Additional support for a revised Gibbs analysis

Langmuir

Volumn 26, Issue 3, 2010, Pages 1588-1589

  Menger, Fredric M ^a   Shi, Lei ^a   Rizvi, Syed A A ^a  

^a EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AIR/WATER INTERFACES; LANGMUIR FILMS; LINEAR REGION; MICELLE FORMATION; SURFACE TENSION REDUCTION;

MOLECULES; SODIUM; SODIUM SULFATE; SURFACE ACTIVE AGENTS; SURFACE CHEMISTRY; SURFACE PROPERTIES; SURFACE TENSION; WETTING;

CAPILLARITY;

EID: 75749087259     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la9043914     Document Type: Article

References (3)

1. Rosen, M. J, Surfactants and Interfacial Phenomena, 3rd ed.; Wiley: Chichester, U.K., 2004; pp 65-80. This reference contains a 16-page listing of surfactant areas.
2. Menger, F. M.; Shi, L.; Rizvi, S. A. A. J. Am. Chem. Soc. 2009, 131, 10380.
3. Moroi, Y. in Croat. Chem. Acta 2007, 80, 381 argues that soluble surfactant films are concentrated as aggregates at some distance beneath the air/water interface. If this is true, then it greatly complicates our comparison of soluble and insoluble films at the air/water interface. Our results are predicated on the assumption that both types of film have the ionic headgroups immersed in the water and the hydrocarbon tails projecting into the air.