Micellization behavior of cationic gemini surfactants in aqueous-ethylene glycol solution

Journal of Surfactants and Detergents

Volumn 14, Issue 4, 2011, Pages 555-562

  Tikariha, Deepti ^a   Kumar, Birendra ^a   Singh, Namrata ^a   Ghosh, Kallol K ^a   Quagliotto, Pierluigi ^b  

^a PT RAVISHANKAR SHUKLA UNIVERSITY   (India)

^b UNIVERSITY OF TURIN   (Italy)

Author keywords

CMC; Effect of salt; Gemini surfactant; Micellization; Thermodynamics of micellization

Indexed keywords

CATIONIC GEMINI SURFACTANT; CMC; CONDUCTOMETRIC MEASUREMENTS; EFFECT OF SALT; ETHYLENE GLYCOL SOLUTIONS; FREE ENERGY OF MICELLIZATION; GEMINI SURFACTANT; MICELLAR IONIZATION; MICELLIZATION BEHAVIOR; MINIMUM SURFACES; SURFACE EXCESS CONCENTRATION; SURFACE PRESSURES; TEMPERATURE DEPENDENCE; THERMODYNAMICS OF MICELLIZATION;

ADSORPTION; BROMINE COMPOUNDS; CATIONIC SURFACTANTS; CONCENTRATION (PROCESS); CRITICAL MICELLE CONCENTRATION; ETHYLENE; ETHYLENE GLYCOL; FREE ENERGY; IONIZATION; MICELLES; SODIUM CHLORIDE; SURFACE TENSION; THERMODYNAMICS;

MICELLIZATION;

EID: 80053935433     PISSN: 10973958     EISSN: 15589293     Source Type: Journal    
DOI: 10.1007/s11743-011-1280-5     Document Type: Article

References (55)

1. B Sohrabi A Bazyari M Hashemianzadeh 2010 Effect of ethylene glycol on micellization and surface properties of gemini surfactant solutions Colloids Surf A 364 87 93 10.1016/j.colsurfa.2010.04.042 1:CAS:528:DC%2BC3cXnslyltLY%3D
2. FM Menger JS Keiper 2000 Gemini surfactants Angew Chem Int Ed 39 1906 1920 10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-Q (Pubitemid 30399120)
3. R Zana Y Talmon 1993 Dependence of aggregate morphology on structure of dimeric surfactants Nature 362 228 230 10.1038/362228a0 1:CAS:528: DyaK3sXis1WntLs%3D (Pubitemid 23638737)
4. FM Menger CA Littau 1991 Gemini surfactants: synthesis and properties J Am Chem Soc 113 1451 1452 10.1021/ja00004a077 1:CAS:528:DyaK3MXmsVOrsQ%3D%3D
5. D Tikariha KK Ghosh P Quagliotto 2010 Micellization of gemini surfactants in polymer solutions Tenside Surf Deterg 47 162 165 1:CAS:528: DC%2BC3cXpvVOgt74%3D
6. Deepti KK Ghosh P Quagliotto 2009 Micellization behavior of [C16-4-C16], 2Br-gemini surfactant in binary aqueous-solvent mixtures Indian J Chem 48A 1522 1526 1:CAS:528:DC%2BC3cXnt1Wh
7. L Han Z Ye H Chen P Luo 2009 The interfacial tension between cationic gemini surfactant solution and crude oil J Surf Deterg 12 185 190 10.1007/s11743-009-1109-7 1:CAS:528:DC%2BD1MXntFaku7w%3D
8. L Prez A Pinazo MR Infante R Pons 2007 Investigation of the micellization process of single and gemini surfactants from arginine by SAXS, NMR self-diffusion, and light scattering J Phys Chem B 111 11379 11387 10.1021/jp071121p (Pubitemid 47598318)
9. T Chakraborty S Ghosh 2007 Mixed micellization of an anionic gemini surfactant () with conventional polyethoxylated nonionic surfactants in brine solution at pH 5 and 298 K Colloid Polym Sci 285 1665 1673 10.1007/s00396-007- 1738-1 1:CAS:528:DC%2BD2sXhtlKlt7nP (Pubitemid 350193637)
10. Y You J Zhao R Jiang J Cao 2009 Strong effect of NaBr on self-assembly of quaternary ammonium gemini surfactants at air/water interface and in aqueous solution studied by surface tension and fluorescence techniques Colloid Polym Sci 287 839 846 10.1007/s00396-009-2038-8 1:CAS:528:DC%2BD1MXlt1Gmtbs%3D
11. JJ Chung SW Lee Choi JHo 1991 Salts effects on the critical micelle concentration and counterion binding of cetylpyridinium bromide micelles Bull Korean Chem Soc 12 411 415 1:CAS:528:DyaK3MXls1OitbY%3D
12. Rosen MJ (1988) Surfactants and Interfacial phenomena, 2nd edn. Wiley, New York
13. G Bai J Wang H Yan Z Li RK Thomas 2001 Thermodynamics of molecular self-assembly of cationic gemini and related double chain surfactants in aqueous solution J Phys Chem B 105 3105 3108 10.1021/jp0043017 1:CAS:528: DC%2BD3MXhslCqtrw%3D (Pubitemid 35372788)
14. T Arnarson PH Elworthy 1981 Effects of structural variations on non-ionic surfactants on micellar properties and solubilization: surfactants containing very long hydrocarbon chains J Pharm Pharmocol 33 141 144 10.1111/j.2042-7158. 1981.tb13736.x 1:CAS:528:DyaL3MXltVehs7g%3D (Pubitemid 11098060)
15. CA Bunton L Robinson 1968 Electrolyte effects on bimolecular nucleophilic displacements J Am Chem Soc 90 5965 5971 10.1021/ja01024a004 1:CAS:528:DyaF1cXltFSmsLw%3D
16. S Paria PK Yuet 2006 Effect of chain length and electrolytes on the adsorbtion of n-alkylpyridinium bromide surfactants at sand water interfaces Ind Eng Chem Res 45 712 718 10.1021/ie050808y 1:CAS:528:DC%2BD2MXhtlSmtrvO (Pubitemid 43164158)
17. D Mitra I Chakraborty SC Bhattacharya SP Moulik 2007 Interfacial and solution properties of tetraalkylammonium bromides and their sodium dodecyl sulfate interacted products: a detailed physicochemical study Langmuir 23 3049 3061 10.1021/la062830h 1:CAS:528:DC%2BD2sXhslahsr8%3D (Pubitemid 46450132)
18. LS Romsted RB Dunlap EH Cordes 1967 Secondary valence force catalysis. V. Salt effects on certain detergent-catalyzed organic reactions J Phys Chem 71 4581 4583 10.1021/j100872a082 1:CAS:528:DyaF1cXjvVKmsQ%3D%3D
19. SK Han M Kim YH Park JH Lee JW Back 1992 Effect of urea derivatives on the critical micelle concentration of polyoxyethylated nonionic surfactant Arch Pharm Res 15 126 129 10.1007/BF02974086 1:CAS:528:DyaK3sXisFOjsr4%3D (Pubitemid 23123107)
20. A Rodriguez MDM Graciani M Angulo ML Moya 2008 Effects of addition of polar organic solvents on micellization Langmuir 24 12785 10.1021/la802320s 1:CAS:528:DC%2BD1cXhtlGku7rF
21. K Glenn S Moroze SC Bhattacharya R Palepu 2005 Effect of ethylene glycol on the thermodynamic and micellar properties of tween 40, 60, and 80 J Dispersion Sci Technol 26 79 86 10.1081/DIS-200040137 1:CAS:528: DC%2BD2MXptFShsQ%3D%3D (Pubitemid 40107200)
22. A MacIsaac Al-Wardian K Glenn R Palepu 2004 Effects of di-, tri-, and tetraethylene glycols on the thermodynamic and micellar properties of triton X-100 in water Can J Chem 82 1774 1780 10.1139/v04-157 (Pubitemid 40767577)
23. CC Ruiz JA Molina-Bolivar J Aguiar G MacIsaac S Moroze R Palepu 2001 Thermodynamic and structural studies of Triton X-100 micelles in ethylene glycol-water mixed solvents Langmuir 17 6831 6840 10.1021/la010529p 1:CAS:528:DC%2BD3MXntlWqsbg%3D (Pubitemid 35330565)
24. D Tikariha KK Ghosh P Quagliotto S Ghosh 2010 Mixed micellization properties of cationic monomeric and gemini surfactants J Chem Eng Data 55 4162 4167 10.1021/je100113r 1:CAS:528:DC%2BC3cXosFaksLY%3D
25. Lu Ting J Huang D Liang 2008 Salt effect on microstructures in cationic gemini surfactant solutions as studied by dynamic light scattering Langmuir 24 1740 1744 10.1021/la702832v (Pubitemid 351500926)
26. IM Umlong K Ismail 2007 Micellization behavior of sodium dodecyl sulfate in different electrolyte media Colloids Surf A 299 8 15 10.1016/j.colsurfa.2006. 11.010 1:CAS:528:DC%2BD2sXjsVSmtro%3D (Pubitemid 46441813)
27. R Zana M Benrraou R Rueff 1996 Alkanediyl-.alpha., omega.- bis(dimethylalkylammonium bromide) surfactants. 1. Effect of the spacer chain length on the critical micelle concentration and micelle ionization degree Langmuir 7 1072 1075 10.1021/la00054a008 (Pubitemid 21667311)
28. R Zana 1996 Critical micellization concentration of surfactants in aqueous solution and free energy of micellization Langmuir 12 1208 1211 10.1021/la950691q 1:CAS:528:DyaK28XhtVCjtrg%3D
29. Rosen MJ (1988) Surfactants and Interfacial phenomena, 2nd edn. Wiley, New York
30. R De Lisi A Inglese S Milioto A Pellerito 1997 Demixing of mixed micelles. Thermodynamics of sodium perfluorooctanoate sodium dodecanoate mixtures in water Langmuir 13 192 202 10.1021/la960636x (Pubitemid 127591918)
31. R Zana H Levy D Danino Y Talmon K Kwektat 1997 Mixed micellization of cetyltrimethylammonium bromide and an anionic dimeric (gemini) surfactant in aqueous solution Langmuir 13 402 408 10.1021/la9606963 1:CAS:528: DyaK2sXps12msA%3D%3D (Pubitemid 127561532)
32. P Carpena J Aguiar P Bernaola-Galván C Carnero Ruiz 2002 Problems associated with the treatment of conductivity-concentration data in surfactant solutions: Simulations and experiments Langmuir 18 6054 6058 10.1021/la025770y 1:CAS:528:DC%2BD38XkvFCktLo%3D (Pubitemid 35383329)
33. P Quagliotto N Barbero C Barolo K Costabello L Marchese S Coluccia K Kalyanasyundaram G Viscardi 2009 Characterization of monomeric and gemini cationic amphiphilic molecules by fluorescence intensity and anisotropy Dyes and Pigments 82 124 129 10.1016/j.dyepig.2008.12.002 1:CAS:528:DC%2BD1MXjs1agtrw%3D
34. N Barbero P Quagliotto C Barolo E Artuso R Buscaino G Viscardi 2009 Characterization of monomeric and gemini cationic amphiphilic molecules by fluorescence intensity and anisotropy Part 2 Dyes and Pigments 83 396 402 10.1016/j.dyepig.2009.06.013 1:CAS:528:DC%2BD1MXptVGitbc%3D
35. P Quagliotto G Viscardi C Barolo E Barni S Bellinvia E Fisicaro C Compari 2003 Gemini pyridinium surfactants: Synthesis and conductometric study of a novel class of amphiphiles J Org Chem 68 7651 7660 10.1021/jo034602n 1:CAS:528:DC%2BD3sXnt1Omtrw%3D (Pubitemid 37186115)
36. P Quagliotto C Barolo N Barbero E Barni C Compari E Fisicaro G Viscardi 2009 Synthesis and characterization of highly fluorinated gemini pyridinium surfactants Eur J Org Chem 2009 3167 3177 10.1002/ejoc.200900063
37. P Quagliotto N Barbero C Barolo E Artuso C Compari E Fisicaro G Viscardi 2009 Synthesis and properties of cationic surfactants with tuned hydrophobicity J Colloid Interface Sci 340 269 275 10.1016/j.jcis.2009.09.009 1:CAS:528:DC%2BD1MXht1OhurfI
38. Mysels KJ (1996) Folklore CC (1981). 6. The surface tension minimum and Gilbert D. Miles. Langmuir, 12:2325-2326
39. MJ Rosen 1981 Purification of surfactants for studies of their fundamental surface properties J Colloid Interface Sci 79 587 588 10.1016/0021-9797(81)90111-9 1:CAS:528:DyaL3MXos1Wjug%3D%3D
40. Lunkenheimer K (2002) On the problem of surface chemical purity of surfactants - phenomena, analysis, results, consequences, and prospects. In: encyclopedia of surface and colloid science. Marcel Dekker, NY, pp. 3739-3772
41. FM Menger AL Galloway ME Chlebowski 2005 Surface tension of aqueous amphiphiles Langmuir 21 9010 9012 10.1021/la051363l 1:CAS:528: DC%2BD2MXpsFarsbc%3D (Pubitemid 41433939)
42. FM Menger L Shi SA Rizvi 2010 Additional support for a revised Gibbs analysis Langmuir 26 1588 1589 10.1021/la9043914 1:CAS:528:DC%2BD1MXhsFWmtbfI
43. R Humphry-Baker M Grätzel Y Moroi 2006 Pyrene fluorescence at air/sodium dodecyl sulfate solution interface Langmuir 22 11205 11207 10.1021/la062014+ 1:CAS:528:DC%2BD28Xht1SqtLfK (Pubitemid 46129661)
44. H Nakahara O Shibata M Rusdi Y Moroi 2008 Examination of surface adsorption of soluble surfactants by surface potential measurement at the air/solution interface J Phys Chem C 112 6398 6403 10.1021/jp7108169 1:CAS:528:DC%2BD1cXktFSgsLw%3D
45. T Priester M Bartoszek K Lunkenheimer 1998 Influence of surface-active trace impurities on the surface properties of aqueous solutions of oligoethylene glycol monooctyl ethers J Colloid Interface Sci 208 6 13 10.1006/jcis.1998.5773 1:CAS:528:DyaK1cXnvFajsb0%3D (Pubitemid 28563526)
46. NR Biswal S Paria 2010 Effect of electrolyte solutions on the adsorption of surfactants at PTFE-water interface Ind Eng Chem Res 49 7060 7067 10.1021/ie100812k 1:CAS:528:DC%2BC3cXotlOqtLw%3D
47. M Shamsipur N Alizadeh H Gharibi 1997 Physicochemical studies of the hexadecylpyridinium bromide micellar system in the presence of various concentrations of sodium bromide using a surfactant-selective electrode Indian J Chem 36A 1031 1037 1:CAS:528:DyaK1cXitVOju7k%3D
48. Israelachvili JN (1992) Intermolecular and surface forces. Academic Press, London
49. S Ghosh SP Moulik 1998 Interfacial and Micellization behaviors of binary and ternary mixtures of amphiphiles (Tween-20, Brij-35, and Sodium dodecyl sulfate) in aqueous medium J Colloid Interface Sci 208 357 366 10.1006/jcis.1998.5752 1:CAS:528:DyaK1cXotV2jtLw%3D (Pubitemid 28564069)
50. T Chakraborty S Ghosh SP Moulik 2005 Micellization andrelated behavior of binary and ternary surfactant mixtures in aqueous medium: cetyl pyridinium chloride (CPC), cetyl trimethyl ammonium bromide (CTAB), and polyoxyethylene (10) cetyl ether (Brij-56) derived system J Phys Chem B 109 14813 14823 10.1021/jp044580o 1:CAS:528:DC%2BD2MXmt1Kgtrs%3D (Pubitemid 41173701)
51. GB Ray I Chakraborty S Ghosh SP Moulik 2007 On mixed binary surfactant systems comprising MEGA 10 and alkyltrimethylammonium bromides: A detailed physicochemical study with a critical analysis J Colloid Interface Sci 307 543 553 10.1016/j.jcis.2006.11.055 1:CAS:528:DC%2BD2sXht1Ggsrw%3D (Pubitemid 46175842)
52. GB Ray I Chakraborty S Ghosh SP Moulik RM Palepu 2005 Self-aggregation of alkyltrimethylammonium bromides (C10-, C12-, C14-, and C16TAB) and their binary mixtures in aqueous medium: a critical and comprehensive assessment of interfacial behavior and bulk properties with reference to two types of micelle formation Langmuir 21 10958 10967 10.1021/la051509g 1:CAS:528:DC%2BD2MXhtFSksr3N (Pubitemid 41775052)
53. M Ao P Huang G Xu X Yang Y Wang 2009 Aggregation and thermodynamic properties of ionic liquid-type gemini imidazolium surfactants with different spacer length Colloid Polym Sci 287 395 402 10.1007/s00396-008-1976-x 1:CAS:528:DC%2BD1cXhsFWitr7O
54. S Ghosh 2001 Surface chemical and micellar properties of binary and ternary surfactant mixtures (Cetyl Pyridinium Chloride, tween-40, and Brij-56) in an aqueous medium J Colloid Interface Sci 244 128 138 10.1006/jcis.2001.7855 1:CAS:528:DC%2BD3MXot1Kis7c%3D (Pubitemid 33144968)
55. P Molyneux CT Rhode J Swardrick 1965 Thermodynamics of micellization of N-alkyl betaines Faraday Trans Soc 61 1043 1052 10.1039/tf9656101043 1:CAS:528:DyaF2MXktlWqu7g%3D