Identification of a novel η2-Se2 bonding mode in Cu(I) complexes of the dimeric selenocarbonyl dianions, [(EPh2P) 2CSeSeC(PPh2E)2]2-> (E = S, Se)

Inorganic Chemistry

Volumn 50, Issue 2, 2011, Pages 406-408

  Risto, Maarit ^a   Konu, Jari ^a   Chivers, Tristram ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; CUPRIC CHLORIDE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; LIGAND; ORGANOSELENIUM DERIVATIVE; SELENIUM;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; CRYSTALLIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; X RAY DIFFRACTION;

COPPER; CRYSTALLIZATION; INDICATORS AND REAGENTS; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOSELENIUM COMPOUNDS; OXIDATION-REDUCTION; SELENIUM; X-RAY DIFFRACTION;

EID: 78651268883     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic101866v     Document Type: Article

References (26)

1. For reviews, see: Silvestru, C. and Drake, J. E. Coord. Chem. Rev. 2001, 223, 117
2. Woollins, J. D. J. Chem. Soc., Dalton Trans. 1996, 2893
3. Haiduc, I. In Comprehensive Coordination Chemistry II; McCleverty, J. A. and Meyer, T. J., Eds.; Elsevier Ltd.: Amsterdam, 2003; pp 323 - 347.
4. Some exceptions that involve N -coordination have been reported, primarily for lanthanides: Pernin, C. G. and Ibers, J. A. Inorg. Chem. 2000, 39, 1216, 1222
5. Pernin, C. G. and Ibers, J. A. Inorg. Chem. 1999, 38, 5478
6. Also for Pd: Necas, M., Foreman, M. R. St. J., Marek, J., Woollins, J. D., and Novosad, J. New J. Chem. 2001, 25, 1256
7. Cantat, T., Mézailles, N., Ricard, L., Jean, Y., and Le Floch, P. Angew. Chem., Int. Ed. 2004, 43, 6382
8. Cantat, T., Ricard, L., Jean, Y., Le Floch, P., and Mézailles, N. Organometallics 2006, 25, 4965
9. Leung, W.-P., Wa, C.-L., Kan, K.-W., and Mak, T. C. W. Organometallics 2010, 29, 814
10. Foo, C., Lau, K.-C., Yang, Y-F, and So, C.-W. Chem. Commun. 2009, 6816
11. Cantat, T., Ricard, L., Mézailles, N., and Le Floch, P. Organometallics 2006, 25, 6030
12. Cantat, T., Demange, M., Mézailles, N., Ricard, L., Jean, Y., and Le Floch, P. Organometallics 2005, 24, 4838
13. Cantat, T., Jaroschik, F., Ricard, L., Le Floch, P., Nief, F., and Mézailles, N. Organometallics 2006, 25, 1329
14. Cantat, T., Jaroschik, F., Nief, F., Ricard, L., Mézailles, N., and Le Floch, P. Chem. Commun. 2005, 5178
15. Tourneux, J.-C., Berthet, J-C, Thuéry, P., Mézailles, N., Le Floch, P., and Ephritikhine, M. Dalton Trans. 2010, 39, 2494
16. Cantat, T., Arliguie, T., Noel, A., Thuéry, P., Ephritikhine, M., Le Floch, P., and Mézailles, N. J. Am. Chem. Soc. 2009, 131, 963
17. Konu, J., Tuononen, H. M., and Chivers, T. Inorg. Chem. 2009, 48, 11788
18. Konu, J. and Chivers, T. Chem. Commun. 2010, 46, 1431
19. Konu, J., Chivers, T., and Tuononen, H. M. Chem. - Eur. J. 2010, 16, 12977
20. 2 bonding mode for REER ligands when E = Se, and only Nb and Ti examples can be found for E = S: McKarns, P. J., Heeg, M. J., and Winter, C. H. Inorg. Chem. 1998, 37, 4743
21. Okuda, J., Fokken, S., Kleinhenn, T., and Spaniol, T. P. Eur. J. Inorg. Chem. 2000, 1321
22. For recent examples, E = S: Siemeling, U., Bretthauer, F., and Bruhn, C. J. Organomet. Chem. 2010, 695, 626
23. Figueroa, J. S., Yurkerwich, K., Melnick, J., Buccella, D., and Parkin, G. Inorg. Chem. 2007, 46, 9234 E = Se: Oilunkaniemi, R., Laitinen, R. S., and Ahlgren, M. J. Organomet. Chem. 2001, 623, 168
24. Grim, S. O. and Walton, E. D. Inorg. Chem. 1980, 19, 1982
25. 2O. Cauzzi, D., Graiff, C., Lanfranchi, M., Predieri, G., and Tiripicchio, A. J. Chem. Soc., Chem. Commun. 1995, 2443
26. Srogl, J., Hyvl, J., Révész, A., and Schröder, D. Chem. Commun. 2009, 3463