Mathematical modeling of Cs(I) transport through flat sheet supported liquid membrane using calix-[4]-bis(2,3-naptho)-18-crown-6 as the mobile carrier

Desalination

Volumn 278, Issue 1-3, 2011, Pages 405-411

  Kandwal, P ^a   Dixit, S ^a   Mukhopadhyay, S ^a   Mohapatra, P K ^a   Manchanda, V K ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

Calix crown; Cesium; Facilitated transport; NPOE; Supported liquid membrane

Indexed keywords

CALIX-CROWN; CARRIER LIGANDS; DIFFUSIONAL TRANSPORT; DISTILLED WATER; FACILITATED TRANSPORT; FEED SOLUTION; FLAT SHEETS; MATHEMATICAL MODELING; MEMBRANE PORES; MOBILE CARRIERS; N-DODECANE; NPOE; OPERATING CONDITION; SUPPORTED LIQUID MEMBRANE; SYSTEM COMPOSITION;

CESIUM; CESIUM COMPOUNDS; CROWN ETHERS; ETHERS; LIGANDS; LIQUID MEMBRANES; MATHEMATICAL MODELS; NITRIC ACID;

LIQUIDS;

CESIUM; DIFFUSION; EXPERIMENTAL STUDY; MATHEMATICAL ANALYSIS; MEMBRANE; NUMERICAL MODEL;

EID: 80052036165     PISSN: 00119164     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.desal.2011.05.062     Document Type: Article

References (28)

1. IAEA Technical Data Series No. 356 1993, IAEA.
2. 3 solutions-a technology review and assessment. Sep. Sci. Technol. 1987, 22:191-214.
3. Miller R.L., Pinkerton A.B., Hurlburt P.K., Abney K.D. Extraction of Cs and Sr in to hydrocarbon solvent using-tetra-cobalt dicarbolide. Solv. Ext. Ion. Exch. 1995, 13:813-827.
4. 137Cesium from acidic nuclear waste solutions. 1: equilibrium capacity and kinetic properties of the sorbent. Solv. Extr. Ion Exch. 2009, 27:199-218.
5. Banerjee D., Rao M.A., Gabriel J., Samanta S.K. Recovery of purified radiocesium from acidic solution using ammonium molybdophosphate and resorcinol formaldehyde polycondensate resin. Desalination 2008, 232:172-180.
6. 3 medium using macrocyclic polyethers. Sep. Sci. Technol. 1981, 16:519-548.
7. Talanov V.S., Talanov G.G., Gorbunova M.G., Bartsch R.A. Novel cesium selective, 1,3-alternate calix[4]arene(bis-crown-6 ethers) with proton ionizable groups for enhanced extraction efficiency. J. Chem.Soc., Perkin Trans. 2002, 2:209-215.
8. Ungaro R., Casnati A., Ugozzoli F., Pochini A., Dozol J.-F., Hill C., Rouquette H. 1,3-Dialkoxycalix[4]arenecrowns-6 in 1,3-alternate configuration: cesium-selective ligands that exploit cation-arene interactions. Angew. Chem. Int. Ed. Engl. 1994, 33:1506-1509.
9. Takeda Y. Solvent extraction of metal by crown ether. Top. Curr. Chem. 1984, 121:1-27.
10. Dietz M.L., Horwitz E.P., Rhoads S., Bartsch R.A., Palka A., Krzykawski J. Extraction of Cesium from acidic nitrate media using macrocyclic polyethers: the role of organic phase water. Solv. Extr. Ion Exch. 1996, 14:1-12.
11. Dietz M.L., Horwitz E.P., Jensen M.P., Rhoads S., Bartsch R.A., Palka A., Krzykawski J., Nam J. Substituent effects in the extraction of Cesium from acidic nitrate media with macrocyclic polyethers. Solv. Extr. Ion Exch. 1996, 14:357-384.
12. Ghidini E., Ugozzoli F., Ungaro R., Harkema S., El-Fadl A., Reinhoudt D.N. Complexation of alkali metal cations by conformationally rigid, stereoisomeric calix[4]arene crown ethers: a quantitative evaluation of preorganization. J. Am. Chem. Soc. 1990, 113:6979-6985.
13. Thuery P., Nierlich M., Lamare V., Dozol J.-F., Asfari Z., Vicens J. Bis(crownether) and azobenzo crown derivatives of calix[4]arene. A review of structural information from crystallographic and modeling studies. J. Incl. Phenom. Macrocycl. Chem. 2000, 36:375-408.
14. Mohapatra P.K., Ansari S.A., Sarkar A., Bhattacharyya A., Manchanda V.K. Evaluation of calix-crown ionophores for selective separation of radio-cesium from acidic nuclear waste solution. Anal. Chim. Acta 2006, 571:308-314.
15. 137Cs transport from acidic solutions. J. Membr. Sci. 2008, 310:229-236.
16. Baker R.W., Tuttle M.E., Kelly D.J., Lonsdale H.K. Couple transport membranes. I. Copper separations. J. Membr. Sci. 1977, 2:213-233.
17. Ibanez J.A., Victoria L., Hernandez A. Flux and characteristic parameters in mediated transport through liquid membranes. I. A theoretical model. Sep. Sci. Technol. 1989, 24:157-164.
18. Kiani A., Bhave R.R., Sirkar K.K. Solvent extraction with immobilized interfaces in a microporous membrane. J. Membr. Sci. 1984, 20:125-145.
19. Prasad R., Kiani A., Bhave R.R., Sirkar K.K. Further studies on solvent extraction with immobilized interfaces in a microporous hydrophobic membrane. J. Membr. Sci. 1986, 26:79-97.
20. Zha F., Fane A.G., Fell C.J.D. Liquid membrane processes for gallium recovery from alkaline solutions. Ind. Eng. Chem. Res. 1995, 34:1799-1809.
21. Huang T., Huang C. The mechanism of transport of uranyl nitrate across a solid supported liquid membrane using tri-butyl phosphate as mobile carrier. J. Membr. Sci. 1986, 29:295-308.
22. Danesi P.R., Horwitz E.P., Rickert P.G. Rate and mechanism of facilitated americium (III) transport through a supported liquid membrane containing a bifunctional organophosphorus mobile carrier. J. Phys. Chem. 1983, 87:4708-4715.
23. De S., Dias J.M., Bhattacharya P.K. Short and long term flux decline analysis in ultrafiltration. Chem. Eng. Commum. 1997, 159:67-89.
24. Danesi P.R. Separation of metal species by supported liquid membranes. Sep. Sci. Technnol. 1984-85, 19:857-894.
25. Wilke C.R., Chang P. Correlations of diffusion coefficients in dilute solutions. A. I. Ch. E J. 1955, 264-270.
26. Cussler E.L. Diffusion -- Mass Transfer in Fluid Systems 1988, Cambridge University Press, New York. first ed.
27. Panja S., Mohapatra P.K., Tripathi S.C., Manchanda V.K. Controlled pertraction of plutonium(III) under reducing conditions from acidic feeds using TODGA as the carrier extractant. Sep. Sci. Technol. 2011, 46:94-104.
28. Panja S., Mohapatra P.K., Dakshinamoorthy A., Manchanda V.K. Transport of thorium(IV) across a supported liquid membrane containing TODGA as the carrier. Sep. Sci. Technol. 2010, 45:1112-1120.