anions for hydrogen storage applications: ab initio density functional calculations Phys Rev B 74 2006 193405
72. J.C. Galvez-Ruiz, and M. Sanchez Towards understanding structure bonding lithium tetrahydroborate its amine complexes J Mol Struc Theochem 818 2007 23 30
73. 4 J Solid State Chem 182 2009 2357 2361
74. 4 J Phys Chem A 114 2010 10117 10121
75. 4-LiI induced by anion exchange and temperature Appl Phys Lett 97 2010 031916
76. K.B. Harvey, and N.R. McQuaker Low temperature Infrared and Raman spectra of lithium borohydride Can J Chem 49 1971 3282 3286
77. 4 measured by spatially resolved Raman spectroscopy Phys Chem Chem Phys 12 2010 5061 5066
78. A. Remhof, R. Gremaud, F. Buchter, Z. Lodziana, J.P. Embs, and T.A.J. Ramirez-Cuesta Hydrogen dynamics in lightweight tetrahydroborates Z Phys Chem 224 2010 263 278
79. 4 due to reduced dimensionality: frequency-dependent NMR spectroscopy Phys Rev B 82 2010 020301(R)
80. 4, a room-temperature lithium fast-ion conductor J Am Chem Soc 131 2009 894 895
81. 4 by LiCl addition Appl Phys Lett 94 2009 084103
82. 4-LiI pseudobinary system Appl Phys Lett 94 2009 141912
83. 4 Solid State Ionics 2010 10.1016/j.ssi.2010.05.017
84. 4 by anion substitution Solid State Ionics 2010 306 311
85. M. Matsuo, and S.I. Orimo Lithium fast-ionic conduction in complex hydrides: review andprospects Adv Energy Mater 1 2011 161 172
86. - anions as new lithium fast-ion conductors J Am Chem Soc 131 2009 16389 16391
87. 4 a new hydrogen storage material J Power Sourc 118 2003 1 7 (Pubitemid 41325593)
88. 4 J Alloy Comp 446-447 2007 301 305 (Pubitemid 47539067)
89. M. Au, and R.T. Walters Reversibility aspect of lithium borohydrides Int J Hydrogen Energ 35 2010 10311 10316
90. H.W. Li, Y. Yan, S.I. Orimo, A. Züttel, and C.M. Jensen Recent progress in metal borohydrides for hydrogen storage Energies 4 2011 185 214
91. 4 Phys Rev B 74 2006 075110
92. 4 Appl Phys Lett 89 2006 021920
93. 2- complexes during hydrogen desorption from metal borohydrides J Phys Chem C 112 2008 3164 3169 (Pubitemid 351488297)
94. 4 Chem Mater 22 2010 3265 3268
95. O. Friedrichs, A. Remhof, A. Borgschulte, F. Buchter, S.I. Orimo, and A. Züttel Breaking the passivation-the road to a solvent free borohydride synthesis Phys Chem Chem Phys 12 2010 10919 10922
96. 2O Inorg Chim Acta 362 2009 3155 3158
97. V. Ozolins, E.H. Majzoub, and C. Wolverton First-principles prediction of thermodynamicallyreversible hydrogen storage reactions in the Li-Mg-Ca-B-H System J Am Chem Soc 131 2009 230 237
98. N. Verdal, W. Zhou, V. Stavila, J.H. Her, M. Yousufuddin, and T. Yildirim Alkali and alkaline-earth metal dodecahydro-closo-dodecaborates: probing structural variations via neutron vibrational spectroscopy J Alloy Comp 2010 10.1016/j.jallcom.2010.08.024
99. 4 Inorg Chem 47 2008 9757 9759
100. 4 J Alloy Comp 404-406 2005 427 430 (Pubitemid 41688671)
101. 2 system J Phys Chem C 114 2010 8089 8098
102. 4/SBA-15 Nanocomposites prepared by melt infiltration under hydrogen pressure: synthesis and hydrogen sorption properties J Phys Chem C 114 2010 6163 6168
103. H.W. Li, S.I. Orimo, Y. Nakamori, K. Miwa, N. Ohba, and S. Towata Materials designing of metal borohydrides: viewpoints from thermodynamical stabilities J Alloy Comp 446-447 2007 315 318 (Pubitemid 47539060)
104. Y. Nakamori, K. Miwa, A. Ninomiya, H. Li, N. Ohba, and S.I. Towata Correlation between thermodynamical stabilities of metal borohydrides and cation electronegativites: first-principles calculations and experiments Phys Rev B 74 2006 045126
105. E.A. Nickels, M.O. Jones, W.I.F. David, S.R. Johnson, R.L. Lowton, and M. Sommariva Tuning the decomposition temperature in complex hydrides: synthesis of a mixed alkali metal borohydride Angew Chem Int Ed 47 2008 2817 2819
106. 4 from first-principles calculations J Phys Chem C 114 2010 678 686
107. 13: a complex double-cation borohydride with a new structure Chem Eur J 16 2010 8707 8712
108. 4) 4 - complex anions J Phys Chem A 112 2008 7551 7555
109. 4 as a hydrogen storage material: multinuclear high-resolution solid-state NMR and first-principles density functional theory studies J Phys Chem C 113 2009 9956 9968
110. D. Ravnsbæk, Y. Filinchuk, Y. Cerenius, H.J. Jakobsen, F. Besenbacher, and J. Skibsted A series of mixed-metal borohydrides Angew Chem Int Ed 48 2009 6659 6663
111. P. Choudhury, S.S. Srinivasan, V.R. Bhethanabotla, Y. Goswami, K. McGrath, and E.K. Stefanakos Nano-Ni doped Li-Mn-B-H system as a new hydrogen storage candidate Int J Hydrogen Energ 34 2009 6325 6334
112. 4 J Alloy Comp 404-406 2005 140 143 (Pubitemid 41688633)
113. 2 mixture associated with the in situ formation of dual-cation borohydride J Alloy Comp 491 2010 L1 L4
114. 2 composite J Phys Chem C 113 2009 15080 15086
115. D.B. Ravnsbæk, C. Frommen, D. Reed, Y. Filinchuk, M. Sørby, and B.C. Hauback Structural studies of lithium zinc borohydride by neutron powder diffraction, Raman and NMR spectroscopy J Alloy Comp 2011 10.1016/j.jallcom.2010.11.008
116. L.H. Rude, T.K. Nielsen, D.B. Ravnsbæk, U. Bösenberg, M.B. Ley, and B. Richter Tailoring properties of borohydrides for hydrogen storage: a review Phys Status Solidi A 2011 10.1002/pssa.201001214
117. T.J. Marks, and J.R. Kolb Covalent transition metal, lanthanide, and actinide tetrahydroborate complexes Chem Rev 77 1977 263 293
118. 3 (R=Y, Dy, and Gd) Phys Rev B 77 2008 104114
119. D.J. Siegel, C. Wolverton, and V. Ozoli Thermodynamic guidelines for the prediction of hydrogen storage reactions and their application to destabilized hydride mixtures Phys Rev B 76 2007 134102
120. 2) J Phys Chem C 111 2007 19134 19140
121. S.V. Alapati, J.K. Johnson, and D.S. Sholl Identification of destabilized metal hydrides for hydrogen storage using first principles calculations J Phys Chem B 110 2006 8769 8776 (Pubitemid 43798583)
122. Y.W. Cho, J.-H. Shim, and B.-J. Lee Thermal destabilization of binary and complex metal hydrides by chemical reaction: a thermodynamic analysis Calphad 30 2006 65 69 (Pubitemid 43172007)
123. 4 J Phys Chem B 109 2005 3719 3722
124. J.J. Vajo, and G.L. Olson Hydrogen storage in destabilized chemical systems Scripta Mater 56 2007 829 834 (Pubitemid 46367737)
125. J.J. Vajo, T.T. Salguero, A.F. Gross, S.L. Skeith, and G.L. Olson Thermodynamic destabilization and reaction kinetics in light metal hydride systems J Alloy Comp 446-447 2007 409 414 (Pubitemid 47539050)
126. 4 composites Acta Mater 55 2007 3951 3958 (Pubitemid 46755696)
127. 2 composite system J Phys Chem C 114 2010 15212 15217
128. 2 J Power Sourc 194 2009 1128 1134
129. X.B. Yu, D.M. Grant, and G.S. Walker A new dehydrogenation mechanism for reversible multicomponent borohydride systems - The role of Li-Mg alloys Chem Commun 37 2006 3906 3908 (Pubitemid 44424677)
130. 2 multicomponent systems investigated by in situ neutron diffraction J Alloy Comp 472 2009 559 564
131. 2 multi-component hydrogen storage system - The effects of stoichiometry and decomposition environment on cycling behaviour Int J Hydrogen Energ 35 2010 4154 4161
132. 2 System J Phys Chem C 112 2008 18232 18243
133. 2: a new route to superior hydrogen storage materials Chem Commun 22 2005 2823 2825 (Pubitemid 40904166)
134. 4 catalyzed magnesium J Phys Chem C 111 2007 12495 12498 (Pubitemid 47387811)
135. 4 destabilized by milling with Al Appl Phys A 89 2007 963 966 (Pubitemid 47613079)
136. 4 J Phys Chem C 113 2009 14059 14066
137. 4-Al-LiH composite powder Scripta Mater 58 2008 963 965
138. 4 system J Alloy Comp 487 2009 434 438
139. 4 system J Phys Chem Solids 71 2010 1144 1149
140. 4 destabilized metal hydride system J Alloy Comp 475 2009 110 115
141. S.V. Alapati, J.K. Johnson, and D.S. Sholl Large-scale screening of metal hydride mixtures forhigh-capacity hydrogen storage from first-principles calculations J Phys Chem C 112 2008 5258 5262
142. 2 (M=Ce, Ca) composites J Phys Chem C 112 2008 9520 9524
143. J.-H. Shim, J.-H. Lim, S.-U. Rather, Y.-S. Lee, D. Reed, and Y. Kim Effect of hydrogen back pressure on dehydrogenation behavior of LiBH4 based reactive hydride composites J Phys Chem Lett 1 2010 59 63
144. 2 composite Int J Hydrogen Energ 35 2010 6578 6582
145. 5 Scripta Mater 59 2008 1251 1254
146. 4: calculated dehydrogenation enthalpy, including zero point energy, and the structure of the phonon spectra J Chem Phys 128 2008 234505
147. F.E. Pinkerton, and M.S. Meyer Reversible hydrogen storage in the lithium borohydride - calcium hydride coupled system J Alloy Comp 464 2008 L1 L4
148. S.V. Alapati, J.K. Johnson, and D.S. Sholl Predicting reaction equilibria for destabilized metal hydride decomposition reactions for reversible hydrogen storage J Phys Chem C 111 2007 1584 1591 (Pubitemid 46347001)
149. S.V. Alapati, J.K. Johnson, and D.S. Sholl Using first principles calculations to identify new destabilized metal hydride reactions for reversible hydrogen storage Phys Chem Chem Phys 9 2007 1438 1452
150. 4 system: experimental assesment of chemical destabilization effects J Phys Chem C 112 2008 8481 8485
151. 2 composite system determined by dynamic pcT measurements J Phys Chem C 114 2010 16801 16805
152. 8 J Phys Chem B 109 2005 6 8 (Pubitemid 40120934)
153. 2.67 with noble metal additions J Phys Chem B 110 2006 7967 7974
154. G.P. Meisner, M.L. Scullin, M.P. Balogh, F.E. Pinkerton, and M.S. Meyer Hydrogen release from mixtures of lithium borohydride and lithium amide: a phase diagram Study J Phys Chem B 110 2006 4186 4192
155. 8 Nanotechnology 20 2009 204002
156. 4 system Dalton Trans 37 2008 2395 2399 (Pubitemid 351631306)
157. 2 Appl Phys A 80 2005 1409 1412 (Pubitemid 40661512)
158. Y. Nakamori, A. Ninomiya, G. Kitahara, M. Aoki, T. Noritake, and K. Miwa Dehydriding reactions of mixed complex hydrides J Power Sourc 155 2006 447 455
159. 2 Appl Phys A 83 2006 277 279
160. 10 J Phys Chem C 113 2009 11172 11176
161. 10 Inorg Chem 45 2006 1433 1435
162. 3 Chem Commun 2006 2439 2441
163. 10 Appl Phys Lett 88 2006 231904
164. 10 J Appl Phys 102 2007 033507
165. 10 from first principles Phys Rev B 75 2007 014101
166. 10 Chem Mater 20 2008 1245 1247 (Pubitemid 351363043)
167. J. Yang, A. Sudik, D.J. Siegel, D. Halliday, A. Drews, and R.O. Carter A self-catalyzinghydrogen-storage material Angew Chem Int Ed 47 2008 882 887
168. 2 J Alloy Comp 446-447 2007 345 349 (Pubitemid 47539073)
169. x mixtures (X = 0.0-1.0) J Phys Chem C 112 2008 4384 4390
170. 2 ternary composites J Phys Chem C 113 2009 2004 2013
171. 4 phase diagram J Alloy Comp 446-447 2007 355 359 (Pubitemid 47539081)
172. 4 system for hydrogen storage Int J Hydrogen Energ 34 2009 8086 8093
173. 2 nanoparticles Int J Hydrogen Energ 35 2010 6323 6331
174. 2 in reactive hydride composites containing complex borohydrides J Alloy Comp 440 2007 L18 L21
175. 2 system with the addition of Mn and V dopants J Power Sourc 195 2010 7380 7385
176. 2 reactive hydride composites for sorption kinetics Acta Mater 58 2010 3381 3389
177. 2 hydrogen storage system Int J Hydrogen Energ 36 2011 5425 5430
178. P.J. Wang, L.P. Ma, Z.Z. Fang, X.D. Kang, and P. Wang Improved hydrogen storage property of Li-Mg-B-H system by milling with titanium trifluoride Energy Environ Sci 1 2009 120 123
179. 2 system using ultrahigh field nuclear magnetic resonance spectroscopy Appl Phys Lett 94 2009 141905
180. 2 system using ultra-high field nuclear magnetic resonance spectroscopy J Power Sourc 195 2010 3645 3648
181. 4/Al studied by in situ neutron diffraction J Alloy Comp 484 2009 654 659
182. W. Li, J.J. Vajo, R.W. Cumberland, P. Liu, S.-J. Hwang, and C. Kim Hydrogenation of magnesium nickel boride for reversible hydrogen storage J Phys Chem Lett 1 2010 69 72
183. 4 and its surfaces: a first-principles study J Phys Chem A 108 2004 8682 8690
184. 4(010) Surface: an ab initio study J Phys Chem C 111 2007 12124 12128 (Pubitemid 47325798)
185. 4 for hydrogen storage: a densityfunctional analysis J Chem Theory Comput 5 2009 3079 3087
186. P. Choudhury, V.R. Bhethanabotla, and E. Stefanakos First principles study to identify the reversible reaction step of a multinary hydrogen storage "Li-Mg-B-N-H" system Int J Hydrogen Energ 35 2010 9002 9011
187. H.W. Brinks, A. Fossdal, and B.C. Hauback Adjustment of the stability of complex hydrides byanion substitution J Phys Chem C 112 2008 5658 5661
188. 4 by fluorine anion doping for hydrogen storage: a density functional study Chem Phys Lett 450 2008 318 321
189. 4 J Alloy Comp 2010 10.1016/j.jallcom.2010.10.005
190. 2 system for reversible hydrogen storage J Phys Chem C 114 2010 10291 10296
191. 4-LiCl solid solutions Chem Mater 21 2009 5772 5782
192. L.H. Rude, E. Groppo, L.M. Arnbjerg, D.B. Ravnsbæk, R.A. Malmkjær, and Y. Filinchuk Iodide substitution in lithium borohydride, LiBH4-LiI J Alloy Comp 509 2011 8299 8305
193. M. Au, A. Jurgensen, and K. Zeigler Modified lithium borohydrides for reversible hydrogen storage (2) J Phys Chem B 110 2006 26482 26487 (Pubitemid 46133369)
194. M. Au, W. Spencer, A. Jurgensen, and C. Zeigler Hydrogen storage properties of modified lithium borohydrides J Alloy Comp 462 2008 303 309
195. 4 J Phys Chem C 113 2009 17231 17234
196. 4-Ni composite J Alloy Comp 479 2009 545 548
197. 4 composites Scripta Mater 60 2009 667 670
198. 3 addition J Power Sourc 195 2010 3266 3274
199. 3 composite J Phys Chem C 112 2008 4005 4010
200. 2 J Phys Chem C 112 2008 11059 11062
201. 4 destabilized with various oxides J Phys Chem C 113 2009 17945 17949
202. M. Au, and A. Jurgensen Modified lithium borohydrides for reversible hydrogen storage J Phys Chem B 110 2006 7062 7067 (Pubitemid 43675369)
203. 4: in-situ synchrotron radiation powder X-ray diffraction study J Phys Chem C 112 2008 1299 1303 (Pubitemid 351262549)
204. M. Au, A.R. Jurgensen, W.A. Spencer, D.L. Anton, F.E. Pinkerton, and S.-J. Hwang Stability and reversibility of lithium borohydrides doped by metal halides and hydrides J Phys Chem C 112 2008 18661 18671
205. 3 Energy Environ Sci 3 2010 465 470
206. n (n = 2 and 3) mixtures J Alloy Comp 2010 10.1016/j.jallcom.2010. 10.070
207. 4 destabilized by chlorides of transition metal Fe, Co, and Ni Int J Hydrogen Energ 35 2010 7288 7294
208. 3 for hydrogen storage J Alloy Comp 509 2010 751 757
209. Y. Nakamori, and S.I. Orimo Dehydriding reaction of metal hydrides and alkali borohydrides enhanced by microwave irradiation Appl Phys Lett 88 2006 112104
210. 2 composite Int J Hydrogen Energ 33 2008 74 80
211. 2 mixtures Int J Hydrogen Energ 35 2010 7519 7529
212. 2-Al system J Phys Chem C 113 2009 21964 21969
213. 2 composite with Pd nanoparticles addition J Alloy Comp 503 2010 345 349
214. 3 Int J Hydrogen Energ 36 2011 7128 7135
215. 2 composites improved by Ce-based additives Int J Hydrogen Energ 36 2011 5418 5424
216. 2 system Int J Hydrogen Energ 2011 10.1016/j.ijhydene.2011.03.027
217. 2 mixture for hydrogen storage Int J Hydrogen Energ 36 2011 1200 1205
218. 2 system catalysed by Ru nanoparticles supported on multiwalled carbon nanotubes J Alloy Comp 509 2011 5012 5016
219. 2 system J Alloy Comp 481 2009 473 479
220. 4 system by addition of ZrCo hydride Int J Hydrogen Energ 33 2010 7809 7814
221. 3 J Phys Chem C 114 2010 11643 11649
222. 4 in nanoporous carbon scaffolds J Phys Chem C 112 2008 5651 5657
223. 4: a density-functional study Nanotechnology 20 2009 275704
224. 4 nanoparticles supported by disordered mesoporous carbon: hydrogen storage performances and destabilization mechanisms Int J Hydrogen Energ 32 2007 3976 3980 (Pubitemid 350016589)
225. 4: elimination of diborane release and tunable behavior for hydrogen storage applications Chem Mater 23 2011 1331 1336
226. 4 via confinement in highly ordered nanoporous carbon J Phys Chem C 114 2010 14036 14041
227. Z.Z. Fang, P. Wang, T.E. Rufford, X.D. Kang, G.Q. Lu, and H.M. Cheng Kinetic and thermodynamic-based improvements of lithium borohydride incorporated in activated carbon Acta Mater 56 2008 6257 6263
228. 4 destabilized by carbon Appl Phys Lett 90 2007 034106
229. Z.Z. Fang, X.D. Kang, P. Wang, and H.M. Cheng Improved reversible dehydrogenation of lithium borohydride by milling with as-prepared single-walled carbon nanotubes J Phys Chem C 112 2008 17023 17029
230. 2 composite Int J Hydrogen Energ 33 2008 5611 5616
231. P.J. Wang, Z.Z. Fang, L.P. Ma, X.D. Kang, and P. Wang Effect of carbon addition on hydrogen storage behaviors of Li-Mg-B-H system Int J Hydrogen Energ 35 2010 3072 3075
232. T.K. Nielsen, U. Bösenberg, R. Gosalawit, M. Dornheim, Y. Cerenius, and F. Besenbacher A reversible nanoconfined chemical reaction ACS Nano 4 2010 3903 3908