Transport of thorium(IV) across a supported liquid membrane containing N,N,N′,N′-tetraoctyl-3-oxapentanediamide (TODGA) as the Extractant

Separation Science and Technology

Volumn 45, Issue 8, 2010, Pages 1112-1120

  Panja, S ^a   Mohapatra, P K ^a   Tripathi, S C ^a   Manchanda, V K ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

Diglycolamide; Liquid membrane; Nuclear waste management; Thorium; Transport

Indexed keywords

DIFFUSION COEFFICIENTS; DIFFUSION CONTROLLED; DIGLYCOLAMIDE; EXTRACTANT CONCENTRATION; EXTRACTANTS; FLAT SHEETS; FLUENCES; MEMBRANE INTERFACE; N-DODECANE; NUCLEAR WASTE MANAGEMENT; OXALIC ACID; SUPPORTED LIQUID MEMBRANE; TRANSPORT BEHAVIOR; TRANSPORT MECHANISM; TRANSPORT RATE;

CONCENTRATION (PROCESS); LIQUIDS; METAL IONS; METAL RECOVERY; RADIOACTIVE WASTES; SOLVENT EXTRACTION; SOLVENTS; THORIUM; WASTE MANAGEMENT;

LIQUID MEMBRANES;

CONTROLLED RELEASE; DIFFUSION; EXTRACTION METHOD; INTERFACIAL PROPERTY; LIQUID; MEMBRANE; PHASE SEPARATION; TRANSPORT PROCESS; WASTE MANAGEMENT; WASTEWATER;

EID: 77952157425     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496391003697416     Document Type: Article

References (31)

1. Boyadzhiev, L.; Lazarova, Z. (1995) In: Membrane Separations Technology: Principles and Applications, Noble, R.D.; Stern, S.A., eds.; Elsevier Science B.V., 283-300.
2. Bartsch, R.A.; Way, J.D.; Chrisstoffels, L.A.J.; de Jong, F.; Reinhouldt, D.N. (1996) In: Chemical Separations with Liquid Membranes, Bartsch, R.A.; Way, J.D., eds.; ACS symposium series number 642, ACS, Washington, DC, p. 1-10.
3. Sastre, A.M.; Kumar, A.; Shukla, J.P.; Singh, R.K. (1998) Improved techniques in liquid membrane separations: An overview. Sep. Purif. Methods, 27: 213-298.
4. Mohapatra, P.K.; Manchanda, V.K. (2003) Liquid membrane based separations of actinides and fission products. Indian J. Chem., 42A: 2925-2939.
5. Kathios, D.J.; Jarvinen, G.D.; Yarbro, S.L.; Smith, B.F. (1994) A preliminary evaluation of microporous hollow fiber membrane modules for the liquid-liquid extraction of actinides. J. Membr. Sci., 97: 251-261.
6. Geist, A.; Weigl, M.; Muellich, U.; Gompper, K. (2003) Application of novel extractants for actinide (III)/lanthanide (III) separation in hollow-fibre modules. Membr. Technol., 5: 5-7.
7. Geist, A.; Weigl, M.; Gompper, K. (2002) Minor actinide partitioning by liquid-liquid extraction: Using a synergistic mixture of bis(chlorophenyl)-dithiophosphinic acid and TOPO in a hollow fiber module for americium(II)-lanthanides (III) separation. Sep. Sci. Technol., 37: 3369-3390.
8. Bhattacharyya, A.; Mohapatra, P.K.; Ansari, S.A.; Raut, D.R.; Manchanda, V.K. (2008) Separation of trivalent actinides from lanthanides using hollow fiber supported liquid membrane containing Cyanex-301 as the carrier. J. Membr. Sci., 312: 1-5.
9. Sugo, Y.; Sasaki, Y.; Tachimori, S. (2002) Studies on hydrolysis and radiolysis of N,N,N',N'-tetraoctyl-3-oxapentane-1,5-diamide. Radiochim. Acta, 90: 161-165.
10. Suzuki, S.; Sasaki, Y.; Sugo, Y.; Apichaibukol, A.; Kimura, T. (2004) Extraction and separation of Am(III) and Sr(II) by N,N,N',N'-tetraoctyl-3-oxapentanediamide (TODGA). Radiochim. Acta, 92: 463-466.
11. Sasaki, Y.; Sugo, Y.; Suzuki, S.; Tachimori, S. (2001) The novel extractants, diglycolamides for the extraction of lanthanides and actinides in HNO3-n-dodecane system. Solv. Extr. Ion Exch., 19: 91-103.
12. Ansari, S.A.; Pathak, P.N.; Manchanda, V.K.; Husain, M.; Prasad, A.K.; Parmar, V.S. (2005) N,N,N',N'-Tetraoctyl diglycolamide (TODGA): A promising extractant for actinide-partitioning from high-level waste (HLW). Solv. Extr. Ion Exch., 23: 463-479.
13. Zhu, Z.-X.; Sasaki, Y.; Suzuki, H.; Suzuki, S.; Kimura, T. (2004) Cumulative study on solvent extraction of elements by N,N,N',N'-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid into n-dodecane. Anal. Chim. Acta, 527: 163-168.
14. Ansari, S.A.; Pathak, P.N.; Husain, M.; Prasad, A.K.; Parmar, V.S.; Manchanda, V.K. (2006) Extraction chromatographic studies of metal ions using N,N,N',N'-tetraoctyl diglycolamide as the stationary phase. Talanta, 68: 1273-1280.
15. Ansari, S.A.; Mohapatra, P.K.; Prabhu, D.R.; Manchanda, V.K. (2006) Transport of Americium(III) through a supported liquid membrane containing N,N,N',N'-tetraoctyl-3-oxapentane diamide (TODGA) in n-dodecane as the carrier. J. Membr. Sci., 282: 133-141.
16. Ansari, S.A.; Mohapatra, P.K.; Prabhu, D.R.; Manchanda, V.K. (2007) Evaluation of N,N,N',N'-tetraoctyl-3-oxapentane-diamide (TODGA) as a mobile carrier in remediation of nuclear waste using supported liquid membrane. J. Membr. Sci., 298: 169-174.
17. Thakur, P.; Veeraraghavan, R.; Mohapatra, P.K.; Manchanda, V.K.; Dash, K.C. (1996) Extraction of ternary complexes of thorium(IV) with 3-phenyl-4-benzoyl-5-isoxazolone and neutral oxodonors. Talanta, 43: 1305-1312.
18. Sriram, S.; Mohapatra, P.K.; Pandey, A.K.; Manchanda, V.K.; Badheka, L.P. (2000) Facilitated transport of americium(III) from nitric acid media using dimethyldibutyl-tetradecyl-1,3-malonamide. J. Membr. Sci., 177: 163-175.
19. Danesi, P.R.; Horwitz, E.P.; Rickert, P.G. (1983) Rate and mechanism of facilitated americium(III) transport through a supported liquid membrane containing a bifunctional organophosphorous mobile carrier. J. Phys. Chem., 87: 4708-4715.
20. Hogefeldt, E. (Ed.). (1982) Stability Constant of Metal Ion Complexes, Part A: Inorganic Ligands; IUPAC Chemical Data Series No. 21, Pergamon: Oxford.
21. Katz, J.J.; Seaborg, G.T.; Morss, L.R. (Eds.). (1986) The Chemistry of the Actinide Elements, Vol. 1, 2nd Ed.;Chapman and Hall:NewYork.
22. Patil, C.B.; Mohapatra, P.K.; Manchanda, V.K. (2008) Transport of thorium from nitric acid solution by non-dispersive solvent extraction using a hollow fibre contactor. Desalination, 232: 272-280.
23. Sasaki, Y.; Rapold, P.; Arisaka, M.; Hirata, M.; Kimura, T.; Hill, C.; Cote, G. (2007) An additional insight into the correlation between the distribution ratios and the aqueous acidity of the TODGA system. Solv. Extr. Ion Exch., 25: 187-204.
24. He, D.S.; Ma, M.; Zha, Z.H. (2000) Transport of cadmium ions through a liquid membrane containing amine extractants as carriers. J. Membr. Sci., 169: 53-59.
25. Juang, R.-S.; Kao, H.-C.; Wu, W.-H. (2004) Analysis of liquid membrane extraction of binary Zn(II) and Cd(II) from chloride media with Aliquat 336 based on thermodynamic equilibrium models. J. Membr. Sci., 228: 169-177.
26. Geist, A.; Plucinski, P.; Nitsch, W. (2000) Mass transfer kinetics of reactive multi-cation coextraction to bis(2-ethylhexyl) phosphoric acid. Solvent Extr. Ion Exch., 18: 493-515.
27. Wilke, C.R.; Chang, P. (1955) Correlation of diffusion coefficients in dilute solutions. AIChE J., 1: 264-270.
28. Schotte, W. (1992) Prediction of the molar volume at the normal boiling point. Chem. Eng. J., 48: 167-172.
29. Mohapatra, P.K.; Lakshmi, D.S.; Mohan, D.; Manchanda, V.K. (2006) Uranium pertraction across a PTFE flatsheet membrane containing Aliquat 336 as the carrier. Sep. Purif. Technol., 51: 24-30.
30. Mohapatra, P.K.; Lakshmi, D.S.; Mohan, D.; Manchanda, V.K. (2004) Selective transport of cesium using a supported liquid membrane containing di-tert-butylbenzo 18 crown 6 as the carrier. J. Membr. Sci., 232: 133-139.
31. Ansari, S.A.; Mohapatra, P.K.; Raut, D.R.; Adya, V.C.; Thulasidas, S.K.; Manchanda, V.K. (2008) Separation of Am(III) and trivalent lanthanides from simulated high level waste using a hollow fiber supported liquid membrane. Sep. Purif. Tech., 63: 239-242.