Selective homogeneous hydrogenation of biogenic carboxylic acids with [Ru(TriPhos)H] +: A mechanistic study

Journal of the American Chemical Society

Volumn 133, Issue 36, 2011, Pages 14349-14358

  Geilen, Frank M A ^a   Engendahl, Barthel ^a   Hölscher, Markus ^a   Klankermayer, Jürgen ^a   Leitner, Walter ^a,b  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

A-DENSITY; ABSOLUTE VALUES; BIOREFINERY CONCEPT; BOND METATHESIS; CATALYTIC PROCESS; CYCLIC ETHER; DIHYDROGEN MOLECULES; EXPERIMENTAL DATA; HYDRIDE TRANSFERS; ITACONIC ACID; LEVULINIC ACID; MECHANISTIC PATHWAYS; MECHANISTIC STUDIES; REACTIVITY PATTERN; SELECTIVE HYDROGENATION;

ALDEHYDES; CATALYST SELECTIVITY; DENSITY FUNCTIONAL THEORY; ETHERS; FUNCTIONAL GROUPS; HYDROGENATION; KETONES; MECHANICS;

CARBOXYLIC ACIDS;

ALDEHYDE; CARBON; CARBONYL DERIVATIVE; CARBOXYLIC ACID; ETHER DERIVATIVE; ITACONIC ACID; KETONE; LACTONE; LEVULINIC ACID; PHOSPHINE DERIVATIVE; RUTHENIUM DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; DENSITY FUNCTIONAL THEORY; ELECTROTRANSFORMATION; ENERGY TRANSFER; HYDROGENATION; NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT;

CATALYSIS; ETHERS, CYCLIC; HYDROGENATION; LACTONES; LEVULINIC ACIDS; RUTHENIUM COMPOUNDS; SUCCINATES;

EID: 80052596465     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2034377     Document Type: Article

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