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Volumn 49, Issue 32, 2010, Pages 5510-5514

Selective and flexible transformation of biomass-derived platform chemicals by a multifunctional catalytic system

Author keywords

Biomass; Homogeneous catalysis; Hydrogenation; Multifunctional catalyst; Platform chemicals

Indexed keywords

CATALYTIC SYSTEM; CYCLIC ETHER; HOMOGENEOUS CATALYSIS; ITACONIC ACID; LEVULINIC ACID; MOLECULAR CATALYSTS; MULTIFUNCTIONAL CATALYST; MULTIFUNCTIONAL CATALYSTS; PLATFORM CHEMICALS; SUSTAINABLE SUPPLY CHAINS;

EID: 77955035656     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201002060     Document Type: Article
Times cited : (545)

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    • In addition to its intrinsic acidity, the formation of HF was also noted by etching of the glass reactor inlets at temperatures above 175°C
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    • note
    • An alternative synthetic route to the two regioisomeric methyl butyrolactones 2-MGBL and 3-MGBL would involve formation of the anhydride and hydrogenation of one of the two C=O groups. However, no indication of the formation of the anhydride was observed by GC analysis of the product mixtures, and reactions with itaconic anhydride as the substrate gave only 14% lactones and 10% undefined side products under conditions that yielded full conversion into 2-MBDO when itaconic acid was used as the substrate.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.