Extraction of caffeine from Robusta coffee (Coffea canephora var. Robusta) husks using supercritical carbon dioxide

Journal of Supercritical Fluids

Volumn 59, Issue , 2011, Pages 53-60

  Tello, J ^a   Viguera, M ^a   Calvo, L ^a  

^a UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

Author keywords

Caffeine; Coffee husks; Extraction; Supercritical CO2

Indexed keywords

CAFFEINE; CAFFEINE CONTENTS; COFFEA CANEPHORA; COFFEE HUSKS; CONTINUOUS FLOWS; EXTRACTION RATE; EXTRACTION YIELD; LABORATORY SCALE; NATURAL SOURCES; OPERATIONAL CONDITIONS; PRE-TREATMENTS; PRESSURE AND TEMPERATURE; PRODUCTION DATA; ROBUSTA COFFEE; SUPERCRITICAL CARBON DIOXIDES; SUPERCRITICAL CO; TECHNICAL FEASIBILITY; TECHNOLOGICAL APPLICATIONS; WATER WASHING;

CARBON DIOXIDE; EXTRACTION; FLOW RATE; MILLING (MACHINING); SUPERCRITICAL FLUID EXTRACTION;

COFFEE;

EID: 80053576710     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2011.07.018     Document Type: Article

References (50)

1. H. Ashihara, and A. Crozier Caffeine: a well known but little mentioned compound in plant science Trends in Plant Science 6 2001 407 413 (Pubitemid 33145937)
2. J.E. James Caffeine mental performance and mood D.H. Watson, Performance Functional Foods 2003 Woodhead Publishing Ltd. and CRC Press Cambridge 168 186
3. L.S. Lundsberg Caffeine consumption G.A. Spiller, Caffeine 1998 CRC Press Boca Raton 199 224
4. B.D. Smith, T. White, and R. Shapiro The arousal drug of choice: sources and consumption of caffeine B.D. Smith, U. Gupta, B.S. Gupta, Caffeine and Activation Theory 2007 CRC Press New York 9 42
5. A. Smith Effects of caffeine on human behavior Food and Chemical Toxicology 40 2002 1243 1255 (Pubitemid 35247455)
6. J.V. Higdon, and B. Frei Coffee health: a review of recent human research Critical Reviews in Food Science and Nutrition 46 2006 101 123
7. P. Nawrot, S. Jordan, J. Eastwood, J. Rotstein, A. Hugenholtz, and M. Feeley Effects of caffeine on human health Food Additives and Contaminants 20 1 2003 1 30 (Pubitemid 36193121)
8. M.L. Nurminen, L. Niittynen, R. Korpela, and H. Vapaatalo Coffee, caffeine and blood pressure: a critical review European J. Clinical Nutrition 53 1999 831 839 (Pubitemid 29532988)
9. K. Ramalakshmi, and B. Raghavan Caffeine in coffee: its removal. Why and how? Critical Reviews in Food Science Nutrition 39 5 1999 441 456
10. K. Zosel, Process for recovering caffeine, U.S. 3,806,619 (April 23, 1974).
11. W.J. Kim, J.-D. Kim, J. Kim, S.-G. Oh, and Y.-W. Lee Selective caffeine removal from green tea using supercritical carbon dioxide extraction J. Food Engineering 89 2008 303 309
12. H. Ien, and M. Gürü Extraction of caffeine from stalk and fiber wastes using supercritical carbon dioxide J. Supercritical Fluids 50 2009 225 228
13. M. Ien H., and M. Gürü Effect of ethanol content on supercritical carbon dioxide extraction of caffeine from tea stalk and fiber wastes J. Supercritical Fluids 55 2010 156 160
14. C.B. Mehr, R.N. Biswal, and J.L. Collins Supercritical carbon dioxide extraction of caffeine from guaraná J. Supercritical Fluids 9 1996 185 191 (Pubitemid 126655329)
15. M.D.A. Saldaña, C. Zetzl, R.S. Mohamed, and G. Brunner Extraction of methylxanthines from guaraná seeds, maté leaves, and cocoa beans using supercritical carbon dioxide and ethanol J. Agricultural and Food Chemistry 50 2002 4820 4826 (Pubitemid 34856151)
16. 2 and ethane Industrial and Engineering Chemistry Research 41 2002 6751 6758 (Pubitemid 36082811)
17. 2 recovery of caffeine from green coffee oil: new experimental solubility data and modeling Quimica Nova 31 6 2008 1319 1323
18. H.S. Park, H.J. Lee, M.H. Shin, K.-W. Lee, H. Lee, Y.-S. Kim, K.O. Kim, and K.H. Kim Effects of cosolvents on the decaffeination of green tea by supercritical carbon dioxide Food Chemistry 105 2007 1011 1017 (Pubitemid 47069739)
19. C.J. Chang, K.-L. Chiu, Y.-L. Chen, and C.-Y. Chang Separation of catechins from green tea using carbon dioxide extraction; Food Chemistry 68 2000 109 113 (Pubitemid 29488686)
20. A.B.A. de Azevedo, P. Mazzafera, R.S. Mohamed, S.A.B. Vieira de Melo, and T.G. Kieckbusch Extraction of caffeine, chlorogenic acids and lipids from green coffee beans using supercritical carbon dioxide and co-solvents Brazilian J. Chemical Engineering 25 03 2008 543 552
21. 2 extraction J. Supercritical Fluids 40 2007 354 359 (Pubitemid 46335944)
22. H.S. Park, H.-K. Choi, S.J. Lee, K.W. Park, S.-G. Choi, and K.H. Kim Effect of mass transfer on the removal of caffeine from green tea by supercritical carbon dioxide J. Supercritical Fluids 42 2007 205 211 (Pubitemid 46898743)
23. Food and Agriculture Organization of the United Nations (FAO). FAO statistics. < http://faostat.fao.org/site/567/default.aspx#ancor > (accessed 07.06.11).
24. M. Saenger, E.-U. Hartge, J. Werther, T. Ogada, and Z. Siagi Combustion of coffee husks Renewable Energy 23 2001 103 121
25. L.A. Duicela, R. Corral, R. Palma, F. Fernández, B. Fischersworring, Reciclaje de los subproductos de la finca cafetalera, Comunicaciones del Consejo Cafetalero Nacional (COFENAC), IG-CT-034. < http://www.cofenac.org/documentos/Compostaje-de-Subproductos.pdf >, 2003 (accessed 07.06.11).
26. A. Pandey, C.R. Soccol, P. Nigam, D. Brand, R. Mohan, and S. Roussos Biotechnological potential of coffee pulp and coffee husk for bioprocesses Biochemical Engineering J. 6 2000 153 162
27. B.M. Gouvea, C. Torres, A.S. Franca, L.S. Oliveira, and E.S. Oliveira Feasibility of ethanol production from coffee husks Biotechnology Letters 31 2009 1315 1319
28. V.S. Shankaranand, and B.K. Lonsane Coffee husk: an inexpensive substrate for production of citric acid by Aspergillus niger in a solid-state fermentation system World J. Microbiology and Biotechnology 10 1994 165 168 (Pubitemid 2050824)
29. R. Rathinavelu, G. Graziosi, Potential alternative uses of coffee wastes and by-products, International Coffee Organization Communications, ED-1967/05. < http://www.ico.org/documents/ed1967c.pdf >, 2005 (accessed 07.06.11).
30. E.R.B.A. Prata, and L.S. Oliveira Fresh coffee husks as potential sources of anthocyanins LWT-Food Science and Technology 40 2007 1555 1560 (Pubitemid 46976962)
31. L.G. Elias Chemical composition of coffee-berry by-products J.E. Braham, R. Bressani, Coffee Pulp: Composition, Technology and Utilization, IDRC Pub., N 108e, 1979 International Development Research Centre Ottawa 11 16
32. J.B. Ulloa Rojas, J.A.J. Verreth, S. Amato, and E.A. Huisman Biological treatments affect the chemical composition of coffee pulp Bioresource Technology 89 2003 267 274 (Pubitemid 36675376)
33. 2 J. Supercritical Fluids 42 2007 80 87 (Pubitemid 46771119)
34. 2, M.Sc. thesis, Universidade Estadual de Campinas, Campinas, Brazil, 1997.
35. M. Johannsen, and G. Brunner Solubilities of the xanthines caffeine, theophilline and theobromine in supercritical carbon dioxide Fluid Phase Equilibria 95 1994 214 226
36. 2 J. Agricultural and Food Chemistry 47 1999 3804 3808 (Pubitemid 29449509)
37. U. Kopcak, and R.S. Mohamed Caffeine solubility in supercritical carbon dioxide/co-solvent mixtures J. Supercritical Fluids 34 2005 209 214 (Pubitemid 40409688)
38. 2. < http://www.nd.edu/∼enviro/design/caffeine.pdf > (accessed 07.06.11).
39. M. McHugh, and V. Krukonis Supercritical Fluid Extraction 2nd ed. 1994 Butterworth-Heinemann Boston MA pp. 294-299
40. S.M. Pourmortazavi, and S.S. Hajimirsadeghi Supercritical fluid extraction in plant essential and volatile oil analysis J. Chromatography A 1163 2007 2 24 (Pubitemid 47247700)
41. Y. Iwai, H. Nagano, G.S. Lee, M. Uno, and Y. Arai Measurement of entrainer effects of water and ethanol on solubility of caffeine in supercritical carbon dioxide by FT-IR spectroscopy J. Supercritical Fluids 38 2006 312 318 (Pubitemid 44512109)
42. E.K. Asep, S. Jinap, T.J. Tan, A.R. Russly, S. Harcharan, and S.A.H. Nazimah The effects of particle size, fermentation and roasting of cocoa nibs on supercritical fluid extraction of cocoa butter J. Food Engineering 85 2008 450 458 (Pubitemid 47632952)
43. 2 extraction and purification of compounds with antioxidant activity J. Agricultural and Food Chemistry 54 2006 2441 2469
44. E. Reverchón, and I. de Marco Supercritical fluid extraction and fractionation of natural matter J. Supercritical Fluids 38 2006 146 166 (Pubitemid 44444936)
45. L. Wang, and C.L. Weller Recent advances in extraction of nutraceuticals from plants Trends in Food Science and Technology 17 2006 300 312
46. G. Brunner Supercritical fluids: technology and application to food processing J. Food Engineering 67 2005 21 33
47. G. Brunner Gas Extraction Steinkopff Darmstadt 1994 Springer New York pp. 188-198
48. E.W. Lemmon, M.O. McLinden, D.G. Friend, In: P.J. Linstrom, W.G. Mallard (Eds.), Thermophysical Properties of Fluid Systems in NIST Chemistry Webbook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg, MD. < http://webbook.nist.gov > (accessed 07.06.11).
49. 2 between 308 and 333 K in the pressure range 80 to 160 bar with supercritical fluid chromatography (SFC) Separation Science and Technology 17 1982 261 270 (Pubitemid 13493617)
50. G. Knaff, and U. Schlünder Diffusion coefficients of naphthalene and caffeine in supercritical carbon dioxide Chemical Engineering and Processing 21 1987 101 105 (Pubitemid 17556643)