Direct selective extraction of titanium silicide Ti5Si 3 from multi-component Ti-bearing compounds in molten salt by an electrochemical process

Electrochimica Acta

Volumn 56, Issue 24, 2011, Pages 8430-8437

  Zou, Xingli ^a   Lu, Xionggang ^a   Zhou, Zhongfu ^a,b,c   Li, Chonghe ^a   Ding, Weizhong ^a  

^a SHANGHAI UNIVERSITY   (China)

^b UNIVERSITY OF OXFORD   (United Kingdom)

^c ABERYSTWYTH UNIVERSITY   (United Kingdom)

Author keywords

Electrochemical reduction; Molten salts; SOM; Ti bearing compounds; Ti5Si3

Indexed keywords

APPLIED POTENTIALS; CYLINDRICAL PELLETS; DOMINANT FACTOR; ELECTRO-DEOXIDATION; ELECTROCHEMICAL PROCESS; ELECTROCHEMICAL REDUCTIONS; ELECTROLYSIS TIME; METALLIC ELEMENTS; MOLTEN SALT; MOLTEN SALTS; MULTICOMPONENTS; OPTIMAL CONDITIONS; PRODUCT MORPHOLOGY; RAPID REDUCTION; SELECTIVE EXTRACTION; SOLID-OXIDE OXYGEN-ION-CONDUCTING MEMBRANES; SOM; TI-BEARING COMPOUNDS; TITANIUM SILICIDE;

BEARINGS (STRUCTURAL); CALCIUM CHLORIDE; ELECTROLYSIS; ELECTROLYTIC REDUCTION; FUSED SALTS; LIQUID METALS; METALLIC COMPOUNDS; MORPHOLOGY; SILICIDES; SILICON; TITANIUM;

TITANIUM COMPOUNDS;

EID: 80052814852     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2011.07.026     Document Type: Article

References (55)

1. L. Zhang, and J. Wu Acta Mater. 46 1998 3535
2. R. Mitra, and V.V. Rama Rao Metall. Mater. Trans. A 29 1998 1665
3. Z.H. Tang, J.J. Williams, A.J. Thom, and M. Akinc Intermetallics 16 2008 1118
4. K. Kishida, M. Fujiwara, H. Adachi, K. Tanaka, and H. Inui Acta Mater. 58 2010 846
5. H.K. Lin, Y.F. Tzeng, C.H. Wang, N.H. Tai, I.N. Lin, C.Y. Lee, and H.T. Chiu Chem. Mater. 20 2008 2429
6. J. Xu, L.L. Liu, X.L. Lu, and S.Y. Jiang Electrochem. Commun. 13 2011 102
7. J.H. Schneibel, and C.J. Rawn Acta Mater. 52 2004 3843
8. J.Y. Yang, J.S. Wu, and W. Hua Phys. B 279 2000 241
9. C.L. Yeh, H.J. Wang, and W.H. Chen J. Alloys Compd. 450 2008 200
10. D.D. Gu, Y.F. Shen, and Z.J. Lu Mater. Lett. 63 2009 1577
11. J.J. Williams, and M. Akinc Oxid. Met. 58 2002 57
12. W.J. Kroll Trans. Am. Electrochem. Soc. 78 1940 35
13. N. Nagamuri, I. Malinsky, and A. Claveau Metall. Trans. B 17 1986 503
14. F. Habashi Handbook of Extractive Metallurgy 1997 Wiley-VCH Weinheim, Germany
15. L. Zhang, H.P. Hu, L.P. Wei, Q.Y. Chen, and J. Tan Metall. Mater. Trans. B 41 2010 1158
16. D.J. Fray, and G.Z. Chen Mater. Sci. Technol. 20 2004 295
17. L. Zhang, L.N. Zhang, M.Y. Wang, G.Q. Li, and Z.T. Sui ISIJ Int. 46 2006 458
18. M.Y. Wang, X.W. Wang, Y.H. He, T.P. Lou, and Z.T. Sui Trans. Nonferrous Met. Soc. China 18 2008 459
19. T. Jiang, H.G. Dong, Y.F. Guo, G.H. Li, and Y.B. Yang Miner. Process. Extract. Metall. (Trans. Inst. Min. Metall. C) 119 2010 33
20. M. Ma, D.H. Wang, W.G. Wang, X.H. Hu, X.B. Jin, and G.Z. Chen J. Alloys Compd. 420 2006 37
21. M. Ma, D.H. Wang, X.H. Hu, X.B. Jin, and G.Z. Chen Chem. Eur. J. 12 2006 5075
22. G.Z. Chen, D.J. Fray, and T.W. Farthing Nature 407 2000 361
23. X.B. Jin, P. Gao, D.H. Wang, X.H. Hu, and G.Z. Chen Angew. Chem. Int. Ed. 43 2004 733
24. G.H. Qiu, D.H. Wang, X.B. Jin, and G.Z. Chen Electrochim. Acta 51 2006 5785
25. T. Nohira, K. Yasuda, and Y. Ito Nat. Mater. 2 2003 397
26. X.Y. Yan, and D.J. Fray Adv. Funct. Mater. 15 2005 1757
27. E. Gordo, G.Z. Chen, and D.J. Fray Electrochim. Acta 49 2004 2195
28. D.R. Sadoway J. Mater. Res. 10 1995 487
29. D.R. Sadoway, US Patent US2008/0023321A1 (2008).
30. A.H.C. Sirk, D.R. Sadoway, and L. Sibille ECS Trans. 28 2010 367
31. A. Krishnan, X.G. Lu, and U.B. Pal Metall. Mater. Trans. B 36 2005 463
32. U.B. Pal, D.E. Woolley, and G.B. Kenney JOM 53 2001 32
33. A. Martin, D. Lambertin, J.C. Poignet, M. Allibert, G. Bourges, L. Pescayre, and J. Fouletier JOM 55 2003 52
34. G.Z. Chen, D.J. Fray, and T.W. Farthing Metall. Mater. Trans. B 32 2001 1041
35. H.M. Rietveld J. Appl. Crystallogr. 2 1969 65
36. W. Xiao, X.B. Jin, Y. Deng, D.H. Wang, X.H. Hu, and G.Z. Chen ChemPhysChem 7 2006 1750
37. Y. Deng, D.H. Wang, W. Xiao, X.B. Jin, X.H. Hu, and G.Z. Chen J. Phys. Chem. B 109 2005 14043
38. D.H. Wang, X.B. Jin, and G.Z. Chen Annu. Rep. Prog. Chem. Sect. C 104 2008 189
39. D.T.L. Alexander, C. Schwandt, and D.J. Fray Acta Mater. 54 2006 2933
40. K. Jiang, X.H. Hu, M. Ma, D.H. Wang, G.H. Qiu, X.B. Jin, and G.Z. Chen Angew. Chem. Int. Ed. 45 2006 428
41. X.L. Zou, X.G. Lu, C.H. Li, and Z.F. Zhou Electrochim. Acta 55 2010 5173
42. X.L. Zou, X.G. Lu, C.H. Li, and B.J. Zhao Miner. Process. Extract. Metall. (Trans. Inst. Min. Metall. C) 120 2011 118
43. I. Barin K. Sora, J. Gardiner, Thermochemical Data of Pure Substances, vol. 1, 3rd ed. 1995 Wiley-VCH Weinheim, Germany
44. S. Tan, T. Örs, M.K. Aydinol, T. Öztürk, and. Karakaya J. Alloys Compd. 475 2009 368
45. R. Bhagat, D. Dye, S.L. Raghunathan, R.J. Talling, D. Inman, B.K. Jackson, K.K. Rao, and R.J. Dashwood Acta Mater. 58 2010 5057
46. K. Yasuda, T. Nohira, R. Hagiwara, and Y.H. Ogata J. Electrochem. Soc. 154 2007 E95
47. Y.J. Du, K.P. Rao, J.C.Y. Chung, and X.D. Han Metall. Mater. Trans. A 31 2000 763
48. C. Schwandt, D.T.L. Alexander, and D.J. Fray Electrochim. Acta 54 2009 3819
49. D.T.L. Alexander, C. Schwandt, and D.J. Fray Electrochim. Acta 56 2011 3286
50. C. Schwandt, and D.J. Fray Electrochim. Acta 51 2005 66
51. R.O. Suzuki, M. Aizawa, and K. Ono J. Alloys Compd. 288 1999 173
52. B. Mishra, and D.L. Olson J. Phys. Chem. Solids 66 2005 396
53. R.O. Suzuki J. Phys. Chem. Solids 66 2005 461
54. G.H. Kucera, and M.L. Saboungi Metall. Mater. Trans. B 7 1976 213
55. J. Ding, T. Tsuzuki, and P.G. McCormick J. Am. Ceram. Soc. 79 1996 2956