Mechanistic insights of the initiation process of the ring-opening polymerization of ε-caprolactone by divalent Sm(BH4) 2(THF)2 with DFT: Concerted or oxidative reaction?

Organometallics

Volumn 30, Issue 17, 2011, Pages 4482-4485

  Iftner, Christophe ^a   Bonnet, Fanny ^b,c   Nief, François ^d   Visseaux, Marc ^b,c   Maron, Laurent ^a  

^a INSA   (France)

^b UNIV LILLE   (France)

^c UNITÉ DE CATALYSE ET DE CHIMIE DU SOLIDE   (France)

^d LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOMETALLICS; SYNTHESIS (CHEMICAL);

ACTIVE SPECIES; CAPROLACTONE; FULLY COMPATIBLE; INITIATION PROCESS; OXIDATIVE MECHANISM; OXIDATIVE REACTION; RADICAL SPECIES; TRANSFER REACTION;

RING OPENING POLYMERIZATION;

EID: 80052506065     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om200512g     Document Type: Article

References (38)

1. Woodruff, M. A.; Hutmacher, D. W. Prog. Polym. Sci. 2010, 35, 1217-1256
2. Dechy-Cabaret, O.; Martin-Vaca, B.; Bourissou, D. Chem. Rev. 2004, 104, 6147-6176
3. Arbaoui, A.; Redshaw, C. Polym. Chem. 2010, 1, 801-826
4. Ajellal, N.; Carpentier, J. F.; Guillaume, C.; Guillaume, S. M.; Helou, M.; Poirier, V.; Sarazin, Y.; Trifonov, A. Dalton Trans. 2010, 39, 8363-8376
5. Visseaux, M.; Bonnet, F. Coord. Chem. Rev. 2011, 255, 374-420
6. Oshimura, M.; Takasu, A. Macromolecules 2010, 43, 2283-2290
7. Dyer, H. E.; Huijser, S.; Susperregui, N.; Bonnet, F.; Schwarz, A. D.; Duchateau, R.; Maron, L.; Mountford, P. Organometallics 2010, 29, 3602-3621
8. Kramer, J. W.; Treitler, D. S.; Dunn, E. W.; Castro, P. M.; Roisnel, T.; Thomas, C. M.; Coates, G. W. J. Am. Chem. Soc. 2009, 131, 16042-16044
9. Xue, M.; Jiao, R.; Zhang, Y.; Yao, Y.; Shen, Q. Eur. J. Inorg. Chem. 2009, 4110-4118
10. 2 for polymerization: Nomura, R.; Endo, T. Chem. Eur. J. 1998, 4, 1605-1610
11. Evans, W. J.; Katsumata, H. Macromolecules 1994, 27, 2330-2332
12. Agarwal, S.; Brandukova-Szmikowski, N. E.; Greiner, A. Macromol. Rapid Commun. 1999, 20, 274-278
13. Binda, P. I.; Delbridge, E. E.; Abrahamson, H. B.; Skelton, B. W. Dalton Trans. 2009, 2777-2787
14. Jiang, L.; Lou, L.; Sun, W.; Xu, L.; Shen, Z. J. Appl. Polym. Sci. 2005, 98, 1558-1564
15. Visseaux, M.; Barbier-Baudry, D.; Blacque, O.; Hafid, A.; Richard, P.; Weber, F. New J. Chem. 2000, 24, 939-942
16. Wei, Y.; Yu, Z.; Wang, S.; Zhou, S.; Yang, G.; Zhang, L.; Chen, G.; Qian, H.; Fan, J. J. Organomet. Chem. 2008, 693, 2263-2270
17. Zhou, S.; Wang, S.; Sheng, E.; Zhang, L.; Yu, Z.; Xi, X.; Chen, G.; Luo, W.; Li, Y. Eur. J. Inorg. Chem. 2007, 1519-1528
18. Wang, S.; Wang, S.; Zhou, S.; Yang, G.; Luo, W.; Hu, N.; Zhou, Z.; Song, H. B. J. Organomet. Chem. 2007, 692, 2099-2106
19. Wu, Y.; Wang, S.; Qian, C.; Sheng, E.; Xie, M.; Yang, G.; Feng, Q.; Zhang, L.; Tang, X. J. Organomet. Chem. 2005, 690, 4139-4149
20. Nishiura, M.; Hou, Z.; Koizumi, T.; Imamoto, T.; Wakatsuki, Y. Macromolecules 1999, 32, 8245-8251
21. Delbridge, E. E.; Dugah, D. T.; Nelson, C. R.; Skelton, B. W.; White, A. H. Dalton Trans. 2007, 1, 143-153
22. Dugah, D. T.; Skelton, B. W.; Delbridge, E. E. Dalton Trans. 2009, 8, 1436-1445
23. Jaroschik, F.; Bonnet, F.; Le Goff, X. F.; Ricard, L.; Nief, F.; Visseaux, M. Dalton Trans. 2010, 39, 6761-6766
24. Guillaume, S. M.; Schappacher, M.; Soum, A. Macromolecules 2003, 36, 54-60
25. Barros, N.; Mountford, P.; Guillaume, S. M.; Maron, L. Chem. Eur. J. 2008, 14, 5507-5518
26. Maron, L.; Eisenstein, O. J. Am. Chem. Soc. 2001, 123, 1036-1039
27. Perrin, L.; Maron, L.; Eisenstein, O. Inorg. Chem. 2002, 41, 4355-4362
28. Eisenstein, O.; Maron, L. J. Organomet. Chem. 2002, 647, 190-197
29. Schinzel, S.; Bindl, M.; Visseaux, M.; Chermette, H. J. Phys. Chem. A 2006, 110, 11324-11331
30. Maron, L.; Eisenstein, O. J. Phys. Chem. A 2000, 104, 7140-7143
31. Labouille, S.; Nief, F.; Maron, L. J. Phys Chem. A 2011, 115, 8295-8301
32. Castro, L.; Bart, S. C.; Lam, O. P.; Mayer, K.; Maron, L. Organometallics 2010, 29, 5504-5510
33. Jenter, J.; Roesky, P. W.; Ajellal, N.; Guillaume, S. M.; Susperregui, N.; Maron, L. Chem. Eur. J. 2010, 16, 4629-4638
34. Evans, W. J.; Giarikos, D. G.; Allen, N. T. Macromolecules 2003, 36, 4256-4257
35. Hou, Z.; Fujita, A.; Zhang, Y.; Miyano, T.; Yamazaki, H.; Wakatsuki, Y. J. Am. Chem. Soc. 1998, 120, 754-766
36. Agarwal, S.; Greiner, A J. Chem. Soc. Perkin Trans. 1 2002, 2033-2042 and references therein
37. Miyake, G. M.; Newton, S. E.; Mariott, W. R.; Chen, E. Y. X. Dalton Trans. 2010, 39, 6710-6718
38. Marks, T. J. Science 1982, 217, 989-997