Dehydriding and re-hydriding properties of high-energy ball milled LiBH4 + MgH2 mixtures

International Journal of Hydrogen Energy

Volumn 35, Issue 14, 2010, Pages 7519-7529

  Crosby, Kyle ^a   Shaw, Leon L ^a  

^a UNIVERSITY OF CONNECTICUT   (United States)

Author keywords

Hydriding and dehydriding properties; Hydrogen storage materials; Lithium borohydride

Indexed keywords

AMORPHOUS PHASIS; BALL-MILLED; CATALYTIC EFFECTS; CRYSTALLINE COMPOUNDS; DEFECT CONCENTRATIONS; DEHYDRIDING; DEHYDRIDING PROPERTIES; HIGH ENERGY; HIGH-ENERGY BALL MILLING; HYDRIDING; HYDRIDING PROPERTIES; HYDROGEN RELEASE; HYDROGEN STORAGE MATERIALS; LIQUID NITROGEN TEMPERATURE; LITHIUM BOROHYDRIDE; NANOCRYSTALLINES;

BALL MILLING; HIGH ENERGY PHYSICS; HYDROGEN; LIQUID NITROGEN; LITHIUM; MIXTURES; SPHERES;

HYDROGEN STORAGE;

EID: 77953914653     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.04.124     Document Type: Article

References (37)

1. Schlapbach L., and Zuttel A. Hydrogen-storage materials for mobile applications. Nature 414 (2001) 353-358
2. 4: I. Crystal structure. J Alloys Compd 346 (2002) 200-205
3. 4 a new hydrogen storage material. J Power Sources 118 (2003) 1-7
4. 4. J Alloys Compd 356-357 (2003) 515-520
5. 4/silica-gel mixtures and the effect of additives. J Phys Chem C 111 (2007) 14026-14029
6. 4 destabilized by carbon. Appl Phys Lett 90 (2007) 034106
7. Fang Z.Z., Wang P., Rufford T.E., Kang X.D., Lu G.Q., and Cheng H.M. Kinetic- and thermodynamic-based improvements of lithium borohydride incorporated into activated carbon. Acta Mater 56 (2008) 6257-6263
8. 4 nanoparticles supported by disordered mesoporous carbon: hydrogen storage performances and destabilization mechanisms. Int J Hydrogen Energy 32 (2007) 3976-3980
9. 4. J Phys Chem B 112 (2008) 906-910
10. 4 in nanoporous carbon scaffolds. J Phys Chem C 112 (2008) 5651-5657
11. 4. J Phys Chem B 109 (2005) 3719-3722
12. Yu X.B., Grant D.M., and Walker G.S. A new dehydrogenation mechanism for reversible multicomponent borohydride systems - the role of Li-Mg alloys. Chem Commun (2006) 3906-3908
13. 2 hydrogen storage material. J Phys Chem C 111 (2007) 12881-12885
14. Nakagawa T., Ichikawa T., Hanada N., Kojima Y., and Fujii H. Thermal analysis on the Li-Mg-B-H systems. J Alloys Compd 446-447 (2007) 306-309
15. 2. J Power Sources 194 (2009) 1128-1134
16. 2). J Phys Chem C 111 (2007) 19134-19140
17. 2 system. J Phys Chem C 112 (2008) 18232-18243
18. 2 system using ultra-high field nuclear magnetic resonance spectroscopy. Appl Phys Lett 94 (2009) 141905
19. Yang Z.G., and Shaw L. Synthesis of nanocrystalline SiC at ambient temperature through high energy reaction milling. Nanostruct Mater 7 (1996) 873-886
20. Klug H.P., and Alexander L.E. X-ray diffraction procedures for polycrystalline and amorphous materials (1974), John Wiley & Sons, Inc., New York, NY
21. Stokes A.R., and Wilson A.J.C. The diffraction of X-rays by distorted crystal aggregates - I. Proc Phys Soc London 56 (1944) 174-181
22. 2 alloys prepared via mechanical alloying. Acta Mater 51 (2003) 2647-2663
23. Ortiz A.L., and Shaw L. X-ray diffraction analysis of a severely plastically deformed aluminum alloy. Acta Mater 52 (2004) 2185-2197
24. Brunauer S., Emmett P.H., and Teller E. Adsorption of gases in multimolecular layers. J Am Chem Soc 60 (1938) 309-319
25. Davis R.M., McDermott B., and Koch C.C. Mechanical alloying of brittle materials. Mater Trans 19A (1988) 2867-2874
26. Miller P.J., Coffey C.S., and DeVast V.F. Heating in crystalline solids due to rapid deformation. J Appl Phys 59 (1986) 913-916
27. Joardar J., Pabi S.K., and Murty B.S. Estimation of entrapped powder temperature during mechanical alloying. Scr Mater 50 (2004) 1199-1202
28. 4/SiC composite powders through high energy reaction milling. Mater Sci Eng A 244 (1998) 113-126
29. Bogdanovic B., Bons P., Schwickardi M., and Seevogel K. Tetrahydrofuran-soluble magnesium dihydride by catalytic hydrogenation of magnesium. Chem Ber 124 (1991) 1041-1050
30. 2/graphite composite. Mater Sci Eng A 447 (2007) 180-185
31. Zeng K., Klassen T., Oelerich W., and Bormann R. Critical assessment and thermodynamic modeling of the Mg-H system. Int J Hydrogen Energy 24 (1999) 989-1004
32. Bouaricha S., Dodelet J.P., Guay D., Huot J., and Schulz R. Activation characteristics of graphite modified hydrogen absorbing materials. J Alloys Compd 325 (2001) 245-251
33. Guvendiren M., Bayboru E., and Ozturk T. Effects of additives on mechanical milling and hydrogenatioin of magnesium powders. Int J Hydrogen Energy 29 (2004) 491-496
34. 2/SWNT composite prepared by ball milling. J Alloys Compd 420 (2006) 278-282
35. 4 catalyzed magnesium. J Phys Chem C 111 (2007) 12495-12498
36. Zaluska A., Zaluski L., and Strom-Olsen J.O. Structure, catalysis and atomic reactions on the nano-scale: a systematic approach to metal hydrides for hydrogen storage. Appl Phys A 72 (2001) 157-165
37. Huot J., Liang G., and Schulz R. Mechanically alloyed metal hydride systems. Appl Phys A 72 (2001) 187-195