Bond stretching and redox behavior in coinage metal complexes of the dichalcogenide dianions [(SPh2P)2CEEC(PPh 2S)2]2- (E=S, Se): Diradical character of the dinuclear copper(I) complex (E=S)

Chemistry - A European Journal

Volumn 17, Issue 42, 2011, Pages 11844-11856

  Konu, Jari ^a,b   Chivers, Tristram ^a   Tuononen, Heikki M ^b  

^a UNIVERSITY OF CALGARY   (Canada)

^b UNIVERSITY OF JYVÄSKYLÄ   (Finland)

Author keywords

coinage metals; dichalcogenides; diradical character; electronic structure; redox chemistry

Indexed keywords

AUROPHILIC; BOND-STRETCHING; COINAGE METALS; DIANIONIC LIGANDS; DIANIONS; DICHALCOGENIDES; DINUCLEAR COPPER; DIRADICALS; MIXED-VALENT; NMR DATA; REDOX BEHAVIOR; REDOX CHEMISTRY; REDOX PROCESS; SOLID-STATE STRUCTURES; TIME DEPENDENT DENSITY FUNCTIONAL THEORY; UV-VISIBLE SPECTRA;

CHLORINE; COINAGE; DENSITY FUNCTIONAL THEORY; ELECTRONIC STRUCTURE; GOLD COMPOUNDS; LIGANDS; METAL COMPLEXES; MINTS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RAMAN SPECTROSCOPY; REDOX REACTIONS; SELENIUM COMPOUNDS; SILVER; X RAY CRYSTALLOGRAPHY;

COPPER COMPOUNDS;

EID: 80053497725     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201100891     Document Type: Article

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