Reaction of O2 with [(-)-sparteine]Pd(H)Cl: Evidence for an intramolecular [H-L]+ "reductive elimination" pathway

Journal of the American Chemical Society

Volumn 133, Issue 34, 2011, Pages 13268-13271

  Decharin, Nattawan ^a   Popp, Brian V ^a   Stahl, Shannon S ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROBIC OXIDATIONS; CATALYTIC MECHANISMS; COMPUTATIONAL RESULTS; COMPUTATIONAL STUDIES; H-BONDS; HYDROGEN ATOMS; INTRAMOLECULAR DEPROTONATION; NITROGEN LIGAND; OXIDATION CATALYSTS; REDUCTIVE ELIMINATION;

ABSTRACTING; CATALYTIC OXIDATION; CHELATION; HYDRIDES; LIGANDS; OXIDATION; OXYGENATION;

REACTION INTERMEDIATES;

CHLORINE; HYDROGEN; LIGAND; NITROGEN; OXYGEN; PALLADIUM; SPARTEINE;

ARTICLE; CATALYST; DENSITY FUNCTIONAL THEORY; ELIMINATION REACTION; OXIDATION REDUCTION REACTION; OXYGENATION; PROTON TRANSPORT; REDUCTIVE ELIMINATION; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY;

CATALYSIS; MODELS, MOLECULAR; OXIDATION-REDUCTION; OXYGEN; PALLADIUM; SPARTEINE;

EID: 80052078778     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja204989p     Document Type: Article

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